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WATER-BASED
PA1 NT
FORM
U
LATIONS
Volume
4
by
Ernest
W.
Flick
NOYES
PUBLICATIONS
I
np
I
WesWood,
New
Jersey,
U.S.A.
Copyright
8
1997
by Ernest W. Flick
No patt
of
this
book
may be reproduced
or
utilized
in
any fonn
or
by any means, electronic
or
mechanical
including photocopying, recording
01
by any informa-
tion stonge and retrieval system, without permission
in
Writing
from
the Publisher.
Library
of
Congress Catalog Card Number:
75-2939
Printed in the United States
ISBN
0-8155-1415-8
Published
in
the United States of America by
Noyes Publications
369
Fairview Avenue
Westwood, New Jersey
07675
10
9
8
7
6
5
4
3 2
1
Library of Congress Cataloging-in-Publications Data
(Revised
for
vol.
4)
Flick, Ernest
W.
Water-based paint formulations.
Vol.
4
published by Noyes Publications.
Includes index.
1.
Paint--Patents.
II.
Title.
TP935.F62 1975 66T.63 75-2939
ISBN
0-8155-0571-X
(v.
1)
ISBN
0-8155-1345-3
(v.
3)
ISBN
0-8155-1415-8
(v.
4)
In Memory
of
My Mother and Father
This collection of
232
up-to-date water-based trade and industrial formulations
will be of value to technical and managerial personnel in paint manufacturing
companies and firms which supply raw materials or services to these
companies, and to those interested in
less
hazardous, environmentally safer
formulations. The book
will
be useful to both those with extensive experience
as well
as
those new to the field. This book includes new and different
formulations than those included in the previously published
Industrial Water
-
Based Paint Formulations
and
Water -Based Paint Formulations.
The data consist of selections of manufacturers' suggested formulations made at
no
cost to, nor influence from, the makers or distributors of these materials.
The information given is presented
as
supplied; the manufacturer should be
contacted
if
there are any questions. Only the most recent data supplied
us
has
been included. Any solvent contained is minimal.
The table of contents
is
organized in such a way
as
to serve
as
a subject index.
The formulations described are divided into sections which cover exterior,
interior, and exterior and/or interior water-based paints, enamels, and coatings,
as
indicated below:
I.
Coatings and Topcoats
11.
Coil Coatings
111.
Enamels
IV.
Enamels-Baking
V.
Exterior Paints and Related Products
VI.
Interior Paints and Related Products
VII.
Lacquers
VIII.
Primers
IX.
Sealants and Related Compounds
X.
Stains
XI.
Miscellaneous
Each formula
has
been placed
in
the chapter which
is
most applicable. The
reader,
if
seeking a formula for a specific end use, should check each chapter
which could possibly apply.
vii
...
viii Preface
In addition to the above, there are
two
other sections which will be helpful to
the reader:
XI.
A chemical trade name section where trade-named raw materials
are listed with a chemical description and the supplier's name. The
specifications which the raw materials meet
are
included if
applicable.
XIII.
Main office addresses of the suppliers of trade-named raw materials
and/or formulations.
Included in the descriptive information for each formulations, where available,
the following properties may be listed: viscosity, solids, content,
%
nonvolatiles, pigment volume concentration, density, pH, spatter, leveling, sag
resistance, scrub stability, freeze-thaw stability, ease of application, gloss
foaming, cratering, brightness, opacity, water spotting, adhesion
to
chalk, brush
clean-up, reflectance, and sheen.
Ernest W. Flick
Notice
To
the best of our knowledge the information in this publications is
accurate; however, the Publisher does not assume any responsibility or
liability for the accuracy or completeness of, or consequence arising from,
such information. These formulations do not purport to contain detailed
manufacturing nor user instruction, and by its range and scope could not
possibly do
so.
Mention of trade names or commercial products does not
constitute endorsement or recommendation for use by the Author or
Publisher.
Water-based paint raw materials could be toxic, and therefore, due caution
should always be exercised in the
use
of
these hazardous materials. Final
determination of the suitability of any information or product for use
contemplated by any user, and the manner of that use, is the sole
responsibility of the user. We strongly recommend that users seek and
adhere to a manufacturer's or supplier's current instructions for handling
each material they use.
The Author and Publisher have used their best efforts to include only the
most recent data available. The reader
is
cautioned to consult the supplier
in case of questions regarding current availability.
SECTION
I:
COATINGS
AND
TOPCOATS
....................
1
Clearcoat Modification
...............................
2
825/Rhoplex CL-104)
................................
3
Ancamine 2410 High Solids Coating
........................
4
2410/Ancamide 500 High Solids Coating
..................
5
Cured with HMMM
.................................
6
Phenolic Clear Bake Coating
..............................
8
Clear Bake Coating
.....................................
9
Phenolic Clear Bake Coating
..............................
9
Clear Wood Coating-A
&
B
&
C K-Flex UD-320W Modified
....
10
Direct to Metal Acrylic Latex Coating Starting Point
Formulation
......................................
11
Low Gloss VinyVABS Topcoat
...........................
12
Clear Topcoat for Flexible Substrates
.......................
12
..........
13
Lower Adhesion
...................................
13
Polyphobe Rheology Modifiers Formula C Good Leveling
.....
14
.................................
14
Acrylic
EmulsiodUrea-Formaldehyde
Wood
Aliphatic Wood Coating Formulation (Sancure
Exhibit
4
.
Starting Formulation Ancamine
Black Single Coat K-Flex XM-4316 PU Dispersion
Clear Bake Coating
.....................................
7
Strippable Coating Sample Formulation A Unmodified
Strippable Coating Sample Formulation B
Strippable Coating Formulations Thickened with Ucar
Formula D High Build
Strippable Coating for Plastic Substrates
.....................
15
Strippable Coating Formulations
..........................
16
Topcoat for Prefinished Hardboard Siding
....................
17
Water-Borne Alkyd/Melamine Wood Clearcoat Modification
......
18
Waterborne Clear High
Gloss
Topcoat
......................
20
White
Gloss
Maintenance Topcoat
.........................
21
White Gloss Topcoat
...................................
22
Wood Topcoat Model Formulations
........................
23
ix
x Contents and Subject Index
SECTION
11:
COIL COATINGS
............................
24
Chromate Coil-Coating Primer
...........................
25
Low-Sheen Coil-Coating Topcoat
.........................
26
Medium-Gloss Coil-Coating Topcoat
......................
27
Strippable Coil Coating
.................................
28
SECTION
LII:
ENAMELS
.................................
29
Acrylic Emulsion Enamel-B&C K-Flex UD-320W Modified
.....
30
Synergistic Effects of Combining Nacorr with Anti-
Corrosive Pigment
in
an Air Dry Water Reducible
Alkyd Modified Acrylic Enamel
.......................
31
Ancamide 2353 Fast Drying White Gloss Enamel
..............
32
Ancamide 2353 Low VOC White Gloss Enamel
...............
33
Cary Gloss White Enamel
...............................
34
Clear Enamel (For Maximum Solvent and Abrasion
Resistance)
.......................................
36
Gloss Safety Red Enamel
...............................
37
Gloss Safety Yellow Enamel
.............................
38
Gloss White Enamel
...................................
39
Gloss White Enamel (Maximum Solvent and Abrasion
Resistance)
.......................................
41
Green Air Dry Enamel for Flexible Substrates
.................
42
High-Hiding Eggshell Enamel
............................
43
MacGregor Gloss Black Enamel
..........................
44
Pinehurst Gloss Green Enamel
............................
45
Self-Priming Interior Semi-Gloss Enamel
...................
46
Exterior Maintenance-Type Coating
........................
46
Semigloss Enamel
.....................................
47
Southern Pines Gloss White Enamel
........................
49
Spensol I54 Orange Enamel
.............................
50
Waterborne Black Enamel Based
on
Epotuf 37-143/37-680
(Formula No
.
3019-28A)
............................
51
Waterborne Blue Enamel Based on Epotuf 37-143/37-680
(Formula
No
.
3019-316)
............................
52
Waterborne Dark Blue Enamel Based on Epotuf
37-143/37-680 (Formula No
.
3019-31D)
.................
53
Waterborne Green Enamel Based on Epotuf 37-143/37-680
(Formula
No
.
3019-3lF)
.............................
54
Waterborne Orange Enamel Based
on
Epotuf 37-143/37-680
(Formula 3019-310
................................
55
Waterborne Red Enamel Based on Epotuf 37-143/37-680
(Formula
No
.
3019-31B)
............................
56
Waterborne Red Orange Enamel Based on Epotuf
37-143/37-680 (Formula
No
.
3019-31E)
.................
57
Contents and Subject Index xi
Waterborne Yellow Epoxy Enamel Based on Epotuf
37-143/37-680 (Formula
No
.
3019-31C)
.................
58
Whispering Pines Semigloss White Enamel
...................
59
Anquamine
401
1:l
White Gloss Enamel
....................
60
Gloss
Enamel
.....................................
61
Anquamine 401/Solid Resin Dispersion 2:l White
SECTION
IV:
ENAMELS-BAKING
........................
62
Clear Bake Coating
....................................
63
Phenolic Clear Bake Coating
.............................
63
Clear High Gloss. Baking Finish
..........................
64
Blue Metallic Urethane Enamel
...........................
64
Experimental Water-Reducible Polyester Gloss White
Baking Enamel Using Halox SZP-391
...................
65
Waterborne Acrylic Bake Enamel
Water Reducible Polyester Baking Enamel
Spensol L54 White Baking Enamel
2-Component Waterborne System
.........................
69
.........................
66
...................
67
........................
68
SECTION
V:
EXTERIOR PAINTS AND RELATED PRODUCTS
...
70
Exterior Flat House Paint with ZnO
........................
71
Exterior
Gloss
White
...................................
73
Exterior House Paint
...................................
74
Exterior House Paint
.
Tint Base
..........................
75
Exterior Semigloss Formulation
...........................
77
Exterior Tint Base Formulation
...........................
78
Exterior Trim Formulation Modified Vinyl Acrylic Paint
.........
79
Exterior Trim Formulation
...............................
80
Exterior White Flat House Paint
...........................
82
Exterior White Trim house Paint
..........................
83
Good Quality White Exterior Flat Paint for Masonry
............
84
Good Quality White Exterior Flat Paint for Wood
..............
85
Gregson Drive Gloss White
..............................
86
High Quality Exterior Semi Gloss Paint
.....................
87
High Sheen White House Paint
...........................
88
Low VOC Exterior House Paint
...........................
89
Quality Exterior Flat Formulation
..........................
90
Quality Exterior Flat Paint
...............................
91
Quality White Exterior Trim Paint
.........................
92
Quality White House Paint with ZnO
.......................
94
Urethane Fortified Porch
&
Deck Enamel
....................
95
Weather Barrier Formulation
.............................
96
White Exterior Flat House Paint with Zinc Oxide
..............
97
Exterior Semigloss
....................................
76
xii Contents and Subject Index
White Roof Coating
...................................
99
SECI'ION
VI:
INTERIOR PAINTS AND RELATED PRODUCTS
.
100
Clear High Gloss Varnish
..............................
101
Fast-Dry Sealer
.....................................
101
Economy Flat Wall Paint
..............................
102
Good Quality Interior Flat with <50g/L VOC
................
104
High Quality Super Flat Interior Paint
.....................
105
Interior Clear Wood Finish (Rhoplex CL-l04/Sancure
815)
......
106
Interior Sanding Sealer (Rhoplex CL-105)
..................
106
Interior Contractor Flat
................................
107
Interior Good Quality Flat for Roller and Brush
Application
.....................................
108
Interior Good Quality Flat
..............................
110
Interior Semigloss Formulation
..........................
111
Interior Vinyl Acrylic Eggshell for Roller and
Brush Application
.................................
112
Interior Vinyl Acrylic Semigloss
.........................
114
Intumescent Interior White Fire-Retardant Paint
..............
115
Low
VOC Interior Flat
................................
116
Solvent Free Interior Satin Paint
.........................
117
White Interior Eggshell
................................
118
SECTION
VII:
LACQUERS
..............................
119
Green Lacquer
......................................
120
DIY Waterborne Lacquer
...........................
121
White Lacquer
......................................
122
Foam Control with Agitan Additives in a High Gloss
SECI'ION
VIII:
PRIMERS
...............................
124
Acrylic Latex Tannin Block Primer Using Halox BW-100
......
125
Alkyd Modified Latex Primer
...........................
126
Ancamide 2353 Curing Agent Anti-Corrosive Primer
..........
127
Anquamine 401/Semi-solid Epoxy Dispersion Lead
and Chromate Free Red Iron Oxide Primer
128
Anquamine 401/Solid Resin Dispersion Lead and
Chromate Free Red Iron Oxide Primer
..................
129
Corrosion Inhibitive Primer
.............................
130
Metal Wash Primer
...................................
130
Cost Effective 2K Water-Base
Epoxy
Primer Using
Halox SW-111
...................................
131
Dipping Primer
......................................
132
Experimental General Purpose Tannin-Stain Resistant
Water-Base Primer Using Halox Xtain A
................
133
...............
Contents and Subject Index xiii
Experimental High Performance Tannin-Stain Resistant
Water-Base Primer Using Halox Xtain A
................
Experimental Waterbase Acrylic Red Iron Oxide Primer ........
135
Exterior House Paint Primer
............................
138
Exterior House Paint Primer Based on Ucar Latex 163
.........
139
General Purpose Latex Maintenance Primer .................
140
General Purpose/Low Cost Water-Base Primer ............... 141
High Performance Bare Metal Primer
......................
142
High Performance Galvanized Metal Primer
.................
143
High Performance 2K Water-Base Epoxy Primer 144
Halox SZP-391
..................................
145
High Solids Red Iron Oxide Epoxy Primer
..................
147
House Paint Primer
...................................
148
Lead and Chromate Free Primer
..........................
149
Lead and Chromate Free Red Iron Oxide Primer
..............
150
Lead and Chromate Free Waterborne Epoxy Primer
...........
151
Lead Based Primer
...................................
152
Lead Silico Chromate Primer
............................
153
Low Sheen Gray Primer ............................... 154
Non-Lead/Non-Chromate Primer ........................
155
134
.............
High Performance 2K Water-Base Epoxy Primer Using
Primer for Factory-Primer Hardboard Siding
................
156
Primer 20323D Based on Phosguard J-0853 and 10 ES
Wollastocoat Henkel's Waterpoxy 1401:701 System
........
157
Primer 203236 Based on Phosguard J-0813 and 10 ES
Wollastocoat Henkel's Waterpoxy 1401:701 System ........ 158
Primer 20596F Based on Heucophos ZPZ and 10 ES
Wollastocoat Henkel's Waterpoxy 1401:701 System
........
159
Primer 20596G Based on Heucophos ZMP and
10
ES
Wollastocoat Henkel's Waterpoxy 1401:701 System
........
160
Primer 21102E Based on Molycoat 212 and
10
AS
Wollastocoat Henkel's Waterpoxy 1401:701 System
........
161
Primer 21105H Based on Phosguard J-0815 and 10 ES
Wollastocoat Henkel's Waterpoxy 1401:702 System
........
162
Primer 211051 Based on Nalzin 2 and
10
ES
Wollastocoat Henkel's Waterpoxy 1401:702 System
........
163
Primer 21109C Based on Strontium Chromate and
10
ES
Wollastocoat Henkel's Waterpoxy 1401:702 System
........
164
Rapid Dry Waterborne Epoxy Primer
......................
165
Red Inhibitive Maintenance Primer
.......................
167
Red Iron Oxide Corrosion Resistant Epoxy Primer (Two
Component System) ............................... 168
Red Iron Oxide Primer ................................ 169
Red Iron Oxide Water Reducible Alkyd Primer
...............
171
xiv Contents and Subject Index
Rust Inhibitive Chromate Primer
.........................
172
Solvent Resistant. Water-Reducible Epoxy Primer
............
173
lT-P-1975 Federal Specification Metal Primer
..............
174
Universal Primer
.....................................
175
Universal Primer Non-Lifting and High Salt Spray Resistance
....
176
Water-Base Acrylic Universal Primer Using Halox
Water-Base Acrylic Universal Primer Using Halox
SZP-391
&
Xtain A
...............................
178
Waterborne Black Iron Oxide Primer Based on
Epotuf 37-143/37-680 (Formula
No
.
3019-38A)
..........
179
Waterborne Red Iron Oxide Primer Based on
Epotuf 37-143/37-680 (Formula
No
.
2954-76A)
..........
180
Waterborne Red Oxide Epoxy Primer
......................
181
Waterborne Yellow Iron Oxide Primer Based on
Epotuf 37-143/37-680 (Formula No
.
3019-39B)
..........
182
Water Reducible Alkyd Yellow Iron Oxide Primer
Using Halox SZP-391
.............................
183
Water Reducible Alkyd Yellow Iron Oxide Primer
Using Halox CW-491
..............................
184
Water Reducible Epoxy-Ester Red Iron Oxide Primer
..........
185
Water Reducible Epoxy-Ester Red Iron Oxide Primer
Using Halox CW-491
..............................
187
White. Corrosion Resistant Latex Primer
...................
188
White Inhibitive Maintenance Primer
......................
189
SZP-391
&
BW-100
..............................
177
SECTION
IX:
SEALANTS AND
RELATED
COMPOUNDS
......
190
Ancamide 2353 Curing Agent Aluminum Mastic
..............
191
Clear Sealant
.......................................
192
High-Quality Exterior Latex Caulk
.......................
193
Patching Compound (Brushing Grade)
.....................
194
Patching Compound (Trowel Grade)
.......................
195
Pigmented Caulk Formulation based on 2:l Vinyl
AcrylidAcrylic Blend
..............................
196
Premium.Performance. Medium-Flexibility
Caulk
............
197
Sealant Application
...................................
198
Translucent
Caulk
Formulation
..........................
199
ASTM C-920 Pigmented
Caulk
Formulation
................
200
Translucent Sealant
...................................
201
Vinyl Acrylic Sealant
.................................
202
Weather-Barrier Mastic
...............................
203
SECTION
X:
STAINS
...................................
205
Brown Wiping Stain
..................................
206
Contents and Subject Index
xv
Interior Wiping Stain (Emulsion E-2977)
...................
207
Light Redwood Wiping Stain
............................
208
Stain Concentrate
....................................
209
Tannin Stain Blocking Formulation
.......................
210
Acrylic Tannin Stain-Blocking Primer
.....................
210
Water Reducible Redwood Solid Color Stain
................
211
Stain
.............................................
207
SECI'ION
XI:
MISCELLANEOUS
.........................
212
Anquamine 401 Clear Coat Semi-Solid Epoxy Dispersion
.......
213
Anquamine 401 Clear Coat Solid Epoxy Dispersion
...........
214
Anquamine 401 Liquid Epoxy Clear Coat
...................
214
Aqueous Polyester-Urethane Pigment Dispersion
.............
215
Black Gloss Enamel
..................................
216
Clear Barriernie Coat for Vinyl
.........................
216
Clear Tint Base
.....................................
217
Clear Waterborne Cement Sealer
......................
218
Waterborne Black Topcoat
.............................
218
Exterior/Interior Block Filler
............................
219
High
Solids Self Priming Alkyd
..........................
220
Masonry Block Fill
...................................
221
Masonry
Blockfill
....................................
222
Water Reducible Alkyd
................................
223
2-Component Waterborne System
........................
224
FCA's
for
Waterborne Building Product Formulations
SECTION
XII:
TRADE NAMED RAW MATEWS
...........
225
SECTION
XIII:
SUPPLIERS ADDRESSES
..................
246
2
Water-Based Paint
Formulations
Acrylic
Eaulsion/Urea-Formaldehyde
Wood
Clearcoat Modification
K-Flex UD-320W is an aliphatic, saturated, water soluble resin
modifier. This urethane diol modifying resin imparts improved
stain resistance to the forced dry (thermoset) wood clearcoat
formul at
i
on bel ow.
What makes this formulation unique, is the absence of neutral-
izing amines. As a result, a free acid catalyst may be used
(Nacure 155) and lower temperature cures may be achieved. A pot
life
of
24-48 hours is possible.
WB Wood Clearcoat
Component:
Beetle 65
Methanol
Silwett
L-77
Rhopl ex AC-1024
Water
Exxate
700
Chemcor AS-35-3
K-Flex UD-320W
Nacure 155
Methanol
Modification:
0%
24.5
2.4
0.4
49.2
7.2
1.4
4.1
0.0
4.9
5.9
%K-Flex UD-320W
-
5%
10%
24.5 24.5
2.4 2.4
0.4 0.4
44.2 39.3
9.4 11.5
1.4 1.4
4.1 4.1
2.8
5.5
4.9 4.9
5.9 5.9
Formulati on Procedure:
1. The components were added in the order as presented, for
easi er
i
ncorporati on.
2. The Nacure 155 catalyst was pre-diluted with the methanol
below
it
in the formulation before incorporation,
with
a
Nacure 155/Methanol ratio
of
45.5/54.5.
Substrate: Birch Faced Plywood
Sealer: Self Sealed (2 Coats, 2 bakes)
Sealer/Topcoat, WFT: 20-25u (0.8-1.0 mil)/Coat
Sealer/Topcoat Bake: 10 min./71C (160F)
4 Hour Spot Test
Stain Test:
0%
UD-320W 10% UD-320W
Acrylic/UD-320W/B-65 50/0/50 40/10/50
Coffee Severe Haze Light Stain
Milk Severe Haze
No
Effect
Mustard
Water
Lemon Juice
No Effect Light Stain
Severe Haze
No
Effect
Slight Haze
No
Effect
No
effect was seen in the 4 hour spot test
in
any of the
formulations
with
ketchup, nail polish remover, isopropanol,
liquid cleaner or lipstick.
160F resulted in an
H
pencil hardness and 100+ MEK double rubs.
SOURCE: King Industries: Formulation WR-26
Drawdowns made over Aluminum panels and baked 10 minutes at
Coatings
and
Topcoats
3
Aliphatic
Wood
Coatinn Formulation
JSancure 825/Rho~lex CL-104)
61 end
:
Rhoplex CL-104 (38% Solids)
Water
Add following with good agitation:
Dowanol
DPM
Hexyl Carbitol
Mix 10-15 minutes
Sancure 825 (34% Solids)
Surfactant Package (Premix the following):
Surfynol 104H
Surfynol DF-l1OL
Mineral Spirits
Surfynol
DF-70
DC-14
Add and mix 30 minutes
Pounds
134.2
33.8
12.75
2.55
100.0
2.6
1.3
1.3
1.3
0.7
Adjust to desired viscosity using Acrysol RM825 (Rohm
&
Haas
Co.)
If
required, flow
is
enhanced by addition of very low levels
of
Fluorad FC-129 (3M Corp.) as a 10% solution in water.
NOTE: Avoid excessive use of fluorocarbons, as sharp surface
tension drops can cause recoat problems and strong foaming
tendencies.
Always adjust to desired viscosity range prior to evaluating
flow/level and deaeration properties. Low viscosity can
yield “Picture-Framing‘‘ and/or a
“Fi
sh-Eye“ effect. High
viscosity can yi el d poor deaeration properti es.
Surfynol additives have been shown to provide the following
benef
i
ts
:
*Color uniformity
of
stains
*Early stain
1
appi ng resistance
*Consistent wetting, flow and leveling
on
various woods
*Foam control
With
no
detrimental effect upon:
*Topcoat recoatability and intercoat adhesion
*Gloss retention upon aging
*Tannin bleed resi stance
*Water sensitivity
*Chemical resistance
SOURCE:
Air
Products
&
Chemicals, Inc.: Surfynol Surfactants:
Formulation
A
(B.F.
Goodrich)
4
Water-Based Paint Formulations
Ancamine
2410
High Solids Coating
A
Side:
DER 331
TS
610
50%
FC430 in Xylene
Disperse, then reduce speed
Stainless steel flake
BYK
320
Aromatic
100
B
Side:
Ancami ne 241
0
Ethyl Alcohol
Dissolve, then add:
Cabosil
TS
720
Wollastocoat 10ES
Disperse to
6
n.s.u.
Methyl Ethyl Ketone
Typical Properties:
Non Volatile by Weight: 0.75
Non Volatile by Volume:
0.60
PVC:
0.16
CPVC:
0.34
PVC/CPVC:
0.48
Pi
gment Content: 0.30
NVV
on Vehicle: 0.64
VOC
g/1: 327.9
VOC
lbs/gal
:
2.74
&
330.9
7
3.5
176
79
7.1
150.5
37.7
8.8
133.3
152.3
Wei ght/Gal lon Comp
A:
Weight/Gallon Comp
0:
Mixinq Ratio:
1:l
Gals
34.1
0.4
0.4
3.2
1
10.9
15.5
5.8
0.5
5.5
22.7
12.06
9.65
Weight per Gallon:
10.85
Initial Viscosity:
580
cP
Pot Life: 4.5 hr
Dry to Touch: 0.75 hr
Dry Hard:
4
hr
Ancamine 2410 Chemical Resistance: 7 Day Immersion Results:
Reagent
:
Acetone
Cyclohexanone
PM
Acetate
Ethyl Acetate
Ethanol
Isodecanol
Aromatic
100
To1 uene
DMF
TH
F
EP
Result:
No Effect
No
Effect
No Effect
No Effect
No Effect
No Effect
No Effect
No Effect
No Effect
No Effect
No Effect
Reagent:
NMP
C1 orox
S
kyd
r
o 1
50%
caustic
10%
caustic
6% HC1
:
Sulfuric:
Acetic Acid
Diethyl ami ne
50%
phenol in xylen
Result
:
No Effect
No
Effect
No Effect
No
Effect
No Effect
No Effect
81
i
stered
81
i
stered
Blistered
0
1
ieD04
SOURCE:
Air
Products and Chemicals, Inc.: Ancamine
2410
Curing
Agent: Exhibit
3
Formulation
Coatings
and
Topcoats
5
Exhibit
4
-
Starting Formul-ation
Ancarni
ne
241
O/Ancami de
500
High.
Sol
ids
Coating
A
Side:
DER
331
Cabosil
TS-610
Lbs Gals
284.6 29.3
7.6 0.43
Disperse at High Speed
Reduce Speed, then add:
A1 umi num
L243 106 8.59
When uniformly mixed, add:
Epodil
759
SF
69
B
Side:
Ancami ne
241
0
Beetle
216-8
Ancamide
500
Ethyl Alcohol
Methyl Ethyl Ketone
nButyl Alcohol
Ethyl Alcohol
Typical Properties:
Non Volatile by Weight:
0.72
Non Volatile by Volume:
0.64
PVC:
0.056
CPVC:
0.31
PVC/CPVC:
0.17
Pigment Content:
0.09
NVV
on Vehicle:
0.7
VOC
g/l:
290.53
VOC
lbs/gal:
2.43
86.3 11.64
0.3 0.04
77.67 8.00
22.7 2.60
81.8 10.34
29.1 4.44
73.9 11.01
81.7 12.10
9.8 1.49
Weight/Gallon Comp
A:
9.68
Weight/Gallon Comp
0:
7.53
Mixing Ratio:
1:l
Weight per Gallon:
8.61
Initial Viscosity:
270
CP
Pot Life:
3
hr
Dry to Touch:
1.5
hr
Dry Hard:
4
hr
Corrosion Resi stance
:
Exhibit
4
is a prel
i
mi
nary starting formulation combi ni ng
Ancamine
2410
curing agent with Ancamide
500
curing agent as the
B
side. Corrosion resistance is very good. Cleveland humidity
testing showed no attack after
700
hours. Salt spray results
on grit blasted steel showed no attack in the field and minor
attack at the scribe
(8
rating) after
700
hours.
SOURCE:
Air
Products and Chemicals, Inc.: Ancamine
2410
Curing Agent: Exhibit
4
6
Water-Eased Paint Formulations
Black Single Coat K-Flex-XM-4316 PU-D~sperslon Cured
with
HMMM
Formulation WR-40 is a high performance high gloss black
formulation based on K-Flex XM-4316 polyester-urethane dispersion
crosslinked with an amino resin. The formulation offers a high
gloss coat
i
ng
Component:
Pigment Grind Paste, Part
1:
K-F1 ex XM-2311
Water, deionized
Dimethylethanolamine (1)
Monarch 1300
K-Sperse 152
MS
Dimethylethanolamine (2)
Pigment Paste, Part
2:
K-Flex XM-2311
K-F1 ex XM-4316
Water, deionized
Pigment Paste
K-F1 ex XM-4316
Water dei oni zed
Resimene 747
Nacure 2547
Silwet L7604/L7605 (1:l) 25% in H20
Water as required for viscosity adjustment
Formulation Characteristics:
Resi n/HMMM, rat1
0:
75/25
Nonvolatile, calculated,
'YO:
39.0
Theoretical
VOC,
g/L, (lb/gallon): 145, (1 .23)
Brookfield Viscosity, 25C, spindle #16, 60 rpm, cp.:
Cure Schedule, temperature, time: 150C,
15
minutes
Dry Film Thickness,
mil,
(micron):
1.0
(25)
Gloss, 60, 20,
90:
91,
81
pH: 7.8-8.3
Film Properties: Substrate, aluminum
%Wt
2.40
2.95
0.15
1
.oo
0.07
0.10
1.20
1.20
1.10
10.17
63.95
6.20
9.55
0.13
0.40
9.60
300-500
Formulation Notes:
Pigment Grind Paste Part
1:
Blend the K-Flex XM-2311 polyurethane
dispersant resin with water and dimethylethanolamine (1) and add
the carbon black, premix and add the blend of K-Sperse with
dimethylethanolamine (2), check the pH and add more dimethyletha-
nolamine
if
pH
is
below 9.2, disperse in a steel ball
mill
to
Hegman
NS
8 rating.
Pigment Paste Part
2:
After grinding in the steel ball
mill
add
the additional K-Flex XM-2311, XM-4316 and water to the ball
mill,
run for an additional 30 minutes. The pigment concentrate
is stable. After longer aging addition of small amounts of amine
for pH adjustment might be required.
Letdown Formula: Let the pigment paste down under agitation
with remainder of K-Flex XM-4316, water, melamine crosslinker
and catalyst. Add the silicone surfactant and use the remainder
of the water for viscosity adjustments. Final
pH
of
the formula-
tion should be between
7.8
to 8.3.
SOURCE:
King Industries: Preliminary Formulation WR-40
Coatings
and
Topcoats
7
Clear
Bake
Coating
Materi a1
:
Epi
-Re2 3522-W-60 Resin
~___
Pounds Gal 1 ons
637.50 69.29
Thoroughly pre-nix the following and add to the above under
gentle agitation.
Cyme1 324
Butyl Oxitol Glycol Ether
2-Propoxyethanol
BYK-301 Anti-cratering agent
Syntex 3981 Accelerator
53.10 5.71
22.50 3.00
40.20 5.00
2.00 0.25
2.75 0.37
Blend thoroughly. Dissolve following by warming to 150F.
Add to above under agitation before allowing to cool.
Oi
cyandi ami de
Dei oni zed water
Typical Coati ng Propert
i
es
:
%
Non-volatile
-
weight: 48.5
-
volume: 43.2
Viscosity: 57
K.U.
pH: 7.0
Pounds/Gallon: 9.05
Volatile Composition:
Water
Organics
Volatile Organic Compounds (VOC):
Pounds/Gallon: 1.46
Grams/Li ter
:
175
13.50 0.41
133.00 15.97
______
Pounds Gallons
388.0 46.50
62.7 8.00
Film
Properties:*
Bake Schedule: Pencil Hardness Reverse Impact, in.-lbs.
160
160
160
160
5 min. at 450F 4H
30
min. at 400F 5H
15 min. at 400F 5H
30 min. at 350F 4H
*
Films cast #42 Myra Bar (0.75
m
flash.
SOURCE:
She1
1
Chemical Co.
:
Start
Epi
-Rez
3522-W-60
Resin
1.) on bonderite 1000;
10
min.
ng Formulation
No.
2500:
8
Water-Based Paint Formulations
Clear Bake Coatinq
Materi a1
:
Pounds
Epi -Rez 3551 -WY-43 Resi n 756.0
Add under agitation:
Ektapro
EEP
Beetle
80
Water
Typical Coating Properties:
Total Weight Solids,
%:
47.5
Total Volume Solids,
%:
41.8
Pounds/Gallon: 8.96
Epoxy/Urea, based on solids
Volatile Organic Compounds
Pounds/Gal lon
:
1 .85
Grams/Li ter
:
222
Viscosity, Brookfield #5 Sp
Dry Film Thickness: 1.0
mil
Substrate: Bonderite 1000
Typical Film Properties:
21.2
86.8
31.5
%:
80/20
VOC)
:
ndle, 20 rpm, cps: 1,400
Gal lons
84.00
2.68
9.54
3.78
Bake Schedule at 350F, minutes: 20
Pencil Hardness: 3H
Reverse Impact, in. lbs.:
80
Starting Formulation No. 2501: Epi-Rez 3551-WY-43 Resin
Phenolic Clear Bake Coating
Pounds Gallons
Materi a1
:
Water 115.5 13.87
Methylon 75108 162.5 16.75
Butyl Oxitol Glycol Ether
48.8
6.50
n-Butyl Alcohol 43.9 6.50
Syntex 3981 Accelerator 58.1 7.90
Typical Coating Properties:
~~
Epi-Rez 3540-WY-55 Resin 442.9 48.48
Premix and add slowly under agitation:
Total Weight Solids,
%:
46.6
Total Volume Solids,
%:
31.0
Pounds/Gallon: 8.72
Epoxy/Phenolic: 60:40
Catalyst, active on resin solids,
%:
3.3
Volatile Organic Compounds
(VOC):
Pounds/Gallon: 2.68
Grams/Li ter
:
322
Viscosity, #4 Ford Cup, seconds: 40-60
pH: 6.4
Reduction for Conventional Spray Application: None
Dry Film Thickness: 0.4 mils
Substrate: Bonderite 1000
Bake Schedule: 15 min. at
450F
Pencil Hardness: 9H
Reverse Impact, in.lbs.: >I60
MEK
Resistance, double rubs: 100
Typical Film Properties:
Starting Formulation
No.
2502: Epi-Rez 3540-WY-55 Resin
SOURCE:
Shell Chemical Co.: Starting Formulations
Coatings
and
Topcoats
9
Clear Bake Coating
Materi a1
:
Epi -Rez 3540-WY-55 Resin
Water
Premix and add:
Beetle Urea Formaldehyde Resin
n-Butyl Alcohol
Syntex 3981 Accelerator
Pounds
579.6
113.7
80.7
43.2
55.9
Gal lons
63.42
13.65
8.92
6.40
7.61
Typical Coating Properties:
Total Weight Solids,
%:
45.7
Total Volume Solids,
%:
42.6
Pounds/Gallon: 8.73
Epoxy/Urea: 80/20
Catalyst,
%
(Active on resin solids): 2
Volatile Organic Compounds (VOC):
Pounds/Gal 1
on:
2.19
Grams/Liter: 263
Viscosity, #4 Ford Cup, seconds: 60-80
pH:
7.1
Starting Formulation
No.
2506: Epi-Rez 3540-WY-55 Resin
Phenolic Clear Bake Coating
Materi a1
:
Part
A:
Epi -Rez 3551 -WY-43 Resin
Premix and add under agitation:
Santol
i
nk
EP560
Ektapro EEP
Add under agitation:
Water
______
Pounds Gal 1 ons
662.1 73.56
93.1 10.18
80.6 10.16
50.8
6.10
Typical Coati ng Properti es
:
Total Weight Solids,
%:
42.0
Total Volume Solids,
%:
36.6
Pounds/Gallon: 8.87
Epoxy/Phenolic, based on solids, percent: 80/20
Volatile Organic Compounds (VOC):
Pounds/Gal 1
on:
2.90
Grams/Liter: 348
Viscosity, #4 Ford Cup, seconds:
70-80
Dry Film Thickness:
0.5
mil
Substrate: Bonderite
1000
Bake Schedule at 350F. minutes: 20
Pencil Hardness:
5H
Reverse Impact, in.lbs.: s160
MEK
Resistance, Double Rubs: 100
Typi cal Fi 1
m
Propert
i
es
:
Starting Formulation
No.
2505: €pi-Rez 3551-WY-43 Resin
SOURCE:
Shell Chemical
Co.
:
Starting Formulations
10
Water-Based Paint Formulations
Clear
Wood
CoatinQ-A
&
B
8
C
_-
K-F1 ex
UD-320W
Modi
f
i
ed
The following wood coating formulation evaluates K-Flex
UD-320W at 5 and 10% modification on solids. The system was
catalyzed with K-Cure 129W. Cure response was examined on
clean bare and 840 treated Aluminum at a rapid schedule of
60
sec./82C. Hardness improvements were found at all levels of
modification (See
film
properties). The treated substrate gave
softer films initially compared to bare metal,
but
improved
properties were observed after 24 hours aging. K-Flex UD-320W
modification increased
film
hardness but did not improve water
resistance properties
Formul ati on
:
Rhoplex AC-1024
Beetle 65
K-Flex UD-320W
K-Cure
129W
Acrylic/Polyol/Urea
%
Solids
Film
Properties:
FC-430
Substrate: Aluminum (Clean Bare)
Cure:
60
sec./82C
Film Thickness: 0.7+-0.1
mil
DFT
W*
66.7
33.3
0.0
0.13
1.7
SO/-/50
66.7
A:
50,’-/50
Initial
24 Hours
0:
45/5/50
Initial
24 Hours
C:
35/10/55
Initial
24 Hours
Penci 1 KHN25
HB-F 4.19
F-H 11.20
HB-F 6.25
H-2H 14.20
HB-F 5.41
H-2H 15.50
W-
Wt%C
61
.8
51.4
34.3 40.4
3.9 8.2
0.13 0.13
1.7
1.8
45/5/50 35/10/55
67.5
72.2
Crosshatch
Adhesion
MEK
Rubs
(%Loss)
200
0
200
0
200
0
200
0
180
0
200
0
SOURCE:
King Industries: Formulation UDW-10
A
&
B
&
C
Coatings
and
Topcoats
11
Ingredients:
Resin Phase:
Water
Maincote PR-71
Ammonia (28)
Direct to Metal Acrylic Latex Coating
Startina Point Formulation
Lbs
Gals
45.9 5.510204
2.05 0.273333
481.2 55.31034
Set aside for later addition, into a separate vessel add:
Water Phase:
Water
Bentone
AD
Tamol 165
Drewpl us L-493
Butyl Cel losolve
Dibutyl Phthalate
Ammonia (28)
Premix:
Chrom. Grn. Oxide 5-5310
Actirox 215
Nyad 1250
Disperse to
5
n.s.u. Then
homogenization, add, whi
Ethyl Alcohol
15%
NaN02 in Water
20% QR-708 in Water
150
1.4
11.2
1
36.6
7.3
n
47.9
89.8
116.3
let down with resin phase
e
mixing, the following:
18
3.06
12.75
18.00720
0.064641
1.222707
0.133155
4 .a73501
0.8371 55
0.4
1.078828
3.368847
4.805785
4fter
2.748091
0.337375
1
.514251
General Performance Benef ts:
Excellent adhesion to steel, galvanized steel and aluminum
Suitable for single coat service
Excel 1 ent recoatabi 1
i
ty with solvent based finishes
High resistance to salt spray, 3000 hours from 2 dry mils on
Appl
i
cab1 e under margi nal conditions (40F)
cold rolled steel
SOURCE:
Nyco Minerals, Inc.: Suggested Formulation
12
Water-Based Paint Formulations
Low
Gloss
Vinvl/ABS
Topcoat
Materi a1
Spensol L53
Di
sperse-Ayd
Surfynol 104H
Fl
att
i
ng Agent TS100
Lodyne S107B
Lbs.
Gals
.
808.7 92.85
6.6
0.75
6.0
0.75
25.0
1
.so
1.4 0.15
Disperse at high speed for 15-20 minutes, then premix and add:
Mi
cheml ube 737
Water
Anal ysi
s:
Percent Sol ids, Weight
:
31
.8
Percent Solids, Volume: 28.4
Viscosity
@
25C, #2 Zahn, Secs.: 20-25
Gloss (60/20): 7/4
VOC
(excluding water):
Grams/Li ter
:
288
Pounds/Gal 1 on
:
2.4
pH: 8.0-8.5
Formulation 2124-54C
16.4 2.0
16.7 2.0
Clear Topcoat
for
Flexible Substrates
Materi a1
:
Spensol L53
Surfynol 104H
Colloid 679
Ucar
SCT
100
Mi
cheml ube 737
Water
Lbs.
Gals.
826.5 95.00
4.0
0.50
1.9 0.25
2.3 0.25
16.4 2.00
16.7 2.00
Add the above materials in order under good agitation.
NOTE: An optional aziridine crosslinking agent can be added to
the above formula at a level of 7-10 lbs./100 gallons.
Analysis:
Percent Sol ids, Wei ght
:
29.8
Percent Solids, Volume: 28.6
Viscosity
@
25C,
#4
Ford, Secs.: 65+-5
Pounds/Gallon: 8.7
VOC
(excluding water):
Grams/Liter: 374
Pounds/Gallon: 3.1
PH:
8.5t-0.3
Formulation 2307-248
SOURCE:
Reichhold Chemicals, Inc.
:
Spensol
L:
Formulations
Coatings
and
Topcoats
13
Strippable Coating Sample Formulation A
_____
Unmodi
f
i
ed
I
nnredi ent
s
:
Ucar Latex 447
Ucar Filmer IBT
Foamaster VF
Water
Coating Properties:
AMP-95
Viscosity, cP: 1060
Stormer Viscosity,
KU:
70
pH Value: 6.6
Total Solids,
%
by weight: 59.3
Pounds
797.3
2.1
47.5
2.1
40.9
Strippable Coatinq Sample Formulation B
-
Lower
-
Adhesion
Inqredients:
Ucar Latex 447
AMP-95
Ucar Filmer IBT
Foamaster VF
Soya Lecithin
Water
Coating Properties:
Viscosity, cP: 1820
Stormer Viscosity,
KU:
83
pH
Value: 6.7
Total Solids,
%
by weight: 60.3
Substrate Strippabi 1
ity:
Substrate:
Galvanized Steel
A1 -Bonderi te
A1 -A1 odi ne
Cold Rolled Steel
My1 ar
G1 ass
Polystyrene
Gloss A1 kyd
Polyester
X=peeled clean and easi ly
__~
Pounds
777.0
2.1
46.7
2.1
20.0
41.1
Gallons
88.54
0.27
6.01
0.27
4.91
Gallons
86.33
0.27
5.91
0.27
2.29
4.93
Formula
A
X
X
X
X
X
X
X
X
X
Formula B
X
X
X
X
X
X
X
X
X
SOURCE: Ucar Emulsion Systems: Ucar Latex 447: Formulations A
&
B
14
Water-Based Paint Formulations
Strippable Coatina Formulations
Thickened
with
Ucar Polyphobe Rheology Modifiers
Formula
C
Good Leveling Pounds Gal lons
Ingredients:
Ucar Latex 447 780.9 06.77
AMP-95 4.4 0.57
Ucar Filmer IBT 46.8 5.95
Foamaster VF 2.1 0.28
Water 40.6 4.89
Ucar Polyphobe 107 13.4 1.54
~~
Coating Properties:
Viscosity, cP: 2500
Stormer Viscosity,
KU:
104
pH Value: 8.1
Total Solids,
%
by weight: 60.1
Formula
D
High Build
Ingredients:
Ucar Latex 447
Ucar Filmer IBT
Foamaster VF
Water
Ucar Polyphobe 102
Coating Properties:
AMP-95
Viscosity, cP:
3200
Stormer Viscosity,
KU:
84
pH Value: 8.9
Total Solids,
%
by weight: 58.8
Substrate Strippabi 1
i
ty:
Substrate:
Galvanized Steel
A1 -Bonderi te
A1 -Alodi ne
Cold Rolled Steel
Mylar
G1 ass
Polystyrene
Gloss Alkyd
Polyester
X=peeled clean and easily NT=not
~~
Pounds Gal 1 ons
702.7 06.97
4.8 0.62
46.9 5.94
2.1 0.27
40.6 4.07
11.6 1.33
Formula
C
Formula
D
X
X
X
X
NT
NT
X
X
X X
X X
NT
NT
X
X
NT
NT
tested
SOURCE:
Ucar Emulsion Systems: Ucar Latex 447: Formulations
Coatings
and
Topcoats
15
Strippable Coatinq for Plastic Substrates
Inqredients:
Premix
#1
:
Ucar Vehicle
441
Defoamer
(1
)
Soya Lecithin
(2)
Premix
#2:
Tri octyl Phosphate
Stripping
Aid
(3)
Water
Premix
#3:
Thickener
(4)
Water
Premix
#4:
Triethylamine
Isopropanol,
91%
Water
Water
Pounds
603.8
9.1
10.1
40.2
13.9
39.2
27.1
27.2
7.2
8.6
14.3
48.3
Gal lons
Wt%
69.80 71.12
1
.31 1.07
1.16
1.19
5.22 4.74
1.47 1.64
4.71 4.62
3.10 3.19
3.26 3.20
1.18
0.85
1.27
1.01
1.72
1
.68
5.80 5.69
iers:
)
Defoamer
-
Patcote
513
(Patterson Chemical) or equivalent.
)
Soya Lecithin
-
Kelecin
1081
(Spencer Kellogg) or equiv-
a1 ent
.
equivalent.
(3)
Stripping Aid
-
Strodex PK-90 (Dexter Chemicals) or
(4)
Thickener
-
Acrysol ASE-60 (Rohm and Haas) or equivalent.
Procedure:
Blend Premix
#1
first, in the order shown, and then add the
remaining Premixes in numerical order. Allow five to
10
minutes
of agitation between additions of Premixes. The last increment
of water, shown below Premix
#4,
can be added in stages to allow
proper agitation.
Coating Properties:
Total Solids,
%
by
wt:
40.1
pH:
8.6
Viscosity, Brookfield, cP:
2410
Viscosity, Stormer, KU:
84
Heat-Age Stability,
2
wk at
12OF:
Pass
Freeze-Thaw Stability,
3
cycles: Pass
SOURCE: Ucar Emulsion Systems: Ucar Vehicle
441:
Formulation
Suggestion
LP-1924
16
Water-Based Paint Formulations
Stri ppable Coati
nq
Formulations
I
n
q
red
i
en t-s
:
Ucar Vehicle 441
Thickener (1) (11%
N.V
)
Butyl Carbi to1 Sol vent
Water
Coating Properties:
Weight per Gallon, lb: 8.6
pH
8.0
Total Solids,
%
by
wt:
43.8
Formul at
i
on LP-3760
Ingredi entg:
Ucar Vehicle 441
Thickener (1)
(11%
N.V.)
Butyl Carbi to1 Solvent
Soya Lecithin
Wetting Agent (2)
Water
Coating Properties:
Weight per Gallon, lb: 8.6
pH:
8.0
Total Solids,
%
by
wt:
44.4
Formulation LP-3761
Ingredients:
icar Vehicle 441
Thickener (1) (11% N.V.)
Butyl Carbitol Solvent
Soya Lecithin
Wetting Agent
(2)
Water
Coating Properties:
Weight per Gallon,
lb:
8.6
pH: 8.0
Total Solids,
%
by
wt:
44.6
Formulation LP-3762
Ingredients:
Ucar Vehicle 441
Thickener
(1)
(11% N.V.)
Butyl Carbi to1 Solvent
Soya Lecithin
Wetting Agent
(2)
Water
Coating Properties:
Weight per Gallon, lb: 8.6
pH: 8.0
Total Solids,
%
by
wt:
45.0
Formulation LP-3763
~-
Pounds
840.0
5.4
8.4
10.0
-~
Gal 1 ons
97.1
0.7
1
.o
1.2
Pounds Gal 1 ons
830.0 95.9
5.4 0.7
8.4 1
.o
6.6 0.8
3.3 0.4
10.0 1.2
Pounds Gallons
827.0 95.6
5.4 0.7
8.4
1
.o
10.0 1
.I
3.3 0.4
10.0
I
.2
Pounds Gal 1 ons
820.0 94.8
5.2
0.6
8.2 1
.o
16.4 1.9
3.3 0.4
10.7 1.3
Suppl
i
ers
:
(1) Thickener
-
Acrysol G-110 (Rohm and Haas) or equivalent.
(2)
Wetting Agent
-
Interwet #33 (Interstab) or equivalent.
Note: Include a suitable preservative in each formula suggestion.
SOURCE: Ucar Emulsion Systems: Ucar Vehicle
441:
Formulations
Coatings
and
Topcoats
17
Topcoat for Pref
i
ni shed Hardboard Siding
Inqredients:
PiQment
Or4
nd:
Water
Tergitol Nonionic Surfactant
Tamol 731
Foamaster
VF
Ti
-Pure R-960
Nytal 400
Silcron G-601
Nuocide 960
Letdown
:
Ucar Vehicle 462
Cyme1 325
Arcosol ve
PP
Sol vent
Cycat 4040
Foamaster VF
CAO-1 Anti-Oxidant
Tinuvin 328
UV
Absorber
NP-10
Pounds
134.8
4.7
9.3
1
.o
174.4
46.5
46.5
4.5
Gal lons
16.2
0.6
1
.o
0.2
5.2
2.7
2.0
0.6
535.4 60.8
45.2 4.4
36.1 4.9
2.8 0.3
1.1 0.1
3.0 0.3
6.5
0.7
Paint Properties:
Pigment Volume Concentration,
%:
28
Crosslinker,
phr:
15
Cosolvent, phr:
15
Volume Solids,
%:
41
Weight per Gallon, lb: 10.6
SOURCE:
Ucar Emulsion Systems: Ucar Vehicle 462: Formulation
Suggestion
18
Water-Based Paint Formulations
Water-Borne
A1
kvd/Mel ami ne
Kood Clearcoat Modification
K-Flex XM-2304 is an experimental primary hydroxyl containing
aliphatic, saturated urethane resin modifier. This water-borne
alkyd/melamine wood clearcoat formulation demonstrates improved
stain resistance and flow/leveling using this product.
%K-Flex XM-2304
Component:
0%
5%
10%
Cargill 7412
Resimene 747
Isopropanol
Water
K-Flex XM-2304
Nacure 155
K-F1 ex XM-2304:
%
Solids (Calculated)
Wetting
Alkyd/XM-Z304/HMMM
31
.5
28.3 25.1
31
.5
31.5 31.5
14.8 14.8 14.8
15.7
15.6 15.6
0.0
3.5 6.5
6.5 6.5 6.5
0%
5%
10%
66.6 66.5 66.4
50/0/50
45/5/50 40/10/50
Poor Good Best
Substrate: Sanded and Sealed Birch Faced Plywood
Sealer
:
Commerci a1 Vinyl Sander/Sealer
Topcoat, WFT: 20-25u (0.8-1.0 mil)
Topcoat Bake:
10
min./71C (160F)
4 Hour
Spot
Test
Stain Test
Mustard
Ketchup
Coffee
Homog. Milk
Lemon Juice
Liquid C1 eaner
Nail Polish Remover
0%
XM-2304
Mild
Attack
Stain
Severe Stain
Severe Attack
Mild Attack
Severe Attack
Severe Atack
5%
XM-2304 10% XM-2304
Mild Attack No Effect
No
Effect
No
Effect
Mild Stain Mild Stain
Mild Attack Mild Attack
Mild Attack No Effect
Severe Attack/Mild Attack
No Effect
No
Effect
While all 3 formulas were unaffected in the 4 hour spot test
by
bleach and mineral oil, they all exhibited a mild attack by
Peps1 Cola; staining from water; and a severe attack from
isopropanol
.
With the above cure condition all three formulas gave an
H-2H pencil hardness and 100+
MEK
double rubs at 23 u
(0.9
mi
1
)
on A1 umi num.
SOURCE:
King Industries: Formulation WR-24
Coatings
and
Topcoats
19
Water-Borne Alkyd/Melamine
Wood Clearcoat Modification
K-Flex UD-320W
is
an aliphatic, saturated, water soluble
resin modifier. This urethane diol modifying resin imparts
stain resistance to the forced dry (thermoset) alkyd/melamine
wood clearcoat formulation below.
What makes this formulation unique is the absence of neutral-
izing amines.
As
a result, a free acid catalyst may
be
used
(Nacure
155)
and lower temperature cures may be achieved. The
binder resin (alkyd) is water dilutable with the addition of
a cosolvent such as isopropanol.
A
pot life of 8-10 hours is
possible.
WB Wood
C1
earcoat -Modi
f
i
cation
Component:
Cargill 7412
Resimene 747
Isopropanol
Water
K-F1 ex UD-320W
Nacure 155
K-Flex UD-320W:
%
Sol
ids (Calculated)
A1 kyd/K-F1 ex UD-32OW/HMMM
%
K-Flex UD-320W
0%
5%
10%
31 .5 28.3 25.1
31
.5
31.5 31.5
14.8 14.8 14.8
15.7 15.4 15.0
0.0
3.5 7.1
6.5
6.5
6.5
0%
5% 10%
66.6
66.5 66.4
50/0/50 45/5/50 40/10/50
Substrate: Sanded and Sealed Birch Faced Plywood
Sealer
:
Commerci a1
Vi
nyl Sander/Seal er
Topcoat, WFT: 20-25u (0.8-1.0
mil)
Topcoat, Bake: 10 min./71C (160F)
Stain Test
Mustard
Ketchup
Coffee
Homog. Milk
Lemon Juice
Pepsi Cola
Nail Polish Remover
4
Hour Spot
Test
0%
UD-320W 5% UD-320W
Mild Attack
Mild
Attack
Severe Stain Severe Stain
Stain No Effect
Severe Attack No Effect
Mild Attack Severe Attack
Mild Attack
Mild
Attack
Severe Attack No Effect
10% UD-320W
No Effect
No Effect
Mild Stain
No
Effect
Severe Attack
No Effect
No Effect
While all 3 formulas were unaffected in the 4 hour spot test
by bleach and mineral oil, they all exhibited staining from water
and a severe attack from isopropanol and liquid cleaner
With the above cure condition all three formulas gave an H-2H
pencil hardness and 100+
MEK
double rubs at 23u
(0.9
mil)
on
A1 umi num.
SOURCE:
King Industries: Formulation WR-25
20
Water-Based Paint Formulations
Waterborne Clear
Hiqh
Gloss
Topcoat
Edaplan LA-402 was used in a Waterborne High Gloss Wood
Topcoat to improve wetting and leveling. In combination
with
Agitan 315 foam control agent, superior
film
properties are
ach
i
eved
.
Materi a1
:
&
Rhoplex E-3188 (Rohm
&
Haas) 608.00 71 .77
Water 101.33 11.96
Adjust pH to 8.5-9.0
Ammonia (28%) 5.27 0.62
Premix and add slowly:
Water
Dowanol PnB
(DOW
Chemical)
Arcosolve DPM (Arco Chemical)
Arcosolve DPt8 (Arco Chemical)
Tributoxyethyl phosphate
Add following while mixing:
FCA
(Foam Control Agent)
Wetting Agent
Michem 392-25 (Michelman)
Adjust vi
scosi
ty
Acrysol RM-825 (Rohm
&
Haas)
Water
Properties:
%
Nonvolatile (by weight): 31.2
%
Nonvolatile (by volume): 29.4
Weight per Gallon (pounds): 8.48
Theoretical
VOC
(grams/liter): 106
Viscosity (cPs): 150+-10%
14.79 1.75
14.79 1.75
14.79 1.75
9.93 1.17
9.93 1.17
0.49 0.06
2.47 0.29
14.11 1.67
0.51
0.06
50.67 5.98
SOURCE:
King Industries: WR-31: Additives for Waterborne Wood
Formulations
Coatings
and
Topcoats
21
White
Gloss
Maintenance Topcoat
Inqredi ents
:
Pigment
Gri
nd:
Methyl Carbitol Solvent
Water
Bentone LT
Ammonium Hydroxide, 28% Aqueous Solution
Tamol 681
Triton Nonionic Surfactant CF-10
Nuosept 95
DeeFo HG-12
Acrysol RM-2020
Acrysol SCT-275
Tronox CR-828
Letdown
:
Methyl Carbitol Solvent )Premix
Acrysol SCT-275
1
Ucar Vehicle 435
Ucar Filmer IBT
Troysan Polyphase AF-1
DeeFo HG-12
Sodium Nitrite, 15% Aqueous Solution
Ammonium Hydroxide, 28% Aqueous Solution
Adjust to minimum pH 8.7
Pounds
59.6
18.4
1
.o
1.8
18.2
2.2
2.3
1.9
17.2
8.6
225.0
8.5
8.6
626.9
15.8
4.9
1.9
9.0
1.8
Pai nt Properti es
:
Pigment Volume Concentration (PVC),
%:
18.3
Total Solids,
%:
pH Value, initial: 8.7
Viscosity:
Stormer,
KU:
78
ICI,
poise: 1.1
by volume: 36.1
Weight per Gallon, lb: 10.3
Freeze-Thaw Stability, 3 cycles: Pass
Heat Stability, 2 weeks at 140F: Pass
Film Properties:
Contrast Ratio, 6-mil wet drawdown: 0.958
Gloss, 60: 70
Gloss, 20: 25
Gal 1 ons
7.00
2.21
0.06
0.25
2.00
0.25
0.25
0.25
2.00
1
.oo
6.59
1
.oo
1
.oo
72.06
2.00
0.50
0.25
1.08
0.25
SOURCE: Ucar Emulsion Systems: Ucar Vehicle 435: Formulation
Suggestion M-2453
22
Water-Based
Paint
Formulations
White
Gloss
Topcoat
____
Materi a1
:
Arolon 580-W-42
Tamol SG-1
Triton CF-10
Colloid 694
Ethylene Glycol
Butyl Carbi to1
Dowicil
75
Water
Mix at low speed:
Titanox 2101
Grind under high shear 15-20 minutes.
Under low shear, add letdown.
Water
Col
loid 694
Arolon 820-W-49
Propylene Glycol
Butyl Carbi to1 Acetate
Cobalt Hydrocure
I1
Hydroxyethyl Cellulose QP-300 (10% Soln)
Ammonia
*lo%
QP-300 in Ethylene Glycol
Analysis:
Pigment Volume Concentration, Percent:
20.0
Pigment/Binder Ratio: 0.94/1
Percent Solids, Weight: 57.4
Percent Solids, Volume: 44.0
Viscosity
@
25C,
KU:
72-76
Pounds/Gallon: 11.08
VOC
(excluding water):
Grams/Li ter
:
144
Pounds/Gallon: 1.2
pH: 8.8-9.0
Lbs.
Gals.
65.0 7.30
5.0 0.52
3.0
0.34
2.5 0.35
23.0 2.48
10.0 1.26
1
.o
0.08
18.0 2.16
300.0
8.57
20.0 2.40
2.5
0.35
598.0 67.95
18.0 2.08
8.0
0.98
0.4 0.05
5.0 0.53
1
.o
0.13
SOURCE: Reichhold Chrmicals, Inc.: Arolon
820:
Formula
194-2
Coatings
and
Topcoats
23
Wood Topcoat Model Formulations
Rohm and Haas:
Wt%
Rhoplex WL-96 (42%) 73.9
Patcote 519 0.2
Butyl Carbi to1
)
6.2
Dowanol PNB
)
Premix 3.1
Michem Lube 110 (25% Solids) 2.9
Ammonia (14%) Adjust to pH 8.0 0.1
Water 13.6
S.C.
Johnson:
Wt%
Joncryl 554 90.9
Ektasolve
EB
3.6
Jonwax 26 4.5
Water 1
.o
Goodyear
:
Wt%
Ektasolve
EP
8.5
Santicizer 160 2.7
Diethyl ami ne 1.1
Drew L-475 0.2
Water 9.1
Pliolite 7104 (44%) 58.5
Wi
tcobond 234 19.9
Sanncor
:
Wt%
Water 16.1
Dowanol
DPM
4.9
Rhoplex WL-96 (42%) 35.3
Sancure 815 42.3
Dehydran 1293 0.5
BYK
306 0.5
Acrysol RM-825 0.3
Ammon
i
a
(
1 4%) Approx. 0.1
Evaluation in Clear Topcoats:
Surfynol 104 surfactant was evaluated in waterborne clear
topcoats to confirm its multiple benefits in actual wood
coating formulas. Since the most stringent performance require-
ments are related to high-end wood coatings. Model topcoat
formulations of this type were selected for study.
Surfynol 104 surfactant was added at 1% to the model topcoat
formulations.
In order to evaluate application and
film
property benefits,
Surfynol 104 surfactant's benefits include:
*Improved
f
1 ow and 1 eve1
i
ng
*Superior substrate wetting
*Low foam, and often defoaming performance
*Rapid di
spl
acement of ai
r
bubbles
*Mi
ni
mal resol ubi 1
i
zat
i
on
i
n water
SOURCE:
Air
Products
8
Chemicals, Inc.
:
Surfynol Surfactants:
Suggested Formulations
Coil
Coatings
25
Chromate Coi
1
-Coati
na
Primer
Ingredients:
Pigment Grind:
Dei oni zed Water
Ethylene G1 ycol
N,N-Dimethylethanolamine
Foamaster VF
Tergitol Nonionic Surfactant
NP-10
Polywet
ND-2
L-203-D Strontium Chromate
233 Basic Zinc Chromate
Ti
-Pure R-900
Letdown
:
N, N-Di
methyl ethanol ami ne
Ucar Vehicle 462
Carbi to1 Solvent
Arcosolve
PP
Solvent
Cyme1 303
Foamaster VF
Deionized Water
~___
Pounds Gallons
46.0 5.54
3.8 0.41
0.6 0.09
0.3 0.03
3.8
0.45
15.3 1.63
25.6 0.83
25.6 0.81
204.5 5.96
5.9 0.79
629.5 71.85
16.1 1.88
16.1 2.15
35.5 3.55
1.8 0.22
31.7 3.81
Wei sht%
4.33
0.35
0.06
0.03
0.35
1.44
2.41
2.41
19.25
0.56
59.26
1.52
1.52
3.42
0.17
2.92
Procedure:
order listed. Thoroughly mix liquid components before adding
pigments. Add pigments slowly and stir until uniform. Grind at
high speed for 10 minutes or until grind reaches about 50C.
For the letdown, add the ingredients in the order shown,
making sure the mix is uniform after each addition. For a less
critical procedure, premix filming aids with crosslinker and
water. Mix paint at least 10 minutes after the final addition.
Paint Properti
8s:
Charge the first six grind components to a Cowles mixer in
Pigment:Binder Ratio: 0.8:l
.O
Total Nonvolatiles,
%
by weight: 54.3
Resin
:
Me1 ami ne: 89; 1 1
Organic in Effluent,
%
by volume:
10
Viscosity, Brookfield, cP: 300
pH Value: 9
SOURCE: Ucar Emulsion Systems: Ucar Veh
Suggestion LP-3821
9
cle 462: Formulation
26
Water-Based Paint Formulations
Low-Sheen Coil-Coatinq Topcoat
Inqredi ents
:
Pigment
Gri
nd:
Ethylene Glycol
Polywet ND-2
Tergitol Nonionic Surfactant NP-10
Foamaster VF
N,
N-Di
methyl ethanol ami ne
Dei
oni zed Water
Si
lcron G-601
Ti
-Pure R-960 or Zopaque RCL-6
Letdown
:
Foamaster VF
Deionized Water
N,N-Dimethylethanolamine
Ucar Vehicle 462
Pigment
Gri
nd
Arcosolve
PP
Solvent
Cyme1 303
Procedure:
___~
Pounds Gallons
2.42 0.26
9.69 1.03
2.39 0.27
1.17 0.15
0.30 0.04
95.87 11.53
48.46 2.77
193.80 5.82
2.11 0.27
22.10 2.65
3.26 0.44
585.18 66.80
354.10 21.87
30.20 4.02
39.50 3.95
Weight%
0.23
0.93
0.23
0.11
0.03
9.25
4.68
18.70
0.20
2.13
0.32
56.47
34.16
2.91
3.81
Charge the first six grind components to a Cowles mixer tank
in the order listed. Mix at low speed for 5 minutes. Slowly add
the pigments and stir until uniform. Grind at high speed for
10 minutes or until grind reaches
50C.
blend into Ucar Vehicle 462 with slow agitation. Reduce the
pigment grind with the neutralized latex and stir at low speed
for
10
minutes. Add the melamine resin and solvent.
Stir
at
moderate speed for 10 minutes.
Paint Properties:
For the letdown, combine the antifoam, water, and the amine;
Pigment:Binder Ratio: 0.8:l
.O
Pigment Volume Concentration,
%:
19.7
Total Nonvolatiles,
%
by weight: 53.6
Organic in Effluent,
%
by volume: 10.5
Resi n:Mel ami ne: 87: 13
SOURCE:
Ucar Emulsion Systems: Ucar Vehicle
462:
Formulation
Suggestion
LP-3794
Coil
Coatings
27
Medium-Gloss Coil-Coating Topcoat
Ingredients:
Pigment Grind:
Ethylene Glycol
Tergitol Nonionic Surfactant
NP-
Foamaster VF
Polywet ND-2
N,N-Dimethylethanolamine
Deionized Water
Ti-Pure R-960 or Zopaque RCL-6
Letdown
:
Foamaster VF
Deionized Water
N,N-Dimethylethanol ami ne
Ucar Vehicle 462
Pigment
Gri
nd
Arcosolve
PP
Solvent
Cyme1 303
Deionized Water
Pounds
2.48
10 2.53
0.47
10.06
0.35
52.89
253.28
4.29
4.61
2.97
630.31
322.06
31.57
35.22
26.02
Gal 1 ons
0.27
0.29
0.06
1.07
0.05
6.36
7.61
Wei qht%
0.23
0.24
0.04
0.95
0.03
5.00
23.96
0.55
0.41
0.55 0.44
0.40 0.28
71.96 59.64
15.69 30.45
4.20 2.99
3.52 3.33
3.13 2.46
Procedure:
Charge the first six grind components to a Cowles mixer tank
in the order listed. Mix at low speed for
5
minutes. Slowly add
the titanium dioxide and stir until uniform. Grind at high speed
for 10 minutes or until grind reaches 50C.
For the letdown, combine the first increment of water, the
antifoam, and the amine; blend into the Ucar Vehicle 462 with
slow agitation. Reduce the pigment grind with the neutralized
latex and stir at low speed for
10
minutes. Add the remaining
water, melamine resin, and solvent.
Stir
at moderate speed for
10 minutes.
Paint Properties:
Pigment:Binder Ratio: 0.8:l
.O
Pigment Volume Concentration (PVC): 18.9
Total Nonvolatiles,
%
by weight: 53.1
Organic in Effluent,
%
by volume: 10.5
Resin:Melami ne: 89: 11
pH Value: 9
SOURCE: Ucar Emulsion Systems: Ucar Vehicle 462: Formulation
Suggestion LP-3793
28
Water-Based Paint Formulations
Ingredients:
Pigment
Gri
nd:
Di
spersant (1
)
Soya Lecithin (2)
Ethylene Glycol
Water
Defoamer
(3)
Calcium Carbonate (4)
Titanium Dioxide
(5)
Let Down:
Ucar Vehicle 441
Dispersant (1
)
Soya Lecithin
Defoamer (3)
Melamine (6)
Butyl Cellosolve Solvent
Thickener (7)
Blue Tint Paste (8)
Suo~l
i
ers:
Pounds
3.3
3.1
4.7
74.3
0.7
263.0
25.6
630.2
3.1
4.9
1.6
5.6
14.4
6.3
2.6
Gallons
0.33
0.33
0.50
8.93
0.09
11.69
0.73
72.86
0.31
0.53
0.20
0.56
1.92
0.73
0.29
Wei qht%
0.32
0.30
0.45
7.12
0.07
25.21
2.46
60.38
0.30
0.47
0.15
0.54
1.38
0.60
0.25
Dispersant
-
Strodex PK-90 (Dexter Chemical)
or
equivalent
Dispersant
-
Ross and Rowe 551 (Ross and Rowe Chemicals)
or equivalent.
Defoamer
-
Foamaster VF (Diamond Shamrock) or equivalent.
Calcium Carbonate
-
Atomite (Thompson, Weinman) or equiv-
alent.
Titanium Dioxide
-
Ti-Pure R-900 (duPont) or equivalent.
Me1 ami ne
-
Cyme1 350 (American Cyanamid) or equivalent.
Thickener
-
Acrysol G-110, 22% (Rohm and Haas) or equiv-
a1 ent
.
Aqueous Dispersion
-
Thalo Blue (Tenneco) or equivalent.
Procedure:
order listed. Mix at low speed for one minute. Slowly add pig-
ments and stir until uniform. Grind at high speed until desired
grind
f
i
neness has been accompl
i
shed.
For the letdown, pre-blend Ucar Vehicle 441, Strodex PK-90,
soya lecithin, and defoamer. With slow agitation, add to the
pigment grind.
Stir
at low speed for
5
to 10 minutes. Pre-blend
Butyl Cellosolve Solvent and melamine and add to let down.
Stir
for five minutes. Add blue tint paste and thickener and stir
for
5
to 10 minutes.
If
done slowly and carefullly, let down
Charge the first five components to a Cowles mixer tank in the
components may be added sequentially.
Coating Properties:
Nonvolatiles,
%:
54 to
55
pH:
8.0
Pigment/Binder Ratio: 1
.O
Viscosity at
25C
(Brookfield LVT, 60
rpm),
cP: 200
SOURCE:
Ucar Emulsion Systems: Ucar Vehicle 441: Formu
Suggestion LP-3024
o
300
ati on
30
Water-Based Paint Formulations
Acryl
i
c
Emu1 sion Enamel
-B&C
K-F1 ex
UD-320W
Modified
K-F1 ex UD-320W modi
fi
cat1 on
of
thi
s
white acryl
i
c/melami ne
emulsion for general industrial applications demonstrated several
advantages
i
ncludi ng: improved
f
low/level
i
ng, higher gloss,
improved gloss retention on
QUV
exposure-higher solids (lower
VOC)
and lower cost per pound on a solids basis.
Grind Composition:
Joncryl 540
Surfynol 104
Ti-Pure R-960
Water
(Grind to
6+
Hegman on the Ball
Mill)
Letdown Composition:
Gr
i
nd
Joncryl 540
HMMM
K-Flex UD-320W
Nacorr 1552
Water
Enamel Characteristics:
AMP-95
Viscosity, cps (25C): 200-205
Pigment/Binder Ratio: 0.76:l
.O
pH: 8.70-8.75
Q
41.8
1
.o
1
.o
48.6
7.6
Wt%-B
Wt04-&
100.0
100.0
50.9 39.1
19.9 29.1
3.6 7.2
1.3 1.3
23.0
25.0
Application and Cure:
Substrate: Bonderite 1000 (iron phosphated
CRS)
Cure Schedule: 15'/300F (150C)
DFT (mils): 0.9+-0.01 (22.5~)
Film Properties:
Acryl ic/K-Flex/HMMM:
Penci 1 Hardness
Knoop Hardness (259)
MEK
Resistance (2X)
Crosshatch Adhesion
Impact Resistance:
Direct (in lbs):
Reverse (in lbs):
C1 eve1 and Humidity (55C)
0
C
65/5/30 57/16/33
4H-5H 4H-5H
17.0 18.4
100
100
100% 100%
100-110 100-110
20-
30
20 -30
9/M 9/MD
SOURCE:
King Industries: Formulation
UDW-12
B
&
C
Enamels
31
Synergistic Effects
of
Combinina Nacorr
with
Anti-Corrosive Pinment
in
an Air
Dry
Water Reducible
A1
kyd
Modified Acryl
ic
Enamel
Improvements in the corrosion resi stance of a water reduci ble
air dry acrylic enamel are possible using Nacorr rust and corr-
osion inhibitors, When used in combination with a calcium stront-
ium phosphosilicate corrosion inhibiting pigment (Halox SW-1111,
a def
i
ni te improvement
i
n corrosion resi stance was obtai ned.
Salt spray testing was carried out over iron phosphated panels
(Bonderite 1000).
Grind:
Aquamac 1090
Nacorr
2-Butoxyethanol
Nytal 400
Halox SW-111
Raven Black 16
Hal
ox
Control SW-111
3.79 3.79
2.79 2.79
11.61 9.29
2.38
0.71 0.71
____
----
____
Letdown: (Add gradually while on
mill
at low rpm):
Cobalt Hydrocure 0.06 0.06
Manganese Hydrocure 0.08 0.08
Water 15.85 15.85
Ammonium Hydroxide, 30% 0.28 0.27
Aquamac 640 (post-add
8
shake) 64.83 64.80
Hal ox
Characteristics: Control SW-111
Pi
gment/Bi nder Ratio 0.4 0.4
Total Resin Solids,
%
by weight 32.0 32.0
Halox,
%
based on total paint weight
--
2.4
Film Properties:
Non-Volatile,
%
by weight 44.3 44.4
Nacorr,
%
based on total paint weight
--
__
Substrate: Bonderite 1000 Iron Phosphated CRS
Cure: 7 days at room temperature (22-23C)
Application: Spray
Film Thickness: 20-25 microns Hal ox
Formulation Test Procedure: Control SW-111
Penci 1 Hardness
Tukon Hardness, KHN25 2B-B 28-8
1.2 2.2
Haloxt
Nacorr
3.76
0.78
2.77
9.21
2.36
0.70
0.06
0.08
15.72
0.27
64.29
Haloxt
Nacorr
0.4
44.0
31.8
0.8
2.4
Hal ox+
Nacorr 1151
28-8
2.2
Crosshatch Adhesion,
%
removed
0 0 0
Salt Spray, 100 hours Light-med Very light No rust
Salt Spray, 310 hours Very Very Medi
um
rust rust
dense rust dense rust rust
The use of Nacorrs with the anti-corrosive pigment offered the
best corrosion results in this study. They had little or no
deleterious effect on other paint properties.
SOURCE: King Industries: Nacorr
WR-14
32
Water-Based Paint Formulations
Ancamide
2353
Fast Drvina White
Gloss
Enamel
Part
A:
Grind Base:
DER
660x80
(Dow)
Nuosperse
657
(Huls
America)
Beetle
216-8
(American Cyanamid)
Dowanol
PM
(Dow)
TiPure
R-960
(DuPont)
Let Down:
High Flash Naphtha (Ashland)
Methyl Propyl Ketone (Eastman)
Part 8:
Ancamide
2353
(Air Products)
n-Butanol (Ashland)
Propert
i
es
:
Part
A
Viscosity:
86KU
Part
B
Viscosity:
64KU
Mi
xed Viscosity
:
80KU
PVC:
15.2%
Vo
1
ume
SOURCE
Solids:
62.2%
-
Lb
472.55
3.54
2.84
47.26
307.16
73.72
14.18
131.44
34.78
VOC,
@
80KU: 2.8
lb/gal
Mix Ratio:
4:l
by Volume
Induction Time:
0
Pot Life, hr:
3
Dry Times:
Set to Touch, min:
50
Dust Free, min:
75
Hard Dry: Overnight
60
Gloss:
104
Gal
51.47
0.42
0.34
6.20
9.44
10.03
2.10
14.86
5.14
Air
Products and Chemicals, Inc.: Ancamide
2353
Curing
Agent: Table
12
Formulation
Enamels
33
Ancamide
2353
Low
VOC
White Gloss Enamel
Part
A:
Grind Base:
Liquid
DGEBA
Epoxy
Nuosperse
657
(Huls America)
Surfynol
740
(Air Products)
Dowanol
PM
(Dow)
TiPure
R-960
(DuPont)
Let Down:
High Flash Naphtha (Ashland)
Methyl Propyl Ketone (Eastman)
Part
8:
Ancamide
2353
(Air Products)
n-Butanol (Ashland)
Propert
i
es
:
Part
A
Viscosity:
73
KU
Part
B
Viscosity:
64
KU
Mixed Viscosity:
70
KU
PVC:
17%
Volume Solids:
70%
352.76 36.43
3.88 0.46
1.76 0.25
48.68 6.32
388.04 11.92
67.73 9.22
14.11 2.09
212.03 23.46
63.14 9.34
VOC,
@
70
KU:
2.2
lb/gal
Mix Ratio:
2:l
by Volume
Induction Time:
0
Pot Life, hr:
2
Dry Times:
Set to Touch, hr:
5
Dust Free, hr:
7
Hard Dry: Overnight
60
Gloss:
102
SOURCE:
Air
Products and Chemicals, Inc.: Ancamide
2353
Curing
Agent: Tab1 e
11
Formulation
34
Water-Based Paint Formulations
Carv
Gloss
White Enamel
Inaredients:
Pigment Grind:
Butyl Cellosolve Solvent
Water
Tamol 731
Triton Nonionic Surfactant CF-10
Byk 023
Ti
-Pure R-900
Natrosol Plus 330
Water
Nuosept 145
Letdown
:
Ucar Latex 481
Water
Butyl Carbi to1 Sol vent
Solvent 142HT
LE-410 Emulsion
Surfynol 104E
Paint Properties:
Pigment Volume Concentration,
%:
17.8
Volume Solids,
%:
40.6
Weight Solids,
%:
51.9
Stormer,
KU:
85
ICI,
Poise: 2.0
pH Value: 9-9.6
Freeze-Thaw Stability, cycles passed: 0.1
Heat-Age Stability,
120F,
weeks passed: 4
VOC,
grams per liter: 196
Pounds
39.0
20.0
9.6
2.4
2.5
240.0
1.1
5.0
1.4
620.0
19.6
12.8
32.8
15.0
2.0
Gal 1 ons
5.20
2.40
1.05
0.27
0.35
7.02
0.10
0.60
0.16
71.84
2.35
1.60
5.00
1.82
0.24
Typical Titanium Dioxide Pigment Performance
Titanium Dioixde Stormer
IC1
Gloss Values
KU
Poise 60 20
Ti
-Pure R-900 85 2.0 85 52
Ti -Pure R-902 83 2.1 79 41
Ti
-Pure R-960 86 2.0 79 41
Ti
-Pure R-706 82 1.7 90 60
Tronox CR-828
Tiona RCL-535
Kronos 2310
Tioxide
TR
90
Tioxide
TR
93
Tioxide
TR
80
86 2.0 87 59
83 1.7 87 59
84 1.8 84 53
83
86
85
1.7 88 54
1.8
86 57
2.0 90 68
SOURCE:
Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion E-2218C
Enamek
35
Caw
Gloss
White Enamel
Ingredients:
Pigment Grind:
Butyl Cell os01 ve
Sol
vent
Water
Tamol 731
Triton Nonionic Surfactant CF-10
Byk 023
Ti -Pure R-900
Water
Nuosept 145
Ammonium Hydroxide, 28% Aqueous Solution
Letdown
:
Ucar Latex 481
Butyl Carbitol Solvent
Sol vent 142HT
LE-410 Emulsion
Ucar Polyphobe 102 Rheo. Mod.
Ucar Polyphobe 106HE Rheo. Mod.
Water
Surfynol 104E
Paint Properties:
Pigment Volume Concentration,
%:
17.8
Volume Solids,
%:
40.7
Weight Solids,
%:
52.1
Stormer,
KU:
86
ICI,
Poise: 2.5
pH Value: 9-9.6
Freeze-Thaw Stability, cycles passed: 0-1
Heat-Age Stability, 120F, weeks passed: 4
VOC,
grams per liter: 196
Fi
1
m
Properties
:
Gloss,
60: 88
Gloss,
20:
47
Flow and Leveling: Excellent
Dry-to-Touch, hour: 1
Recoat, hours: 2-4
Water/Bl
i
ster Resistance: Excel lent
Pounds
39.0
20.0
9.6
2.4
2.5
240.0
5.8
1.4
2.0
620.0
12.8
32.8
15.0
5.0
2.7
10.0
2.0
Gal 1 ons
5.20
2.40
1.05
0.27
0.35
7.02
0.70
0.16
0.27
71.84
1.60
5.00
1.82
0.57
0.31
1.20
0.24
SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion E-221
6G
36
Water-Based
Paint
Formulations
Clear Enamel
(For
Maximum Solvent and Abrasion Resistance)
______
Pounds Gal lons
Materi a1.L
Part
A:
Epi-Rez 5522-WY-55 Resin 490.6 54.82
Michem Lube 743 Mar and Slip Agent 41
.O
5.00
Cyclo Sol 63 32.3 4.37
Ektasolve
EP,
2-Propoxyethanol
33.2
4.37
Water 53.6 6.44
Part
0:
Epi-Cure 8290-Y-60 Curing Agent
DeeFo
PI-4
Concentrate Defoamer
Water
Composite Blend:
Vi
scosi ty
Part
A
58 K.U.
Part
B
68 K.U.
Parts
A
and
0
85 K.U.
145.8 16.51
4.0 0.49
66.6 8.00
650.7 75.00
216.4 25.00
Typical Coating Properties:
Total Weight Solids,
%:
41.8
Total Volume Solids,
%:
37.6
Volatile Organic Compounds
(VOC):
Pounds/Gallon: 2.74
Grams/Liter: 329
Induction Time, minutes: 30
Resi n Composi
ti
on
:
Epoxy Resin,
%:
75.0
Curing Agent,
%:
25.0
Total,
%:
100.0
SOURCE:
Shell Chemical Co.: Starting Formulation
No.
1802:
€pi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60 Curing Agent
Enamels
37
Gloss Safety
Red
Enamel
Ingredients:
Pi
gment
Gri
nd
:
Ucar Latex 481
Triton Nonionic Surfactant CF-10
Toluidine Red 10-6C-41-L100
Aquatrend
I1
Red Iron Oxide Disp. 878-1046
Colanyl Carmine Disp. 13-3148 (Azo Red)
Foamaster 333
Natrosol Plus 330
Water
Nuosept 145
Letdown
:
Ucar Latex 481
Butyl Cellosolve Solvent
Butyl Carbitol Solvent
Solvent 140
LE-410 Emulsion
Aquatrend
I1
Red Iron Oxide Disp. 878-1046
Colanyl Carmine Disp. 13-3148 (Azo Red)
Surfynol 104E
Paint Properties:
Pigment Volume Concentration,
%:
11
.O
Volume Solids,
%:
39.5
Weight Solids,
%:
43.4
Stormer,
KU:
88
ICI,
Poise: 1.5
pH Value: 8.5-9.5
Freeze-Thaw Stability, cycles passed:
5
Heat-Age Stability, 12OF, weeks passed: 4
VOC,
grams per liter: 210
Film Properties:
Gloss,
60:
81
Gloss, 20: 40
Flow and Leveling: Excellent
Dry-to-Touch, hour:
I
Recoat, hours: 2-4
Water/Bl
i
ster Resistance: Excel lent
Pounds
173.4
10.0
110.0
9.4
7.8
15.0
1
.o
8.3
1.2
416.9
38.3
12.4
32.8
15.0
5.0
3.0
2.0
Gal lons
20.09
1.14
11.58
0.59
0.76
2.00
0.09
1
.oo
0.13
48.31
5.10
1.55
5.00
1.82
0.31
0.29
0.24
SOURCE:
Ucar
Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion
E-2222C
38
Water-Based Paint Formulations
Gloss Safety Yellow Enamel
Inpred
i
en
t
s
:
Pi ament
Gri
nd: Pounds
BuTyl Cellosolve Solvent
Water
Tamol 731
Triton Nonionic Surfactant CF-10
Foamaster 333
Ti
-Pure R-900
Natrosol Plus 330
Water
Nuosept 145
Butyl Cellosolve Solvent
Letdown
:
Ucar Latex 481
Water
Byk 026
Butyl Carbitol Solvent
Sol vent 142HT
LE-410 Emulsion
Aquis Dalamar Yellow Disp. YW-811D
Aquatrend
I1
Yellow Iron Oxide Disp. 878-0012
Aquatrend
I1
Lamp Black Disp. 878-9908
Surfynol 104E
Paint Properties:
Pigment Volume Concentration,
%:
11.4
Volume Solids,
%:
37.4
Weight Solids,
%:
43.9
Stormer,
KU:
89
ICI,
Poise: 1.7
pH Value: 8.5-9.5
Freeze-Thaw Stability, cycles passed:
5
Heat-Age Stability, 120F, weeks passed: 4
VOC,
grams per liter: 218
Fi 1
m
Properti
es
:
Gloss, 60: 86
Gloss, 20: 46
F1 ow and Level
i
ng
:
Excel 1 ent
Dry-to-Touch, hour: 1
Recoat, hours: 2-4
Water/Blister Resistance: Excellent
12.8
10.0
5.0
10.0
15.0
66.3
2.8
5.0
1.2
24.8
572.9
24.0
2.0
12.8
32.8
15.0
76.2
12.1
0.1
2.0
Gallons
1.70
1.20
0.54
1.14
2.00
1.94
0.25
0.60
0.13
3.30
66.39
2.88
0.25
1.60
5.00
1.82
8.28
0.73
0.01
0.24
SOURCE:
Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion E-2225C
Enameh
39
Gloss
White
Enamel
Materi a1
:
Part
A:
Epi -rez 3520-WY-55 Resin
Michemlube 182 Mar and Slip Agent
Water
Part
0:
Epi-Cure 8537-WY-60 Curing Agent
Ektasolve DB Acetate
Triethylamine
Patcote 519 Defoamer
Kronos 2020
or
Tronox
CR-800
Pounds
411.6
27.8
13.7
160.0
8.2
3.7
4.0
250.0
Gal
1
ons
45.03
3.33
1.64
17.70
1
.oo
0.61
0.57
7.33
High Speed disperse to a texture
of
10
P.C.S.,
then add:
Epi-Cure 8537-WY-60 Curing Agent
Water 42.4 4.69
150.0 18.10
Composi te 81 end
:
Part
A
Part
B
Parts
A
and
B
Vi
scosi ty
85
KU
453.1
50.00
110
KU
619.1
50.00
99
KU
Typical Coating Properties:
Total Weight Solids,
%:
55.8
Total Volume Solids,
%:
42.3
PVC,
%:
17.3
Volatile Organic Compounds (VOC):
Pounds/Gal 1 on
:
1
.61
Grams/Li ter: 187
Resin Composition (based
on
solids):
Epoxy Resin,
%:
65.0
Curing Agent,
%:
35.0
Total,
%:
100.0
Reduction for Conventional Spray (by volume):
Parts
A
and
B:
17 Parts
Water: 1 Part
SOURCE:
Shell Chemical Co.: Starting Formulation
No.
1606:
Epi-Rez
3520-WY-55
Resin/Epi-Cure
8537-WY-60
Curing
Agent
40
Water-Based
Paint
Formulations
Gloss White
~..~
Enamel
Mat
cr
i
_a
1-1
Part
A:
Epi -Rez 3520-WY-55 Resin
Michemlube 182 Mar and Slip Agent
Water
Part
B:
Epi-Cure 8536-MY-60 Curing Agent
Deefo PI-4 Concentrate Defoamer
Rutile Titanium Dioxide, Kronos 2020 or
Tronox CR-800
High speed disperse to a texture of
10
P.C.S
Epi-Cure 8536-MY-60 Curing Agent
Water
Typical Coating Properties:
Total Weight Solids,
%:
51.5
Total Volume Solids,
%:
37.6
PVC, %:
19.5
Volatile Organic Compounds (VOC):
Pounds/Gal lons: 1 .89
Grams/Li ter: 227
Resin Composition (based
on
solids):
Epoxy Resin,
%:
62.2
Curing Agent,
%:
37.8
~~
Pounds
329.4
88.6
27.8
160.0
4.0
250.0
Gallons
36.04
3.33
10.63
19.28
0.49
7.33
then add:
22.5 2.71
168.2 20.19
Reduction for Conventional Spray
(by
volume):
None required
SOURCE: Shell Chemical Co.: Starting Formulation
No.
1805:
Epi-Rez
3520-WY-55
Resin/Epi-Cure
8536-MY-60
Curing
Agent
Enamels
41
Gloss White Enamel (Maximum Solvent and Abrasion Resistance)
Materi a1
:
Part
A:
€pi
-Rez 5522-WY-55 Resin
Cyclo Sol 63
Ektasolve EP, 2-Propoxyethanol
Water
Part 8:
Epi -Cure 8290-Y-60 Curing Agent
Deefo PI-4 Concentrate Defoamer
Ti-Pure R-960 or Kronos 2160
Water
High speed disperse to a texture of 10
P.S.C
Water
Glacial Acetic Acid
Composite Blend:
Vi
scosi ty
Part
A
61
K.U.
Part
B
103
K.U.
Parts
A
and
B
83
K.U.
Typical Coating Properties:
Total Weight Solids,
Oh:
54.0
Total Volume Solids,
%:
40.4
PVC,
%:
19.2
Volatile Organic Compounds (VOC):
Pounds/Gallon: 2.34
Grams/Liter: 280
Induction Time, minutes: 30
Resin Composition (based on solids):
Epoxy Resin,
%:
74.5
Curing Agent,
%:
25.5
~___
Pounds Gal 1 ons
442.2 49.41
22.2
3.00
22.7 3.00
93.8 11 .26
135.1 15.30
4.0 0.49
250.0 7.74
12.5 1
.so
66.1 7.93
3.2 0.37
580.9 66.67
470.9 33.33
Reduction for Conventional Spray (by volume):
Parts
A
and
B:
25 parts
Water:
1
part
SOURCE:
Shell Chemical Co.: Starting Formulation
No.
1803:
Epi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60 Curing Agent
42
Water-Based
Paint
Formulations
Green
Air
Dry
Enamel
for
Flexible Substrates
Materi a1
:
Spensol L53
Amrnoni um Hydroxi de
Di
sperse-Ayd W28
Colloid 679
Ucar
SCT
100
Sunbrite Yellow 272-0558
Sunbri te Green 264-8142
Titanox 2101
Mapico 1075
Lbs.
261.6
1.9
4.4
1.9
2.3
50.0
25.0
25.0
50.0
Gals.
30.00
0.25
0.50
0.25
0.25
4.69
1.43
0.75
1.48
Add the above in order under good agitation, then pebble or
sandmill grind to 7 Hegman.
Letdown
:
Spensol L53 526.7 60.40
Analysis:
Pigment Volume Concentration, Percent: 24.7
Pigrnent/Binder Ratio: 0.6/l.O
Percent Solids, Weight: 41.2
Percent Sol ids, Vol ume: 33.8
Viscosity
@
25C, #2 Zahn, Secs.: 50-60
Pounds/Gallon: 9.5
VOC
(excluding water):
Grams/Liter: 289
Pounds/Gallon: 2.4
pH: 8.5+-0.3
SOURCE:
Reichhold Chemicals, Inc.
:
Spensol L:
Formula
2316-62A
Enamels
43
Hi
qh-Hidi
nq
Esashe11
Enamel
Pounds
Insredi ents:
Pigment Grind:
Water 226.7
Cel losi
ze
Hydroxyethyl Cell ul ose ER-4400
2.0
Nuosept 145 2.3
Tamol 731 9.2
Triton Nonionic Surfactant N-57 2.3
AMP-95 1
.o
Propylene Glycol 51.8
Col loid 643 1.9
Tronox CR-800 225.0
Optiwhi te 100.0
Burgess No. 98 25.0
Letdown
:
Ucar Filmer
IBT
Butyl Carbi to1 Solvent
Acrysol SCT-275
Ucar Latex 379G
Col loid 643
Pai nt Properties
PVC,
%:
35.6
Volume Sol
i
ds
Weight Sol ids
Weight per Ga
Stormer.
KU:
ICI.
noise:
1
%:
37.6
%:
53.4
lon, lb:
04
.4
11.9
11.9
17.2
418.2
2.8
1.09
Gal
1 ons
27.21
0.18
0.25
1
.oo
0.25
0.13
6.00
0.25
6.54
5.46
1.15
1.50
1.50
2.00
46.21
0.37
I.
pH, initial: 8.2
Freeze-thaw Stability,
3
cycles: Pass
Heat-Aged Stability, 2 weeks at 120F: Pass
Fi 1
m
Properties
:
Ref 1 ectance,
%:
91.9
Gloss, 60: 8
Sheen, 85: 22
Contrast Ratio, 3-mil
film*:
0.968
Flow and leveling, brushed: Good
*Opacity increased with toning.
SOURCE:
Ucar Emulsion Systems: Formulation Suggestion
I-1998A
44
Water-Based Paint Formulations
MacGregor Gloss B1
ack
Enamel
Ingredients:
Pigment Grind:
Ucar Latex 481
Byk 023
Triton Nonionic Surfactant CF-10
Aurasperse Carbon B1 ack W-7012
Water
Nuosept 145
Ammoni urn Hydroxi de, 28% Aqueous Sol uti on
Letdown
:
Ucar Latex 481
Dee Fo 102OF
Butyl Cell osolve Sol vent
Butyl Carbitol Solvent
Sol vent 142HT
LE-410
Emu1
si
on
Water
Ucar Polyphobe 102 Rheo. Mod.
Ucar Polyphobe 106HE Rheo. Mod.
Surfynol 104E
Pounds
88.0
2.5
10.0
45.0
8.3
1.2
2.4
556.0
5.0
39.0
12.4
32.8
15.0
15.0
8.3
4.5
2.0
Gallons
10.20
0.35
1.14
4.69
1
.oo
0.13
0.29
64.43
0.68
5.21
1.57
5.00
1.80
1.80
0.95
0.52
0.24
Paint Properties:
Pigment Volume Concentration,
%:
2.3
Volume Solids,
%:
37.9
Weight Solids,
%:
40.6
Stormer,
KU:
90
ICI,
Poise:
2.6
pH Value: 8.5-9
Freeze-Thaw Stability, cycles passed: 5
Heat-Age Stability, 120F, weeks passed:
4
VOC,
grams per liter: 204
Film
Properties:
Gloss, 60: 91
Gloss, 20: 65
Flow and Leveling: Excel lent
Dry-to-Touch, hour: 1
Recoat, hours: 2
Water/Bl
i
ster Resistance: Excel lent
SOURCE:
Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggest
i
on E-2221
E
Enamels
45
Pinehurst Gloss Green Enamel
Ingredients:
Pigment Grind:
Butyl Cellosolve Solvent
Water
Tamol 731
Triton Nonionic Surfactant CF-10
Byk 023
Chromium Oxide Green W-6017
Aurasperse Carbon Black W-7012
Aurasperse Phthalo Green W-6013
Yellow Iron Oxide 878-1812
Natrosol Plus 330
Water
Nuosept 145
Letdown
:
Ucar Latex 481
Water
Butyl Carbitol Solvent
Solvent 142HT
Butyl Cellosolve Solvent
Water
LE-410 Emulsion
Surfynol 104E
Pounds
7.5
5.8
5.0
10.0
2.5
53.3
3.2
25.4
7.0
2.0
4.2
1.2
640.0
8.3
12.4
32.8
31
.5
8.8
15.0
2.0
Gal 1 ons
1
.oo
0.70
0.54
1.14
0.31
3.08
0.34
2.54
0.42
0.18
0.59
0.13
74.16
1
.oo
1.55
5.00
4.20
1.06
1.82
0.24
Paint Properties:
Pigment Volume Concentration,
%:
4.6
Volume Solids,
%:
37.1
Weight Solids,
%:
42.0
Stormer,
KU:
88
ICI,
Poise: 2.3
pH Value: 8.5-9.5
Freeze-Thaw Stability, cycles passed: 5
Heat-Age Stability, 120F, weeks passed: 4
VOC,
grams per liter: 221
Film Properties:
Gloss,
60:
88
Gloss, 20: 64
Flow and Level
i
ng: Excel
1
ent
Dry-to-Touch, hour: 1
Recoat. hours: 2-4
Water/Blister Resistance: Excellent
SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion E-22429
46
Water-Based Paint Formulations
Self-Primina Interior Semi-Gloss Enamel
Pigment Grind:
Water
Busperse 203
Igepal CTA-639
Bubreak 448
Water*
Cellosize
QP
15,000*
Atomi te
Ti-Pure R-900
Disperse 10-15 minutes on a high-speed
mill
Add the following
with
slow agitation.
Let Down:
Rhopl ex R-AC-507
Ethylene glycol
Texanol
Water
*These ingredients are premixed.
Lbs.
100.0
14.0
3.0
3.0
25.0
2.0
73.0
200.0
550.0
40.0
25.0
32.0
Exterior Maintenance-Type Coating
Pigment Grind:
Water
Tam01 -681
8ubreak 448
Igepal CTA-639
E-845
Ti-Pure R-900
Atomi te
Mica
Kadox 911
Disperse 10-15 minutes on a high-speed
mi
11.
Add the following
with
slow agitation.
Let Down:
Rhopl ex MV-23
Texanol
Ethylene glycol
Water
Lbs.
100.0
14.0
3.0
3.0
40.0
150.0
191
.o
25.0
12.0
527.0
5.0
30.0
30.0
&&
9.37
1 .31
0.28
0.28
2.34
0.19
6.84
18.74
51.55
3.75
2.34
3.01
Wt%
8.85
1.24
0.27
0.27
3.54
13.27
16.90
2.21
1.06
46.64
0.44
2.65
2.66
SOURCE:
Buckman Laboratories: Butrol
35:
Formulation Suggestions
Enamels
47
Semi
gloss
Enamel
Inqredients:
Piament Grind:
WaIer
Cellosize Hydroxyethyl Cellulose ER-15,000
Nuosept 145
Tamol 731
Triton Nonionic Surfactant N-57
Propylene G1 ycol
Byk 035
Tronox CR-800
Letdown
:
Thickener; premix*
Ucar Latex 3796
Ucar Filmer IBT
Byk 035
Triton Anionic Surfactant GR-7M
AMP-95
Pounds
268.2
2.0
2.4
9.2
2.1
1
.o
43.2
1
.o
250.0
29.9
428.4
20.0
1.9
0.5
Gal 1 ons
32.20
0.18
0.25
1
.oo
0.25
0.13
5.00
0.13
7.27
3.48
2.52
0.25
0.06
47.28
Pa
*Premix consists of 1:l:l blend of Propylene Glycol; Rohm
and Haas' Acrysol SCT-275 thickener:water, respectively.
nt Properties:
PVC,
%:
23.0
Volume Solids,
%:
31.8
Weight Solids,
%:
46.0
Weight per Gallon, lb: 10.60
Stormer,
KU:
82
ICI,
poise: 0.4
pH, initial: 8.5
Freeze-thaw Stability, 3 cycles: Pass
Heat-Aged Stability, 2 weeks at 120F: Pass
Fi 1
m
Properti es
:
Reflectance,
%:
89.5
Gloss, 60: 59
Contrast Ratio, 3-mil
film:
0.967
Flow and Leveling:
brushed: Very Good
drawdown,
NYPC
Blade: 8
SOURCE:
Ucar Emulsion Systems: Formulation Suggestion
I-1989A
48
Water-Eased Paint Formulations
Semi
ql
oss
Enamel
I
ngredi ent
s
:
Pigment Grind:
Water
Propylene Glycol
Tamol 1124
Proxel GXL
Col 1 oid 640
Ti
-Pure R-900
Triton Nonionic Surfactant N-101
ASP-1
70
Water
Letdown
:
Water
Colloid 640
NeoCar Latex 6040
Water
Ucar Filmer IBT
Ammonium Hydroxide, 28% Aqueous Solution
Ucar Polyphobe 102 Rheology Modifier
Water
Paint Properties:
PVC,
%:
24.9
Volume Solids,
%:
30.5
Weight Solids,
%:
44.5
Weight per Gallon, lb: 10.47
Stormer,
KU:
88-93
ICI,
poise: 1.1
pH Value: 8.75-9.25
Heat-Aged Stability, 4 weeks at 140F:
Pass
Film Properties:
Gloss, 20: 20
Gloss, 60: 65
Contrast Ratio, 3-mil
film:
0.980
ASTM
Scrub Cycles, with shim: 1600
Block Resistance, 1 day: Exc
Wet Adhesion,
4
hours: Exc
Flow and Leveling: Exc
Stain Removal
:
Exc
Pounds
15.0
55.0
5.0
1
.o
2.0
230.0
4.0
15.0
50.0
39.9
1
.o
425.0
100.0
30.0
4.0
20.0
50.0
Gal 1 ons
1.80
6.35
0.51
0.11
0.26
6.90
0.46
0.70
6.00
4.79
0.13
47.39
12.00
3.79
0.52
2.30
6.00
Source: Ucar Emulsion Systems: NeoCar Polymers: Formulation
Suggestion
E-2481
Enamels
49
Southern Pines Gloss White Enamel
Ingredients:
Pigment Grind:
Propylene Glycol
Water
Tamol 731
Triton Nonionic Surfactant
CF-10
Byk 023
Ti -Pure R-900
Nuosept 145
Water
Ammoni um Hydroxi de, 28% Aqueous Sol uti on
Letdown
:
Ucar Latex 481
Butyl Carbitol Solvent
Sol vent 142HT
Triton Anionic Surfactant GR-5M
Byk 026
LE-410 Emu1 si on
Ucar Polyphobe 102 Rheo. Mod.
Water
Surfynol 104E
Pai
nt Properties
:
Pigment Volume Concentration,
%:
17.6
Volume Solids,
%:
41.1
Weight Solids,
%:
53.1
Stormer,
KU:
90
ICI,
Poise: 1.9
pH Value: 8.5-9.5
Freeze-Thaw Stability, cycles passed: 5
Heat-Age Stability, 12OF, weeks passed: 4
VOC,
grams per liter: 174
Film Properties:
Gloss, 60: 88
Gloss, 20: 52
F1 ow and Level
i
ng
:
Excel 1 ent
Dry-to-Touch, hour: 2
Recoat, hours: 4
Water/Bl
i
ster Resistance: Excel 1 ent
___
Pounds
40.0
20.0
9.6
2.4
2.5
240.0
1.4
11.1
2.0
620.0
12.8
20.0
1
.o
1
.o
15.0
20.0
11.9
2.0
Gallons
4.62
2.40
1.05
0.27
0.35
7.02
0.16
1.33
0.24
71.84
1.62
3.05
0.12
0.14
1.82
2.30
1.43
0.24
SOURCE:
Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion
E-2251
C
50
Water-Based
Paint Formulations
Spensol L54 Oranqe Enamel
Materi a1
:
Water
Ammoni um Hydroxi de
Bentone EW
Lbs.
Gals.
30.0 3.60
1.1 0.15
3.0 0.14
Premix the above three materials and Cowles
grind
15-20 minutes
to fully disperse Bentone
EW.
Then add the following materials
under good agitation:
Spensol L54
Surfynol GA
Aerosol OT-75
Nalco 2300
Molybdate Orange
Water
Pebble
or
sand
mill
grind
to
7
N.S.
Letdown
:
_____
Materi a1
:
Spensol L54
Surfynol 104H
15% Solution
FC430
in
Water
Ucar SCT-100
Analysis:
Pigment Volume Concentration,
Pigment/Binder Ratio: 0.5/1
.O
Percent Solids, Weight: 39.1
Percent Solids, Volume:
30.0
Viscosity, #4 Ford, Secs.: 80-
Pounds/Gallon: 9.7
VOC (excluding water):
Grams/Li ter
:
303
Pounds/Gallon: 2.5
Gloss (60): 50-60
pH: 8.5+-0.3
Percent: 9.0
.90
87.3 10.00
4.4 0.50
2.3 0.25
0.5 0.06
125.0 2.70
41.7 5.00
Lbs.
670.9
2.0
2.1
2.3
Gals.
76.85
0.25
0.25
0.25
SOURCE: Reichhold Chemicals, Inc.: Spensol
L:
Formula 2154-59A
Enamels
51
Waterborne Black Enamel
Based on Eootuf
37-143/37-680
XForrula
No.
3019-28A1
Component
A:
Arcosolv
PTB
2-Butoxy Ethanol
Dowanol
PPH
Add following in order under agitation:
Wollastokup 10
ES
Raven 410
High speed disperse
to
5
N.S.
Add following under agitation:
Epotuf 37-680
&
Gals
78.91 8.91
24.41 3.34
3.68 0.49
7.37
0.04
48.40
20.02 2.00
1.38
Epotuf 37-680
2-Butoxy Ethanol 432.06 48.77
9.54 1.27
Component
0:
Mix following under high-speed agitation until uniform:
Epotuf 37-1 43 91.85 10.32
Epotuf 37-058 7.95 1.07
2-Butoxy Ethanol 73.09 9.84
Tap Water 98.04 11.77
Wei ght/Gal lon
(Lbs.
)
:
8.96
Percent Solids (Wt.): 57.50
Percent Solids (Vol.): 37.30
PVC
(%):
46.30
VOC
(
Lbs. /Gal 1 on)
:
2.80
SOURCE:
Reichhold Chemicals, Inc.: Formula 3019-28A
52
Water-Based Paint Formulations
Waterborne Blue Enamel
Based On Epotuf
37-143/37-600
LFormula
No.
3019-31Gl
Component
A:
Epotuf 37-680
Arcosolv PTB
2-8utoxy Ethanol
Oowanol PPH
Add following
in
order under agitation:
Wollastokup
10
ES
Sunfast
81
ue 248-3750
Tioxide TR92
High speed disperse to
5
N.S.
Add following under agitation:
j&S
Gals
133.28 15.04
24.31 3.33
3.63 0.48
7.38
0
.84
64.54
34.37
22.02
Epotuf 37-600 368.
1
2.67
2.29
0.66
1.58
Component
B:
Mix following under high-speed agitation
until
uniform:
EDotUf 37-143
88.91
Epotuf 37-058
2-Butoxy Ethanol
Tap Water
Weight/Gallon (Lbs.): 9.29
Percent Sol
ids
(Wt
.
)
:
57.50
Percent Solids (Vol.): 37.30
PVC
(%):
46.30
VOC (Lbs./Gallon): 2.83
9.99
7.62 1.03
91
.15 12.14
82.89 9.95
SOURCE:
Reichhold Chemicals, Inc.: Formula
No.
3019-31G
Enamels
53
Waterborne Dark Blue Enamel
Based on Epotuf 37-143/37-600
(Formula
No.
3019-31Dl
Component
A:
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Add following in order under agitation:
Wollastokup
10
ES
Sunfast Blue
248-3750
High speed disperse to
5
N.S.
Add following under agitation:
Epotuf
37-680
!&
Gals
134.16 15.14
24.47 3.35
3.65 0.49
7.43 0.84
64.97
34.60
Epotuf
37-680 370.85
Component
0:
Mix following under high-speed agitation until uniform:
Epotuf
37-1 43
Epotuf
37-050
2-Butoxy Ethanol
Tap Water
89.50
7.67
91.75
83.44
Weight/Gallon
(Lbs.):
9.12
Percent Solids (Wt.):
57.50
Percent Solids (Vol.):
37.30
PVC
(%):
46.30
VOC
(Lbs/Gallon):
2.83
SOURCE:
Reichhold Chemicals, Inc.
:
Formula
No.
3019-31D
2.68
2.31
41 .86
10.06
1.04
12.22
10.02
54
Water-Based Paint Formulations
Waterborne Green Enamel
XFormula
No.
3019-31F)
Based
on
EDOtUf
37-143/37-680
Component
A:
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Add following in order under agitation:
Epotuf 37-680
Wollastokup
10
ES
Sunbrite Yellow 75
Sunfast Blue 248-3750
Tioxide TR92
High speed disperse to 5
N.S.
Add following under agitation:
Epotuf 37-680
2-Butoxy Ethanol
~
Lbs
165.99
23.12
3.47
8.05
78.51
23.71
9.68
9.21
295.72
29.74
Component
B:
Mix following under high-speed agitation until uniform:
Epotuf 37-058 6.97
Tap Water 123.78
Epotuf 37-143 82.10
2-Butoxy Ethanol 59.85
Wei ght/Gal 1 on (Lbs
.
)
:
9.20
Percent Sol ids (Wt
.
)
:
57.50
Percent Solids (Vol.): 37.30
PVC
(%):
46.30
VOC
(Lbs./Gallon): 2.80
SOURCE:
Reichhold Chemicals, Inc.
:
Formula
No.
3019-31F
18.73
3.17
0.46
0.91
3.24
2.22
0.65
0.28
33.38
3.96
9.22
0.94
7.97
14.86
Enamels
55
Waterborne Oranqe Enamel
Based on Epotuf
37-143/37-600
(Formula
3019-3111
Component
A:
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Add following in order under agitation:
Wollastokup 10
ES
Sunbri te Ye1 low 74
Novoperm Red F3RK-70
High speed disperse to 5
N.S.
Add following under agitation:
Epotuf 37-680
EpOtuf 37-680
2-Butoxy Ethanol
Lbs
179.20 20.23
22.73 3.11
3.41 0.45
8.36 0.95
78
*
45
26.52
8.20
282.39
30.04
Component
B:
Mix
following under high-speed agitation until uniform:
EpOtuf 37-143 82.02
Epotuf 37-058 7.80
2-Butoxy Ethanol 60.60
Tap Water 122.11
Wei ght/Gal 1
on
(
Lbs
.
)
:
9.12
Percent Solids (Wt.): 57.50
Percent Solids (Vol.): 37.30
PVC
(%):
46.30
VOC
(Lbs./Gallon): 2.80
SOURCE: Reichhold Chemicals, Inc.: Formula
No.
3019-311
3.24
2.49
0.76
31.87
4.00
9.22
1
.oo
8.07
14.66
56
Water-Based Paint Formulations
Waterborne Red Enamel
Based
on
Epotuf 37-143/37-6%0
(Formula
No.
3019-3181
Component
A:
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Add following in order under agitation:
Wollastokup
10
ES
Novoperm Red F3RK-70
High speed disperse to 5
N.S.
Add following under agitation:
2-Butoxy Ethanol
Tap Water
Epotuf 37-680
Epotuf 37-680
!&
97.48 11
.oo
25.04 3.43
3.73
0.50
9.29 1 .06
60.09 2.48
20.69 1.92
377.11
18.73
12.91
Component
8:
Mix following under high-speed agitation until uniform:
Epotuf 37-1 43 80.34
Epotuf 37-058 7.88
2-Butoxy Ethanol 65.27
Tap Water 118.45
Wei ght/Gal
1
on
(
Lbs
.
)
:
8.97
Percent
Sol
ids (Wt
.
)
:
57.50
Percent Solids (Vol.): 37.30
PVC
(%):
46.30
VOC
(Lbs./Gallon): 2.84
SOURCE:
Reichhold Chemicals, Inc.: Formula
No.
3019-318
42.56
2.49
1.55
9.03
1.06
14.22
8.69
Enamels
57
Waterborne Red Orange Enamel
Based on EDOtUf
37-143/37-600
Iformula
No.
3019-31El
Component
A:
Arcosolv PTB
2-Butoxy Ethanol
Dowanol
PPH
Add following in order under agitation:
Epotuf 37-680
Wol lastokup 10
ES
Sunbrite Yellow 74
Novoperm Red F3RK-70
Tioxide TR 92
High speed disperse to 5
N.S.
Add following under agitation:
Epotuf 37-680
2-Butoxy Ethanol
Arcosolv
PTB
Lbs
Gals
157.10 17.73
23.40 3.21
3.49 0.46
8.57 0.97
73.31
19.47
8.20
7.56
307.00
25.51
5.40
Component 8:
Mix following under high-speed agitation until uniform:
Epotuf 37-143 84.28
Epotuf 37-058 7.36
2-Butoxy Ethanol 57.28
Tap Water 124.03
Weight/Gallon (Lbs.): 9.12
Percent Solids (Wt.): 57.50
Percent Solids (Vol.): 37.30
PVC
(%I:
46.30
VOC
(Lbs./Gallon): 2.80
SOURCE:
Reichhold Chemicals, Inc.: Formula
No.
3019-31E
3.03
1.83
0.76
0.23
34.65
3.40
0.75
9.47
1.00
7.63
14.89
58
Water-Based Paint Formulations
Waterborne Yellow
EDOXY
Enamel
Based
on
EDOtuf
37-143/37-680
(Formula
No.
3019-31Cl
Component
A:
Arcosolv PT8
2-Butoxy Ethanol
Dowanol PPH
Add following
in
order under agitation:
Wollastokup
10
ES
Sunbrite Yellow 74
Ti
oxide TR-92
High speed disperse to 5
N.S.
Add following under agitation:
Epotuf 37-680
Epotuf 37-680
2-8utoxy Ethanol
Lbs
Gal
198.55 22.41
22.56 3.09
3.36 0.45
8.21 0.93
83.03
32.49
12.63
3.43
3.05
0.38
263.53 29.74
26.43 3.52
Component
8:
Mix following under high-speed agitation until uniform:
Epotuf 37-143 80.25 9.02
Epotuf 37-058 6.91 0.93
2-Butoxy Ethanol 65.03 8.66
Tap Water 119.86 14.39
Wei ght/Gall on (Lbs.
)
:
9.23
Percent Solids (Wt.): 57.50
Percent Solids (Vol.): 37.30
PVC
(%):
46.30
VOC
(Lbs./Gallon): 2.40
SOURCE: Reichhold Chemicals, Inc.: Formula
3019-31C
EnameLF
59
Whisoering Pines Semigloss White Enamel
Inqredients:
Pigment Grind:
Propylene Glycol
Water
6yk 023
Tamol 731
Ti -Pure R-902
Path 9
Nuosept 145
Water
Ammoni um Hydroxi de,
Pounds
30.0
53.3
2.5
10.0
230.0
40.0
1.5
16.7
28% Aqueous Sol uti on 2.0
Letdown
:
Ucar Latex 461
Ucar Filmer I6T
Sol vent 142HT
LE-410 Emulsion
Ucar Polyphobe 102 Rheo. Mod
Water
Surfynol 104E
556.0
12.4
31.5
15.0
16.9
19.7
2.0
Gal 1 ons
3.47
6.40
0.35
1.09
6.92
1.98
0.17
2.00
0.94
64.66
1.57
4.80
1
.BO
1.94
2.37
0.24
Paint Properties:
Pigment Volume Concentration,
%:
23.3
Volume Solids,
%:
39.2
Weight Solids,
%:
51.5
Stormer,
KU:
93
ICI,
Poise: 2.1
pH Value: 8.5-9.5
Freeze-Thaw Stability, cycles passed:
5
Heat-Age Stability, 120F. weeks passed: 4
VOC,
grams per liter: 181
Film Properties:
Gloss, 60:
54
Gloss, 20: 14
Flow and Leveling: Excellent
Dry-to-Touch, hour: 2
Recoat, hours: 4
Water/61
i
ster Resistance: Excel lent
SOURCE:
Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion E-2245C
60
Water-Based Paint Formulations
Anquamine 401
1:l
White
Gloss
Enamel
Part
A:
j&
Gals
Epi -Rez 3520-WY-55 Epoxy Resin (She1 1
)
363.24 39.20
DER
331 Epoxy Resin (Dow) 40.36 4.17
Water
Surfynol DF-11OD
(Air
Products) 52.32 6.27
3.00 0.36
Part
B:
Anquami ne 401 Curing Agent
(Air
Products) 90.46 9.90
Dowanol PM Solvent (Dow) 40.87 5.37
Benzyl Alcohol 29.97 3.44
Surfynol DF-l10D
(Air
Products) 3.00 0.36
TiPure 960 (DuPont) 272.48 8.16
Glacial Acetic Acid (Air Products)
5.31
0.61
Water 185.01 22.16
Typical Properties:
Wt
Solids
(%):
65.84 Resin Stoichiometry: 1.3:1
Volume Solids
(36):
40.95
VOC
(lb/gal): 1.53
PVC
(%):
19.94
VOC
(g/l): 184
White G1
oss
Enamel Propert
i
es
:
Pot Life, hr: >4
Gloss,
60
spec,
1
day: >90
Gloss,
60
spec, 4 week: >90
Mix Ratio: 1:l
Mixed Viscosity, cP: 290
Tack Free Time, hr: 1
Hard Dry Time, hr: 6-8
Pencil Hardness, overnight:
HB
Pencil Hardness,
7
days:
H
Cross Hatch Adhesion: 5
1/8" Mandrel Bend: Pass
Direct Impact Resistance, in-lbs: 60
Reverse Impact Resistance, in-lbs: 20
VOC,
lb/gal:
1.6
Volume Solids,
%:
41
PVC,
Yo:
19.9
SOURCE:
Ai
r
Products and Chemicals, Inc.
:
Aquamine 401 Curing
Agent: Formulation 1
Enamels
61
Anquamixe-401/Sol
id
Resin Dispersion
2
:
1
White -Gloss Enamel
Part
A:
Lbs G-a 1
s
Epi -Rez
3520-WY-55
Epoxy Res1 n (She1 1
)
557.4 61.26
Water
45.1 5.41
Part
B:
Anquamine
401
Curing Agent (Air Products)
72.5 7.93
Dowanol PM Solvent
(00,)
Dowanol EPh Solvent (Dow)
Defoamer
Ti
Pure R960 (DuPont)
G1 aci a1 Acetic Acid (Ai
r
Products)
Water
26.0
3.42
17.0 1.85
4.0 0.50
227.7 6.82
2.0
0.23
105.0 12.58
Typical Properties:
Wt
Solids
(%):
74.26
Resin Stoichiometry:
1.58:l
Volume Sol ids
(%)
:
43.03
VOC
(lb/gal)
:
1
.26
PVC
(%I:
15.85
VOC
(g/l):
151
White Gloss Enamel Properties:
Pot Life, hr:
>6
Gloss,
60
spec,
1
day:
>90
Gloss,
60
spec,
4
wk:
>90
Mix Ratio:
2:l
Mixed Viscosity, cP:
360
Tack Free Time, hr:
1
Hard
Dry Time, hr:
6-8
Pencil Hardness, overnight: HB
Pencil Hardness,
7
days:
H
Cross Hatch Adhesion:
5
1/8"
Mandrel Bend: Pass
Di
rect Impact Resistance,
i
n-1 bs.
:
60
Reverse Impact Resistance, in-lbs.:
20
Taber Abrasion, mg loss/lOOO cycles:
90
VOC,
lb/gal:
1.8
Volume
Sol
ids,
'%:
43
PVC,
%:
16.5
SOURCE:
Air
Products and Chemicals, Inc.
:
Anquamine
401
Curing
Agent
:
Formul ati on
2
Enamels-Baking
63
Clear Bake Coatins Pounds Gal lons
Materi a1
:
___~
Epi -Rez 3551 -WY-43 Resi n 617.04 68.56
Ektapro EEP 16.14 2.04
Beetle 80 188.87 20.87
Water 71
.OS
8.53
Typical Coating Properti es
:
Add under agitation:
Total Weight Solids,
%:
51.8
Total Volume Solids,
%:
47.4
Pounds/Gallon: 8.93
Epoxy/Urea, based on solids,
%:
60/40
Volatile Organic Compounds (VOC):
Pounds/Gallon: 1.47
Grams/Li ter
:
176
Viscosity, #4 Ford Cup, seconds: 60-70
Dry Film Thickness: 0.7
mil
Substrate: Bonderite 1000
Bake Schedule at 350F, minutes: 20
Pencil Hardness: 6H
Reverse Impact, in.lbs.: 160
M€K
Double Rubs: 100
Typical Film Properties:
Starting Formulation
No.
2503: Epi-Rez 3551-WY-43 Resin
Phenol
i
c
Clear Bake Coating
Pounds Gal lons
Materi a1
:
Epi -Rez 3540-WY-55 Resin 439.6 48.07
___~
Methyl Isobutyl Ketone 98.8 14.81
Dei oni zed Water 98.8 11.85
Silwet L-7604 Surfactant 2.4 0.28
Santol ink EP-560 193.3 21.15
Dimethylethanolamine 19.1 2.54
Syntex 3981 Accelerator 9.1 1.30
Typical Coating Properties:
Total Weight Solids,
%:
46.8
Total Volume Solids,
%:
42.7
Pounds per Gallon: 8.61
Epoxy/Phenol
i
c,
sol
ids: 60/40
Percent Catalyst, Active, on Resins Solids:
0.5
Volatile Organic Compounds (VOC):
Pounds/Gallon:
2.90
Grams/Li ter: 348
Viscosity, Brookfield,
#5
Spindle at
50
RPM,
cps: 1,200
Dry Film Thickness:
0.5
mils
Substrate: Bonderite 1000
Bake Schedule: 10 minutes at 400F
Pencil Hardness: 6H
Reverse Impact, in.lbs.: 160
MEK
Resistance, double rubs: 100
Typical Film Properties:
Starting Formulation
No.
2504: Epi-Rez 3540-WY-55 Resin
SOURCE: Shell Chemical Co.: Starting Formulations
64
Water-Based Paint Formulations
Clear
Hiqh
Gloss, Bakina Finish
Materi a1
:
Lbs.
Cymel 303 premi x--combi ne
i
n the fol lowing order:
Cymel 303 57.6
Isopropanol 4.5
Nacure 2500-X 4.5
Triethylamine 0.6
Water 28.8
Add in following order with agitation:
Spensol L51 768.1
Cymel 303 Premix 96.0
Aerosol OTS 5.4
Lodyne S107B 5.4
Byk 301 3.1
Cure for 2 hours at
250F
or 30 minutes at 300F.
Analysis:
Ratio of Spensol L51 to Cymel 303: 80:20
Percent Solids, Weight: 33.8
Percent Solids, Volume: 30.1
VOC
(excluding water):
Grams/Li ter
:
189
Pounds/Gallon: 1.6
Formulation 2061-40D
Blue
Metal
1
ic
Urethane Enamel
Material
:
Lbs.
Component A--add in following order with agitation:
Spensol L51 707.9
Premix the following two materials, then add:
A1 umi num Paste #E2255
30.0
Water 31
.2
Add
:
Aurasperse W4123 92.0
Surfynol 104H
4.0
Lodyne 51076 1.5
Component
B:
XAMA-7 7.4
NOTE: Add the above Component
B
to Component
A
prior to
Analysis:
tion and mix well for 5 to
10
minutes.
Percent Sol ids, Weight
:
31
.8
Percent Solids, Volume: 28.4
Viscosity
@
25C, #2 Zahn, Secs.: 25-30
VOC
(excluding water): Grams/Liter: 408
pH:
8.0-8.5
Pounds/Gallon: 3.4
Formulation 2099-19
Gals.
5.76
0.68
0.55
0.10
3.46
87.88
10.55
0.63
0.56
0.38
Gals.
81
.oo
2.34
3.75
11.50
0.50
0.16
0.75
appl
i
ca-
SOURCE:
Reichhold Chemicals, Inc.
:
Spensol L: Formulations
Enamels-Baking
65
Experirental Water-Reducible Polyester
Gloss
White
Baking Enamel Usina Halox SZP-391
Grind:
W/R
Polyester 72-7203
DMEA
Cyme1 303
Lbs./lOO
Gals. Gms/Liter
170.0 204.0
10.0
12.0
50.0
60.0
Premix the next two raw materials before adding.
n-Butyl Alcohol
Dow Corning 14
R-902 Ti02
Halox SZP-391
Deionized Water
High Speed Disperse to 7 Hegman grind.
Letdown
:
W/R
Polyester 72-7203
DMEA
n-Octyl Alcohol
Troysol LAC
n-Butyl Alcohol
Deionized Water
Mix until uniform
-
Do not aerate!
Hold following for viscosity adjustment.
8.0
9.6
0.8
I
.o
225.0 275.0
15.0
18.0
50.0
60.0
100.0
120.0
15.0
18.0
1
.o
1.8
1.5 1.8
10.0
12.0
325.0 390.0
Deionized Water
55.0
66.0
Formula Constants:
%
Pi
gment/Wt
.
:
23.16
%
Pigment/Vol
.
:
7.25
%
Solids/Wt.: 48.24
Formula Properties:
Density 1
bs.
/gal
.
:
10.36
Density g/L: 1,249
Visc. #2 Zahn (sec.
%
Solids/Vol.: 33.12 pH
@
R.T.:
8.5-9.0
%
PVC:
21.85
VOC,
lbs./gal.: 2.03
VOC,
g/L:
304.5
SOURCE:
Halox Pigments: Suggested Formulation PEG39
:
50-60
66
Water-Based Paint Formulations
Waterborne Acrylic Bake Enamel
The WR-17 study was conducted to demonstrate the improved
corrosion resistance afforded a waterborne system by choosing
a more hydrophobic catalyst, Nacure 155 (DNNDSA), over a more
hydrophilic catalyst, K-Cure 1040 (p-TSA). Free acid catalyst,
rather than the blocked versions, were used in this study,
since the formula already contained
a
neutralizing amine.
A
summary of the formulation, its physical properties and test
results are listed below.
Gri
nd Composition
:
Titanox 2020
Acrysol WS-68
2-Butoxyethanol
n-Butanol
DMEA
0.1.
Water
(Pebble
Mill
Grind to 7t on Hegman)
Letdown Composi
ti
on
:
Acrysol WS-68
n-Butanol
Hexamethoxymethylmelamine
2-Butoxyethanol
*DMEA
(10% in water)
*O.I.
Water
*Used to adjust pH and viscosity
Characteristics:
Pi
gment/Bi nder
:
40/60
Acryl
i
c/Mel ami ne:
80/20
Total Solids,
%:
37.7
Total Resin Solids,
%:
22.6
Wt./gal.
C
25C (lb/gal): 9.65
V.O.C.
(Measured) lb./gal.: 1.84
Application and Cure:
Substrate: Bonderite 1000 (iron phosphated
CRS)
Cure Schedule: 15' at 149C (300F)
Fi
1
m
Thickness
:
0.7-0.8
mi
1
Wt%
15.07
3.97
0.67
0.63
0.90
4.69
43.63
0.54
4.51
3.90
2.20
20.10
Film Properties: Control K-Cure 1040 Nacure 155
p-TSA DNNDSA
Pencil Hardness H-2H
Tukon Hardness, KNH25 13.2
MEK
Rubs (2X) 24
Impact Resistance, (in-lbs.)
Reverse 90-100
Oi
rect 40-50
Crosshatch Adhesion,
%
Loss
100
Salt Spray, 150 hrs. (ASTM 8117)
mm
Creep/Blister: 6-7mm/10 6
H-2H H-2H
13.2 13.0
42 50
20-1 30 90-1
00
30-40 30-40
100 100
7mm/lO 3-4mm/
0
SOURCE:
King Industries: Formulation WR-17
Enamels-Baking
67
Water Reducible Polvester Baking Enamel
In this study Nacorr corrosion inhibitors were incorporated
into a pigmented waterborne polyester system crosslinked with a
high -NH type melamine resin. The Nacorrs were added at a level
of 3%, based on the total formula weight. Since the Nacorrs also
function as dispersing agents, there is a definite advantage in
i
ncorporati ng them
i
nto the di spersi ng stage.
Grind (Pebble Mill):
Ti -Pure R-960
Cargi 11 72-7203
2-Butoxyethanol
Nacorr
Water
DMEA
Letdown
:
Cargi
11
72-7203
DMEA
Cyme1 327
Silwet 7605
(10%
in 2-butoxyethanol)
Water
Control Nacorr
24.00 24.00
18.00
17.81
4.00 2.50
----
3.00
1.31
0.69
6.00 6.19
1
.oo
1
.69
6.67 6.67
1
.oo
1
.oo
37.33 37.14
----
----
Characteristics: Control Nacorr
Pol yester/Mel ami ne Ratio 75/25 75/25
Pigment,
%
24 24
Total Resin Solids,
%
by weight 24 24
Additive level,
%
based on total weight of paint
--
3.0
Film Properties:
Pigment/Bi nder Ratio 1
/I
1
/I
Substrate: Bonderite
1000
Iron Phosphated CRS
Cure: 10 minutes/300F (149C)
Film Thickness: 16-21 microns
Pencil Hardness
Tukon Hardness KHN25
Control N-1151 N-1351
2H-3H 2H-3H H-2H
16.6 17.7 11
.o
MEK Rubs (2X) 65
Impact (i nch
1
bs.
)
,
Reverse 5-10
Di
rect 70-80
Gloss, 60 91.4
Salt Spray, 408 hrs. 13/D3
Film Properties:
Substrate: Bonderite
1000
Iron Phosphated
Cure:
10
minutes/250F (121C)
Film Thickness: 16-21 microns Control
Penci
1
Hardness H-2H
Tukon Hardness KHN25
11.1
MEK Rubs (2x1 12
Impact
(
i
nch
1
bs.
)
,
Reverse (5
Di
rect 60-70
Gloss, 60 93.3
Salt Spray, 408 hrs. 13/MD4
SOURCE: King Industries: Nacorr WR-18
64
5-10
60-70
90.6
2/10
CRS
N-1151
H-2H
12.2
13
<5
60-70
94.7
2/10
24
5-10
60-70
92.2
2/F8
N-1351
HB-F
6.7
12
5-10
50-60
93.3
3F/2
68
Water-Based Paint Formulations
Spensol
L54
White
Bakina
Enamel
____
Materi a1
:
Speneol L54
Water
Ammonium Hydroxide
Surfynol
GA
Aerosol
OT-75
Foamki 11 639AA
Titanox 2101
Lbs.
87.3
75.0
1.9
4.4
2.3
1.1
200.0
Pebble
or
sandmill grind the above materials to
7+
N.S.
Letdown
:
Spensol L54 536.9
Gals.
10.00
9.00
0.25
0.50
0.25
0.15
5.85
61.50
Premix the next four materials, then add under good agitation.
Cyme1 385
DMEA
Isopropanol
Water
Add the following under good agitation:
Surfynol 104H
Versa-Flow 102
Bake schedule: 10 minutes at 300F (150C).
Analysis:
Pigment Volume Concentration, Percent: 18
Pigment/Binder Ratio: 0.8/1
.O
Percent Solids, Weight: 44.7
Percent Solids, Volume: 32.6
Viscosity
@
25C, #4 Ford, Secs.
:
30
Pounds/Gal lon
:
10.3
VOC
(excl udi ng water)
:
Grams/Liter: 240
Pounds/Gal 1 on
:
2
Gloss (60): 60-70
pH: 8.3+-0.3
62.1
5.75
1.8
0.25
6.8 1
.oo
41.7
5.00
2.0
0.25
2.0 0.25
SOURCE:
Reichhold Chemicals, Inc.:
Spensol
L:
Formula
2154-598
Enamels-Baking
69
?-Component Waterborne SysteE
Formulation WR-41 demonstrates the improved performance of a
2-component waterborne system when modified with K-Flex XM-4316,
a polyester-urethane dispersion.
At
both
NCO/OH
ratios, improve-
ments were made in gloss,
MEK
resistance, and flexibility.
NCO/OH
Ratio: 1.1
Acrylic/PU-Dispersion: 80/20
Component
A:
Emulsion E-3275
K-F1 ex XM-4316
Sodium Nitrite (5% aq)
Proglyde
DMM
Edaplan LA 402
Silwet 7001 (5% aq)
Silwet 7605 (25% aq)
Silwet 7604 (25% aq)
Dimethylethanolamine
Component 0:
Bayhydur XP-7063
Formulation Characteristics:
Nonvolatile, theoretical,
%:
46.3
Theoretical
VOC,
g/L,
(lb/gallon): 60, (0.5)
Formulation Propert
Gloss 60,
%:
95
20,
%:
69
Koenig Hardness
Pencil Hardness:
es,
Air-Dry 20-25C,
2
weeks:
sec): 69
H-2H
Knoop Hardness: 2.4
MEK
Double Rubs:
80
Impact, Direct, inch.lb.: >160
Impact, Reverse, inch.lb.: >160
Wt%
71 .38
17.40
0.00
0.89
0.07
0.00
0.25
0.25
0.73
9.03
Formulation Properties, Bake 8OC
20
min. Post-cure 20-25C, 2
weeks
:
Substrate: Bonderite 1000 cold rolled steel
Fi
lm
thickness, micron (mi
1
.
)
:
32+-2 (1.3+-0.1)
NCO/OH Ratio: 1.1 Knoop Hardness: 3.7
Gloss 60,
%:
96
MEK
Double Rubs: 120
Koenig Hardness (sec): 89 Impact, Reverse, inch x lb.: 160
Pencil Hardness: 2H
20,
%:
66 Impact, Forward, inch
x
lb.: ,160
Formulation Preparation:
agitation for approx. 5 minutes.
SOURCE:
King Industries: Preliminary Formulation WR-41
Add component
B
to component
A
under low shear mechanical
Exterior
Paints
and
Related
Products
71
Exterior Flat House Paint
with
ZnO
Inqredi ents:
Pi gment
Gr
i
nd
:
Water
Ucar Pol yphobe 9831 Rheology Modi
f
i
er
Ammonium Hydroxide, 28% Aqueous Solution
Proxel GXL
Colloid 226/35
Colloid 640
Triton Nonionic Surfactant X-100
Propylene G1 ycol
Potassium Tripolyphosphate (KTPP)
Ti -Pure R-706
417-W
Zinc Oxide
Minex 4
Nytal 300
___.
Pounds
236.2
9.5
1.8
2.0
8.5
1.9
3.3
25.9
1.5
225.0
25.0
125.9
50.0
Letdown
:
Ucar Latex 625 426.4
Butyl Carbitol Solvent 10.7
Colloid 640 1.9
Skane
M-8
2.2
Ammonium Hydroxide, 28% Aqueous Solution 0.9
Paint Properties:
Pigment Volume Concentration,
%:
40.0
Volume Solids,
%:
38.0
Weight Solids,
%:
55.6
Weight per Gallon,
lb:
11.59
Stormer,
KU:
95
ICI,
Poise: 1.1
pH
Value: 8.9
Freeze-Thaw Stability, cycles passed: 3
Heat-Age Stability, 120F, weeks passed: 2
Fi
1
m
Properti es
:
Contrast Ratio, 6-mil wet drawdown: 0.969
Reflectance,
%:
91.9
Sheen, 85: 8
Wet Adhesion, gloss alkyd: Excellent
Flow and Leveling: Good
Sag Resistance, mils: >12
Gal lons
28.30
1.10
0.20
0.20
0.80
0.30
0.40
3.00
0.10
6.60
0.60
5.80
2.10
48.40
1.40
0.30
0.30
0.10
SOURCE: Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology
Modifier: Formulation Suggestion E-2483
72
Water-Based Paint Formulations
Exterior Flat House Paint
with
ZnO
Inqredients:
Pigment Grind:
Water
Ucar Polyphobe 102 Rheo. Mod.
Ammonium Hydroxide, 28% Aqueous Solution
Proxel GXL
Col 1 oid 226/35
Colloid 640
Triton Nonionic Surfactant X-100
Propylene G1 ycol
Potassium Tripolyphosphate (KTPP)
Ti
-Pure R-706
417-W Zinc Oxide
Minex 4
Nytal 300
Pounds
227.2
18.5
1.8
2.0
8.5
1.9
3.3
25.9
1.5
225.0
25.0
125.9
50.0
Letdown
:
Ucar Latex 625 426.4
Ucar Filmer
IBT
10.7
Colloid 640 1.9
Skane ME 2.2
Ammonium Hydroxide, 28% Aqueous Solution 0.9
Pai nt Propert
i
es
:
Pi
gment Vol ume Concentration,
%:
40.0
Volume Solids,
%:
38.0
Weight Solids,
%:
55.6
Viscosity, equi 1
i
brated:
Stormer,
KU:
98
ICI,
Poise: 1.5
Freeze-Thaw Stability, cycles passed: 3
Heat-Aged Stability, 120F, weeks passed: 2
Film
Properties:
Contrast Rati
0,
6-mi
1 wet drawdown
:
0.968
Reflectance,
%:
91.9
Sheen, 85: 7
Heat-Aged Stability, 2 weeks at 120F: Pass
Wet Adhesion, gloss alkyd: Excellent
Gal lons
27.30
2.10
0.20
0.20
0.80
0.30
0.40
3.00
0.10
6.60
0.60
5.80
2.10
48.40
1.40
0.30
0.30
0.10
SOURCE:
Ucar Emulsion Systems: Ucar
Latex
625:
Formulation
Suggestion
E-2463
Exterior Paints and Related
Products
73
Exterior
Gloss
White
Inqredients:
Pigment Grind:
Water
Ammonium Hydroxide, 28% Aqueous Solution
Sol vent 142HT
Tamol 165
Potassium Tripolyphosphate (KTPP)
Triton Nonionic Surfactant CF-10
Proxel GXL
Byk 023
Ti -Pure R-706
Letdown
:
Ucar Latex 481
Sol
vent 142HT
Byk 025
Butyl Carbitol Solvent
Water
Ammonium Hydroxide, 28% Aqueous Solution
Ucar Pol yphobe 9831 Rheology Modi
f
i
er
Paint Properties:
Pigment Volume Concentration,
%:
19.8
Volume Solids,
%:
33.9
Weight Solids,
%:
45.8
Weight per Gallon, lb: 10.28
Stormer,
KU:
95
ICI,
Poise:
1.8
pH
Value: 9-9.5
Freeze-Thaw Stability, cycles passed: 0-1
Heat Age Stability, 120F, weeks passed: 4
Volatile Organic Content, g/L: 120
Film Properties:
Gloss, 60:
77
Gloss, 20: 34
F1 ow and Level
i
ng
:
Excel
1
ent
Dry-to-Touch, hours: 2
Recoat, hours: 4-6
Water/Bl
i
ster Resi stance: Good
Pounds
112.0
1
.o
10.0
13.7
0.5
3.0
2.0
2.5
225.0
519.0
10.0
2.0
26.0
85.6
1
.o
14.8
Gallons
13.40
0.10
1.50
1.50
0.03
0.40
0.20
0.30
6.80
58.60
1.50
0.30
3.30
10.10
0.10
1.70
SOURCE:
Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology
Modi
f
i
er
:
Formulation Suggestion E-2482
74
Water-Based Paint Formulations
Exterior House Paint
Materi a1
:
Grind:
Water
Nuosept
95
(Nuodex)
Tamol
731
(Rohm and Haas)
Igepal
CO-630
(GAF)
Ti-Pure
R-902
(DuPont)
Beaverwhite
325
Talc (Cyprus)
325
W.G.
Mica (Unimin)
FCA (Foam Control Agent)
Premix and add:
Ethylene Glycol
Texanol (Eastman)
Natrosol Plus
330
PA (Aqualon)
Letdown
:
Water
248-5809
(McWhorter)
FCA (Foam Control Agent)
Water
Properties:
Pigment Volume Content,
%:
31.2
%
Nonvolatile
(by
weight):
54.6
%
Nonvolatile (by volume):
39.3
VOC.
g/l:
126
Stormer Viscosity.
K.U.:
90+-5
IC1
Viscosity, Poise:
1+-0.1
Gloss at
60,
%:
0-5
Recommended Products:
Agitan
260, 315
or
731
-
Lbs
101.6 12.20
1.5 0.16
7.5 0.82
3.4 0.38
213.3 6.23
111.7
1.07
25.4 4.99
4.5
0.20
23.6 2.54
5.9 0.74
4.0 0.36
125.0 15.01
437.8 48.03
3.0 0.39
50.0 6.10
SOURCE:
King Industries: Formulation WR-39:
FCA's
for Trade Sales
Paint
Exterior Paints and Related
Products
75
Exterior House Paint
-
Tint Base
Inaredients:
Pigment Grind:
Water
Ucar Polyphobe 102 Rheo. Mod.
Ammoni um Hydroxide, 28% Aqueous Sol uti on
Proxel GXL
Tamol 1124
Colloid 640
Triton Nonionic Surfactant N-101
Propylene Glycol
Tronox CR-828
Minex 4
Hydrite Flat
D
Pounds
209.6
19.6
1.8
2.0
5.0
1.9
3.2
25.9
150.0
125.0
75.0
Gal 1 ons
25.20
2.10
0.20
0.20
0.50
0.30
0.40
3.00
4.40
5.80
3.50
Letdown
:
Ucar Latex 625 455.9 51.80
Ucar Filmer IBT 11.4 1.40
Colloid 640 1.9 0.30
Troysan Polyphase AF-1 7.3 0.80
Ammonium Hydroxide, 28% Aqueous Solution 0.9 0.10
Paint Properties:
Pigment Volume Concentration,
%:
35.8
Volume Solids,
%:
38.0
Weight Solids,
%:
53.2
Viscosity, equilibrated:
Stormer,
KU:
91
ICI,
poise: 1.4
Freeze-Thaw Stability, cycles passed: 3
Heat-Aged Stability, 120F, weeks passed: 2
Fi
lm
Properties:
Contrast Ratio, 6-mil wet drawdown: 0.956
Reflectance,
%:
90.1
Sheen, 85: 7
Color Acceptance: Excellent
Color Float: Good
Wet Adhesion, 4-hr: Excellent
Flow and Leveling, ASTM D-4062: 8
Film Build, sq.ft./gal.: 411
Low
Temperature Coalescence:
sealed: 10
unsealed: 10
SOURCE:
Ucar Emulsion Systems: Ucar Latex
625:
Formulation
Suggestion E-2460
76
Water-Based Paint Formulations
Exterior Senialoss
~___
Pounds Gal 1 ons
Inqredi ent
s
:
Pigment Grind:
Water
Nuosept
95
Propylene G1 ycol
Tamol
1124
Ammonium Hydroxide
(28%
Aqueous Solution)
Triton Nonionic Surfactant
N-57
Colloid
653
Ti -Pure
R-700
Letdown
:
Water
Ucar Pol yphobe
102
Rheology Modi
f
i
er
Ucar Latex
2300
Ucar Filmer IBT
Col loid
653
Troysan Polyphase AF-1
Triton Anionic Surfactant GR-7M
Paint Properties:
Pigment Volume Concentration,
%:
22.0
Volume Solids,
%:
32.6
Weight Solids,
%:
47.2
Weight per Gallon, lb:
10.43
Stormer,
KU:
99
ICI,
Poise:
1
.26
pH Value:
8.0
Freeze-Thaw Stability, cycles passed:
7
Film Properties:
Gloss,
60: 78.3
Gloss,
20: 39.6
Contrast Ratio, 6-mil wet drawdown:
0.964
Reflectance,
%:
91.8
Scrub Resistance, cycles passed:
161
150.0 18.96
2.3 0.25
60.5 7.00
7.4 0.75
2.0 0.25
2.1 0.25
1.9 0.25
250.0 7.16
91.5 10.99
13.1
1
.so
447.7 50.88
11.2 1.41
2.8 0.37
7.3 0.75
1.1 0.13
SOURCE:
Ucar Emulsion Systems: Formulation Suggestion
E-2263
Exterior Paints and Related Products
77
Exterior Semisloss Formulation
Inqredients:
Pi
gment
Gr
i
nd
:
Water
Ucar Polyphobe 102 Rheology Modifier
Ammonium Hydroxide, 28% Aqueous Solution
Propylene Glycol
Troysan 586
Tamol 1124
Colloid 643
Triton Nonionic Surfactant
N-57
Tronox CR-828
Polygloss 90
Pounds
190.0
17.4
1.8
60.5
1.8
5.3
1.8
2.1
250.0
25.0
Letdown
:
Water
1
5.5
Ucar Polyphobe 102 Rheology Modifier
)
Premix 4.4
NeoCar Latex 2300 474.4
Colloid 643 1.8
Ucar Filmer
IBT
15.8
Troysan Polyphase
AF-1
7.4
Triton Anionic Surfactant GR-7M 1.1
Ammonium Hydroxide, 28% Aqueous Solution 1.8
Gal 1 ons
22.80
2.00
0.23
6.99
0.19
0.54
0.23
0.25
7.50
1.15
0.66
0.51
53.61
0.23
1.99
0.74
0.13
0.23
Note:
If
wet adhesion is desired, blending with an acrylic
resin, such as Ucar Latex 625, is recommended.
Pai nt Properti es
:
PVC,
%:
23.6
Volume Solids,
%:
38.7
Weight Solids,
%:
52.6
Weight per Gallon, lb: 10.68
Stormer,
KU:
99
ICI,
poise: 1.5
pH Value: 8.7
Freeze-Thaw Stability, 3 cycles: Pass
Heat-Aged Stability, 4 weeks at 140F: pass
Fi
1
m
Propert
i
es
:
Reflectance,
%:
92.3
Gloss, 20: 19
Gloss, 60: 59.5
Flow and Leveling: Exc
Color Acceptance: Exc
SOURCE:
Ucar Emulsion Systems: NeoCar Polymers: Formulation
Suggest
i
on E-2264
78
Water -Based Paint Formulations
Exterior Tint Base Formulation
I
nqred
i
en
t
s
:
Pigment Grind:
Water
Ucar Pol yphobe 102 Rheology Modi
f
i
er
Ammonium Hydroxide, 28% Aqueous Solution
Troysan 586
Tamol 1124
Colloid 640
Triton Nonionic Surfactant N-101
Propylene G1 ycol
Tronox CR-828
Minex 4
Hydrite Flat
D
Pounds
197.4
15.2
1.8
2.0
5.0
1.9
3.2
25.9
150.0
125.0
75.0
Letdown
:
Water 3.8
Ucar Latex 625 319.2
Ucar Latex 461 145.5
Ucar Filmer IBT 11.4
Colloid 640 1.9
Troysan Polyphase AF-1 7.3
Ammonium Hydroxide, 28% Aqueous Solution 0.9
Pai nt Propert
i
es
:
Pi gment Vol ume Concentrat
i
on,
%:
35.8
Volume Solids,
%:
38.0
Weight per Gallon, lb: 10.9
Stormer,
KU:
83
ICI,
Poise: 0.95
pH Value: 9.6
Freeze-Thaw Stability, cycles passed: 3
Heat-Age Stability, 12OF, weeks passed: 2
Ratio of Ucar Latexes 625:461: 70:30
Fi
lrn
Properties:
Sheen. 85: 9.2
Gal lons
23.7
1.7
0.3
0.2
0.5
0.3
0.4
3.0
4.4
5.8
3.5
0.5
36.3
16.9
1.4
0.3
0.8
0.1
Contrast Ratio, 6-mil wet drawdown: 0.952
Dry Adhesion (untreated aluminum, galvanized steel, a1 kyd
Wet Adhesion (untreated aluminum, galvanized steel, alkyd
B1
i
steri ng (untreated a1 umi num, gal vani zed steel, a1 kyd
and latex chalk): Exc
and latex chalk, gloss alkyd): Exc
and latex chalk): Exc
SOURCE:
Ucar Emulsion Systems: Ucar Latex
461:
Formulation
E-2474
Exterior Paints and Related Products
79
Exterior Trim Formulation
Modi
f
i
ed
Vi
nvl
Acrvl
i
c
Paint
Inqredi ents:
Pi
ament
Gri
nd:
WaTer
Ucar Pol yphobe 102 Rheology Modi
f
i
er
Ammonium Hydroxide, 28% Aqueous Solution
Propylene Glycol
Nuosept 95
Tamol 1124
Colloid 643
Triton Nonionic Surfactant N-57
Tronox CR-828
Polygloss 90
Letdown
:
Water
Ucar Pol yphobe 1 14 Rheology Modi
f
i
er
Butyl Carbitol Solvent
Ucar Filmer I8T
Ucar Latex 3796
Ucar Latex 633G
Colloid 643
Troysan Polyphase AF-1
Byk 346
Ammonium Hydroxide, 28% Aqueous Solution
Pai nt Propert
i
as
:
Pigment Volume Concentration,
%:
24.2
Volume Solids,
%:
35.0
Weight per Gallon, lb: 10.7
Stormer, KU: 96
ICI,
Poise: 1.2
pH
Value: 7.6
Freeze-Thaw Stability, cycles passed: 3
Heat-Age Stability, 120F, weeks passed: 2
Ratio
of
Ucar Latexes 379G:6336: 70:30
Film Properties:
Gloss, 60: 46
Gloss, 20: 10
Contrast Ratio, 6-mil wet drawdown: 0.967
Reflectance,
%:
91.8
Block Resistance: 8
Pounds
98.5
19.3
1.8
59.6
2.3
7.3
1.9
2.1
246.3
24.6
78.0
6.5
20.5
10.2
316.1
162.0
2.8
7.2
1.1
1.8
Gal 1 ons
11.8
2.2
0.3
6.9
0.2
0.7
0.3
0.2
7.2
1.1
9.4
0.7
2.6
1.3
34.9
18.4
0.4
0.7
0.1
0.3
Dry Adhesion (untreated aluminum, galvanized steel, a1 kyd
Wet Adhesion (untreated aluminum, galvanized steel, alkyd
Blistering (untreated aluminum, galvanized steel, alkyd
and latex chalk): Exc
and latex chalk, gloss alkyd); Exc
and latex chalk): Exc
SOURCE:
Ucar Emulsion Systems: Ucar Latex
0336:
Formulation
E-2471
80
Water-Based Paint Formulations
Exterior Trim Formulation
Ingredients:
Pigment Grind:
Water
Ucar Pol yphobe 102 Rheology Modi
f
i
er
Ammonium Hydroxide, 28% Aqueous Solution
Propylene Glycol
Troysan 586
Tamol 1124
Colloid 643
Triton Nonionic Surfactant N-57
Tronox CR-828
Polygloss
90
Letdown
:
Water
NeoCar Latex 2300
Ucar Latex 6336
Colloid 643
Ucar Filmer IBT
Troysan Polyphase
AF-1
Triton Anionic Surfactant GR-7M
Ammonium Hydroxide, 28% Aqueous Solution
Paint Properties:
Pigment Volume Concentration,
%:
24.0
Volume Solids,
%:
35.5
Weight per Gallon, lb:
10.7
Stormer,
KU:
93
ICI,
Poise: 1.4
pH Value: 8.9
Freeze-Thaw Stability, cycles passed: 3
Heat-Age Stability, 12OF, weeks passed: 2
Pounds
190.6
21.8
1.8
60.5
1.8
5.3
1.8
2.1
250.0
25.0
7.2
365.4
107.8
1.8
15.8
7.4
1.1
1.8
Gal
1
ons
22.9
2.5
0.3
7.0
0.2
0.5
0.3
0.2
7.3
1.1
0.9
41.3
12.3
0.3
2.0
0.8
0.1
0.3
Film
Properties:
Gloss, 60: 77
Gloss, 20: 28
Contrast Ratio, 6-mil wet drawdown: 0.977
Reflectance,
%:
92.2
Block Resistance, 1-week dry,
RT:
8
Dry Adhesion (untreated aluminum, galvanized steel,
Wet Adhesion (untreated aluminum, galvanized steel,
61
i
steri ng (untreated a1 umi num, galvanized steel, a1 kyd
alkyd chalk): Exc
alkyd chalk, gloss alkyd): Good
chalk): Good
SOURCE:
Ucar Emulsion Systems: Ucar Latex
6336:
Formulation
E-2472
Exterior Paints and Related Products
81
Exterior Trim Formulation
Inaredients:
Pigment Grind:
Water
Ucar Polyphobe 102 Rheology Modifier
Ammoni um Hydroxi de, 28% Aqueous Sol uti on
Propylene G1 ycol
Nuosept 95
Tamol 1124
Colloid 643
Triton Nonionic Surfactant N-57
Tronox CR-828
Polygloss 90
Pounds
98.5
19.3
1.8
59.6
2.3
7.3
1.9
2.1
246.3
24.6
Letdown
:
Water
Butyl Carbitol Solvent
Ucar Filmer I8T
Ucar Latex 626
Ucar Latex 471
Colloid 643
Troysan Polyphase AF-1
Byk 346
Ammonium Hydroxide, 28%
47.2
20.5
10.2
372.5
129.4
2.8
7.2
1.1
Aqueous Sol uti on 1.8
Paint Properties:
Pigment Volume Concentration,
%:
24.2
Volume Solids,
%:
35.0
Weight per Gallon, lb: 10.5
Stormer,
KU:
89
ICI,
Poise: 1.5
pH
Value:
8.8
Freeze-Thaw Stability, cycles passed: 3
Heat-Age Stability, 120F, weeks passed: 2
Ratio
of
Ucar Latexes 626:Ucar 471: 70:30
Fi 1
m
Propert
i
es
:
Gloss, 60: 53
Gloss, 20: 15
Contrast Ratio, 6-mil wet drawdown: 0.97
Reflectance,
%:
92.2
Block Resistance: 9
Gallons
11
.8
2.2
0.3
6.9
0.2
0.7
0.3
0.3
7.2
1.1
5.7
2.6
1.3
42.8
14.9
0.4
0.8
0.1
0.3
Dry Adhesion (untreated aluminum, galvanized steel, alkyd
Blistering (untreated aluminum, galvanized steel,
and latex chalk): Exc
latex chalk): Exc
latex chalk, gloss alkyd): Exc
Wet Adhesion (untreated aluminum, galvanized stee
SOURCE:
Ucar Emulsion Systems: Ucar Latex 471: Formu
E-2475
alkyd and
,
alkyd and
ation
82
Water-Based
Paint
Formulations
Exterior White Flat House Paint
Inqredi ents:
Pi gment
Gr
i
nd
:
Water
Ucar Polyphobe 102 Rheo.
Mod.
Ammonium Hydroxide, 28% Aqueous Solution
Proxel
GXL
Tamol 1124
Col loi d 640
Triton Nonionic Surfactant N-101
Propylene G1 ycol
Ti
-Pure
R-706
Minex 4
Nytal 300
Pounds
234.5
19.6
1.8
2.0
5.0
1.9
2.1
25.9
225.0
135.4
75.0
Letdown
:
Ucar Latex 625 408.6
Ucar Filmer IBT 10.2
Colloid 640 1.9
Troysan Polyphase
AF-1
7.3
Ammonium Hydroxide, 28% Aqueous Solution 1.8
Paint Properties:
Pigment Volume Concentration,
%:
42.5
Volume Solids,
%:
38.0
Weight Solids,
%:
55.7
Viscosity, equi
1
i
brated:
Stormer,
KU:
90
ICI,
Poise:
1.3
Freeze-Thaw Stability, cycles passed: 3
Heat-Aged Stability, 120F, weeks passed: 2
Film Properties:
Contrast Ratio, 6-mil wet drawdown: 0.965
Reflectance,
%:
91.9
Wet Adhesion, gloss alkyd: Excellent
Chalk Adhesion, ASTM
#5:
Good
Gal 1 ons
28.20
2.30
0.20
0.20
0.50
0.30
0.30
3.00
6.60
6.20
3.20
46.40
1.30
0.30
0.80
0.20
SOURCE:
Ucar Emulsion Systems: Ucar Latex
625:
Formulation
Suggestion E-2459
Exrenor
Paints
and Related
Products
83
Exterior
White
Trim House Paint
Inqredients:
Pi Qment
Gri
nd:
Water
Ucar Polyphobe 102 Rheo. Mod.
Ammonium Hydroxide, 28% Aqueous
Troy 586
Tamol 1124
Colloid 640
Triton Nonionic Surfactant N-57
Propylene
G1
ycol
Ti -Pure R-902
Polygloss 90
Letdown
:
Ucar Latex 625
Ucar Filmer IBT
Pounds
208.1
19.6
Solution 1.8
2.0
7.4
1.9
2.1
60.5
237.5
50.0
Gal
1
ons
24.90
2.30
0.20
0.20
0.70
0.30
0.20
7.00
7.10
2.30
459.3 52.20
11.5 1 .50
Colloid 640 2.8 0.40
Troysan Polyphase AF-1 7.3
0.80
Ammonium Hydroxide, 28% Aqueous Solution 0.9 0.10
Byk 346 1.1 0.10
Paint Properties:
Pigment Volume Concentration,
%:
27.0
Volume Solids,
%:
34.0
Weight Solids,
%:
48.6
Viscosity, equilibrated:
Stormer, KU: 91
ICI,
Poise: 1.3
Freeze-Thaw Stability, cycles passed: 3
Heat-Aged Stability, 120F, weeks passed: 2
Film Properties:
Contrast Ratio, 6-mil wet drawdown: 0.968
Reflectance,
%:
93.4
Gloss, 60: 40
Wet Adhesion, gloss alkyd, 4-hr: Excellent
Adhesion, 1 week, ASTM D3359 (wet):
alkyd: 4A
aluminum: 5A
Chalk Adhesion, ASTM #5: Good
Blistering, 24 hrs.
:
aluminum: 10
alkyd chalk (ASTM
#5):
8F
Flow and Leveling, brushed:
7
SOURCE: Ucar Emulsion Systems: Ucar Latex 025: Formulation
Suggestion E-2402
84
Water-Based Paint Formulations
Good
Quality
White
Exterior
Flat Paint
for
Masonry
Inaredients:
Pi gment
Gri
nd
:
Water
Cellosize Hydroxyethyl Cellulose QP-15,000
Potassium Tripolyphosphate (KTPP)
Nuosept 95
Colloid 643
Triton Nonionic Surfactant N-101
Tamol 850
Ti-Pure R-902
Eagle 417W
Snowf 1 ake
Minex
4
AMP-95
Pounds
199.9
2.5
2.0
1.5
2.0
3.0
1
.o
7.0
220.0
25.0
100.0
131.7
Gallons
24.00
0.22
0.09
0.16
0.26
0.34
0.13
0.71
6.60
0.53
4.44
6.07
Disperse at high speed for 15 minutes. Do not exceed 120F.
Dispersion should be 3-4 on Hegman.
Letdown
:
Water
1
127.1 15.26
Propylene G1 ycol
)
Premi x 40.0 4.62
Cellosize Hydroxyethyl Cellulose
)
QP-15,000
)
2.3 0.20
Colloid 643 2.0 0.26
NeoCar Latex 2300 305.0 34.47
Ucar Filmer IBT 13.0 1.64
Paint Properties:
PVC,
%:
50.0
Volume Solids,
%:
35.3
Weight Solids,
%:
54.6
Weight per Gallon, lb: 11.98
Stormer,
KU:
88-93
ICI,
poise: 0.8-1.0
pH Value: 8.0-8.5
Heat-Aged Stability,
4
weeks at 140F: Pass
Film Properties:
Reflectance,
%:
89.4
Gloss, 60: 2
Sheen, 85: 3
Contrast Ratio, 3-mil
film:
0.970
ASTM Scrub Cycles, with shim Failure: >3000
SOURCE:
Ucar Emulsion Systems: NeoCar Polymers: Formulation
Suggest
i
on E-2252
Exterior Paints and Related Products
85
Good
Quality White Exterior Flat Paint for Wood
Ingredients:
Pigment
Gri
nd:
Water
Cellosize Hydroxyethyl Cellulose
QP-
Potassium Tripolyphosphate (KTPP)
Nuosept
95
Colloid 643
Triton Nonionic Surfactant N-101
Tamol 850
Ti
-Pure R-902
Eagle 417W
Snowf 1 ake
Minex
4
AMP-95
Pounds
195.8
15,000 2.5
2.0
1.5
2.0
3.0
1
.o
7.0
245.0
50.0
70.0
85.0
Gallons
23.50
0.22
0.09
0.16
0.26
0.34
0.13
0.71
7.35
1.07
3.11
3.92
Disperse at high speed for 15 minutes. Do not exceed 120F.
Dispersion should be 3-4 on Hegman.
Letdown
:
Water
)
51
.5
6.17
Propylene G1 ycol
1
40.0 4.62
Cellosize Hydroxethyl Cellulose
)
Premix
QP-15,OOO
1
2.0 0.17
Colloid 643 2.0 0.26
NeoCar Latex 2300
405.0
45.77
Ucar Filmer
IBT
17.0 2.15
Note:
If
wet adhesion is desired, blending with an acrylic
resin, such as Ucar Latex 625, is recommended.
Paint Properties:
PVC,
%:
39.8
Volume Solids,
%:
38.8
Weight Solids,
%:
56.6
Weight per Gallon,
lb:
11.82
Stormer,
KU:
88-93
ICI,
poise: 0.8-1
.O
pH value: 8.0-8.5
Heat-Aged Stability,
4
weeks at 140F: Pass
Reflectance,
%:
90.8
Gloss, 60: 3
Sheen, 85: 6
Contrast Ratio, 3-mil
film:
0.976
ASTM Scrub Cycles, with shim Failure: >3000
Fi 1
m
Propert
i
es
:
SOURCE:
Ucar Emulsion Systems: NeoCar Polymers: Formulation
Suggestion E-2253
86
Water-Based
Paint
Formulations
Ingrediernrs;
Pigment
Gri
nd:
Water
Ucar Polyphobe
Ammoni um Hydrox
Sol
vent 142HT
Tamol 165
Potassi um Tri po
Triton Nonionic
Proxel
GXL
Byk 023
Ti-Pure R-706
Greqson
Drive
Gloss
White
Pounds
112.0
02 Rheo. Mod. 10.0
de, 28% Aqueous Solution 1
.o
10.0
13.7
yphosphate (KTPP)
0.5
Surfactant CF-10 3.0
2.0
2.5
225.0
Letdown
:
Ucar Latex 481 519.0
Sol vent 142HT 10.0
Byk 025 2.0
Butyl Carbitol Solvent 26.0
Water 76.4
Ammonium Hydroxide, 28% Aqueous Solution 1
.o
Ucar Polyphobe 106HE Rheo. Mod. 14.0
Paint Properties:
Pigment Volume Concenrtation,
%:
19.8
Volume Solids,
%:
33.9
Weight Solids,
%:
45.8
Stormer, KU: 87
ICI,
Poise: 1.0
pH Value: 9-9.5
Freeze-Thaw Stab
Heat-Age Stabili
VOC,
grams per 1
Film Properties:
Gloss, 60: 90
Gloss. 20: 70
lity, cycles passed: 0-1
y. 12OF, weeks passed: 4
ter: 120
Gal lons
13.40
1.20
0.10
1
.50
1.50
0.03
0.40
0.20
0.30
6.80
____
58.60
1.50
0.30
3.30
9.17
0.10
1
.60
F1 ow and Level
i
ng
:
Excel 1 ent
Dry-to-Touch, hours: 2
Recoat, hours: 4-6
Water/Blister Resistance: Good
SOURCE:
Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion
E-2256
Exterior Points
and
Related
Products
87
High
Quality Exterior
Semi
Gloss Paint
Materi a1
:
Grind:
Water
Natrosol Plus (Aqualon)
Acrysol
RM
1020 (Rohm and Haas)
Acrysol
RM
825 (Rohm and Haas)
Pigment Disperser NL (BASF)
TKPP (10% in water)
Proxel
GXL
(IC1 Biocides)
FCA (Foam Control Agent)
Kronos 2310 (Kronos)
Letdown
:
Propylene glycol
Dowanol DPnB
(Dow)
Mineral
Spi
ri
ts
Acronal
DS
6183 (BASF)
FCA (Foam Control Agent)
Water
Propert
i
es
:
Pigment Volume Content,
%:
25.5
%
Nonvolatile (by weight): 45.2
%
Nonvolatile (by volume): 32.1
VOC,
g/l: 107.0
Stormer Viscosity,
K.U.:
105t-5
IC1
Viscosity, Poise: 1.5+-2
Gloss at 60,
%:
67.0
Weight per Gallon, lbs/gallon:
%
foam on manufacturing:
Recommended Product:
Alternative Products:
SOURCE:
King Industries: Formulat
Agitan 731: High performance
w
Agitan 260 or Agitan 315
62.50 5.99
0.52 0.05
31.32 3.00
7.31 0.70
1.04 0.10
3.13 0.30
2.09 0.20
3.13 0.30
261 .02 25.02
41.76 4.00
10.44 1
.oo
10.44 1
.oo
417.63
40.00
3.13 0.30
188.46 18.04
Agitan 731
10.6
0.66
th excel lent persi stency
on
WR-39-2
88
Water-Based Paint Formulations
High Sheen White House Paint
Inqredients: Pounds
Pigment Grind:
Water 203.9
Ucar Polyphobe 102 Rheo. Mod. 15.2
Ammoni um Hydroxi de, 28% Aqueous Sol uti on 1.8
Troy 586 2.0
Tamol 1124 4.9
Colloid 643 1.9
Triton Nonionic Surfactant
N-101
2.1
Propylene Glycol 34.6
Kronos 2310 225.0
Minex 10 71
.O
Burgess
No.
98
75.0
Letdown
:
Ucar Latex 625
Ucar Fi lmer IBT
Col loid 643
Troysan Polyphase
AF-1
Byk 346
Ammmonium Hydroxide, 28% Aqueous Solut
Paint Properties:
Pigment Volume Concentration,
%:
35
Volume Solids,
%:
38.1
Weight Solids,
%:
54.0
Viscosity, equi 1
i
brated:
Stormer,
KU:
88
ICI,
Poise: 1
.O
461.9
11.5
1.9
7.3
1.1
on 0.9
2
Gallons
24.48
1.75
0.25
0.20
0.48
0.25
0.25
4.00
6.75
3.27
3.42
52.19
1.45
0.25
0.75
0.13
0.13
Freeze-Thaw Stability, cycles passed: 3
Heat-Aged Stability, 120F, weeks passed: 2
Film
Properties:
Contrast Ratio, 6-mil wet drwadown: 0.984
Reflectance,
%:
92.2
Sheen, 85: 64.0
Wet Adhesion, gloss alkyd: Excellent
Chalk Adhesion, ASTM
#5:
Good
SOURCE:
Ucar Emulsion Systems: Ucar Latex
625:
Formulation
Suggestion
E-2461
Exterior Paints
and
Related Products
89
Low
VOC
Exterior House Paint
Materi a1
:
Grind:
Natrosol 250 MHR 2.5% (Aqualon)
Water
Tamol 731 (Rohm and Haas)
KTPP
Triton CF-10 (Rohm and Haas)
Kathon
LX
1.5% (Rohm and Haas)
FCA (Foam Control Agent)
Ti -Pure R-902
(
DuPont
)
Eagle Zinc 417W (Eagle)
Minex
4
(Indusmin)
Attagel 50 (Englehard)
Letdown
:
Emulsion E-3122 (Rohm and Haas)
FCA (Foam Control Agent)
Acrysol RM-2020 (Rohm and Haas)
Natrosol 250 MHR 2.5% (Aqualon)
Skane M-8 (Rohm and Haas)
Water
Lbs
127.0
85.0
16.0
1
.o
1
.o
1.7
2.0
250.0
25.0
144.0
5.0
301
.O
2.0
15.0
29.0
2.0
149.0
%Wt
15.2
10.2
1.8
0.1
0.1
0.2
0.3
7.5
0.5
6.6
0.2
34.0
0.3
0.2
1.7
3.5
17.9
Properties:
Pigment Volume Content,
%:
43.5
%
Nonvolatile (by weight): 52.4
%
Nonvolatile (by volume): 34.3
Stormer Viscosity, K.U.: 92t-5
IC1
Viscosity, Poise: 1.3+-2
Recommended Product:
Agitan 731: Superior performance
in
both application and
production of paint. Fine tuning
will
optimize
performance and may provide a cost advantage.
Agitan 315: Excellent foam control in all aspects
of
paint
manufacture and application. Lower cost alter-
native to 731.
Alternative Product: Agitan 260
SOURCE: King Industries: Formulation WR-39-4
90
Water-Based Paint Formulations
Quality Exterior Flat Formulation
Ingredients:
Pigment
Gri
nd:
Water
Cellosize Hydroxyethyl Cellulose QP-15,000
Potassium Tripolyphosphate (KTPP)
Drewpl us L-475
Triton Nonionic Surfactant N-101
Tamol 850
AMP-95
Ti
-Pure R-902
Eagle 417W
Imsil A25
Celite 499
Water
Letdown
:
Water
1
Natrosol Plus 330
)
premix
Propylene Glycol
Drewpl us L-475
Ucar Latex 6390
NeoCar Latex 2300
Ucar Filmer I8T
Paint Properties:
Pigment Volume Concentration,
%:
48.7
Volume Solids,
%:
30.0
Weight per Gallon, lb: 11.5
Stormer,
KU:
83-88
ICI,
Poise: 0.9
pH Value: 8.9
Low
Temperature Coalescence: Pass
Film Properties:
Gloss, 60:
2
Sheen, 85: 2
Contrast Ratio, 6-mil wet drawdown: 0.990
Reflectance,
%:
88.4
Scrub Resistance, cycles passed: >1500
Dry Adhesion, crosshatch tape pull: Pass
Wet Adhesion, cycles passed: >2000
50-mil Mudcracking: Pass
Pounds
183.3
2.5
2.0
2.0
4.0
7.0
1.5
220.0
50.0
130.0
20.0
16.7
188.2
4.0
30.0
2.0
65.0
208.0
14.0
Gal 1 ons
22.0
0.2
0.1
0.3
0.5
0.7
0.2
6.6
1.1
5.9
1
.o
2.0
22.6
0.4
3.5
0.3
7.4
23.5
1.7
SOURCE:
Ucar Emulsion Systems: Ucar Latex
8390:
Formulation
E-2477
Exterior Paints and Related
Products
91
Qual
i
ty Exterior Flat
Paint
Inaredients;
Pigment Grind:
Water
Cellosize Hydroxyethyl Cellulose ER-30,000
Nuosept 145
Tamol 960
Potassi
um
Tripolyphosphate (KTPP)
Triton Nonionic Surfactant N-101
Propylene G1 ycol
Colloid 640
Ti -Pure R-900
Eagle 417W
Mica 325WG
~~p-95
IT-325
Letdown
:
Ucar Latex 379G
Ucar Filmer IBT
Skane M-8
Colloid 640
Paint Properti 8s:
PVC,
%:
40.1
Volume Solids,
%:
39.3
Weight Solids,
%:
57.7
Weight per Gallon, lb: 11.9
Stormer, KU: 100
ICI, poise: 0.9
pH,
initial: 8.9
Freeze-thaw Stability, 3 cycles: Pass
Heat-Aged Stability, 2 weeks at 120F: Pass
Film
Properties:
Ref
1
ectance,
%:
90.5
Sheen, 85: 5.1
Contrast Ratio, 3-mil film: 0.966
Pounds
252.1
4.0
2.3
10.5
2.0
2.2
1
.o
34.5
1.9
225.0
25.0
25.0
175.0
408.3
17.8
2.2
1.9
Gal
1
ons
30.27
0.36
0.25
1
.oo
0.10
0.25
0.13
4.00
0.25
6.54
0.54
1.07
7.37
45.12
2.25
0.25
0.25
SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-19928
92
Water -Based Paint Formulations
Quality White Exterior Trim Paint
Inaredients:
Pigment Grind:
Water
Ucar Pol yphobe 9831 Rheology Modi
f
i
er
Ammonium Hydroxide, 28% Aqueous Solution
Propylene Glycol
Nuosept 95
Tamol 1124
Col loi
d
643
Triton Nonionic Surfactant
N-57
Tronox CR-828
Polygloss 90
Pounds
98.5
5.0
1.8
59.6
2.3
7.3
1.9
2.1
246.3
24.6
Letdown
:
Water
Ucar Polyphobe 9831 Rheology Modifier)
Water
)
Premix
Butyl Carbitol Solvent
Ucar Latex 626
Col loi d 643
Troysan Polyphase
AF-1
Triton Anionic Surfactant
GR-7M
Ammonium Hydroxide, 28% Aqueous Solution
16.7
5.8
44.7
30.7
496.7
2.8
7.2
1.1
0.9
Gallons
11.79
0.60
0.20
6.90
0.30
0.69
0.30
0.30
7.39
1.18
1.99
0.69
5.38
3.04
57.08
0.39
0.79
0.10
0.10
Paint Properties:
Pigment Volume Concentration,
%:
24.2
Volume Solids,
%:
35.0
Weight Solids,
%:
49.7
Weight per Gallon, lb: 10.56
Stormer,
KU:
95
ICI,
Poise: 1.4
pH Value: 8.9
Freeze-Thaw Stability, cycles passed: 3
Heat-Age Stability, 12OF. weeks passed:
2
Film Properties:
Gloss, 60: 71
Gloss,
20:
26
Color Acceptance: Excellent
Flow and Leveling: Excellent
Wet Adhesion,
24-hr
dry: Excellent
SOURCE:
Ucar Emulsion Systems: Ucar Polyphobe Q83l Rheology
Modifier: Formulation Suggestion E-2484
Ingredients:
Pigment Grind:
Water
Ucar Polyphobe
Ammoni um Hydrox
Propylene G1 yco
Nuosept 95
Tamol 1124
Col loi d 643
Triton Nonionic
Tronox CR-828
Polygloss
90
Letdown
:
Water
Exterior Paints and Related Products
93
Quality White Exterior Trim Paint
02 Rheology Modi
f
i
er
de, 28% Aqueous Solut
Surfactant N-57
on
Ucar Pol yphobe 102 Rheology Modi
f
i
er
)
Premi
x
Water
1
Butyl Carbi to1 Sol vent
Ucar Filmer IBT
Ucar Latex 626
Colloid 643
Troysan Polyphase AF-1
Triton Anionic Surfactant GR-7M
Ammonium Hydroxide, 28% Aqueous Solution
Paint Properties:
Pigment Volume Concentration,
%:
24.2
Volume Solids,
%:
35.0
Weight Solids,
%:
49.7
Weight per Gallon, lb: 10.56
Stormer,
KU:
90-95
ICI,
Poise: 1.4
pH Value: 8.9
Freeze-Thaw Stability, cycles passed: 3
Heat-Age Stability, 12OF, weeks passed: 2
Film Properties:
Gloss, 60: 62
Gloss, 20: 15
Color Acceptance: Excellent
Flow and Leveling: Excel lent
Wet Adhesion, 24-hr dry: Excellent
Pounds Gal 1 ons
98.5 11.79
10.7 1.28
1 .8 0.20
59.6 6.90
2.3 0.30
7.3 0.69
1.9 0.30
2.1 0.30
246.3 7.39
24.6 1.18
8.2 0.98
8.6 1.02
44.7 5.38
20.5 2.56
10.2 1.28
496.7 57.08
2.8 0.39
7.2 0.79
1.1 0.10
0.9
0.10
SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-2458
94
Water -Based Paint Formulations
Quality White House Paint with
ZnO
Inqredi ents:
Pigment
Gri
nd:
Water
Cellosize Hydroxyethyl Cellulose ER-30,000
Nuosept
95
Propylene Glycol
Col loi d
226/35
Potassium Tripolyphosphate (KTPP)
Triton Nonionic Surfactant N-101
Col loi d
653
Ti
-Pure
R-902
XX503R
Nytal
300
Minex
4
Pounds
295.6
4.0
2.3
25.9
10.3
1
.o
2.2
1.9
225.0
25.0
100.0
96.4
Letdown
:
Ucar Latex
624 364.2
Ucar Filmer
I8T
9.1
Skane
M8
2.2
Colloid
653 2.8
Ammoni um Hydroxi de,
28%
Aqueous Sol
uti
on
2.0
Paint Properties:
Pigment Volume Concentration,
%:
45.0
Volume Solids,
%:
35.4
Viscosity, equi 1
i
brated:
Stormer,
KU:
82
ICI,
poise:
0.85
Weight per Gallon,
lb:
11.70
Freeze-thaw Stability,
3
cycles: Pass
Heat-Aged Stability,
2
weeks at
120F:
Pass
Fi
1
m
Propert
i
es
:
Contrast Ratio, 6-mil wet drawdown:
0.951
Reflectance,
%:
91
.1
Sheen,
85: 4.0
Flow and Leveling, brushed: Good
Wet Adhesion: Excellent
Gal lons
35.49
0.36
0.25
3.00
1
.oo
0.05
0.25
0.25
6.75
0.54
4.21
4.44
41.39
1
.I5
0.25
0.37
0.25
SOURCE:
Ucar Emulsion Systems: Ucar Latex 624: Formulation
Suggestion E-2426
Exterior Paints
and
Related
Products
95
Urethane Fortified Porch
&
Deck
Enamel
Materi a1
:
Arolon 840-W-39
Water
Colloid 679
Cel losi ze QP4400
Ammonium Hydroxide
Di
sperse-Ayd W28
Kroma Red
RO
7097
Titanox 2101
Durami te
Lbs.
130.5
50.0
1.9
1
.o
1.9
4.4
50.0
5.0
150.0
Gals
.
15.00
6.00
0.25
0.09
0.25
0.50
1.23
0.15
6.61
Add the above in order under good agitation, then pebble or sand
mill
grind to 7 Hegman.
Letdown
:
Arolon 840-W-39
Spensol
L51
Ucar
SCTI
00
us
I
Gals_
304.5 35.00
304.1 34.75
2.3 0.25
Analysis:
Pigment Volume Concentration, Percent: 22.0
Pigment/Binder Ratio:
0.8/1
.O
Percent Solids, Weight: 46.9
Percent Solids, Volume: 36.4
Viscosity
(a
25C,
KU:
85-95
Pounds/Gal lon
:
IO.
1
VOC
(excluding water):
Grams/Li ter: 150
Pounds/Gallon: 1.3
pH: 8.5+-0.3
SOURCE:
Reichhold Chemicals, Inc.
:
Spensol
L:
Formula
2262-80
96
Water-Based
Paint
Formulations
Weather Barrier Formulat-
IlrpdEnts
:
Pigment Grind:
Water
Cellosize Hydroxyethyl Cellulose ER-52M
Dispersant (1
)
Potassi um Tripolyphosphate (KTPP)
Ethylene Glycol
Wetting Agent (2)
Antifoam (3)
Titanium Dioxide (4)
Calci um Carbonate
(5)
Zinc Oxide
(6)
Mildewcide
(7)
Pounds
143.3
4.0
8.0
2.0
20.0
1.2
1.5
103.0
385.0
40.6
5.0
Letdown
:
Ucar Latex 123 496.6
Ucar Fi lmer IBT 6.0
Antifoam (3) 2.0
Ammonium Hydroxide, 28% Aqueous Solution 2.5
Gal lons
17.3
0.3
0.8
2.2
0.2
0.2
3.2
17.1
0.9
0.5
---
55.9
0.8
0.3
0.3
S
,uppl
i
(1)
ers:
Dispersant
-
Colloid 226/35 (Rhone-Poulenc) or equivalent.
Wetting Agent
-
Surfynol 104 (Air Products) or equivalent.
Antifoam
-
Colloid 643 (Rhone-Poulenc) or equivalent.
Titanium Dioxide
-
Ti-Pure R-960 (DuPont)
or
equivalent.
Calcium Carbonate
-
Atomite
(ECC)
or equivalent.
(6)
Zinc Oxide
-
Kadox 915 (Cookson) or equivalent.
(7)
Mildewcide
-
Nopcocide N-96 (Henkel) or equivalent.
Paint Properties:
Pigment Volume Concentration (PVC),
%:
40
Total Solids,
%:
by Volume: 53.8
by Weight:
68.5
Stormer Viscosity,
KU:
110
Fi 1
m
Properti es*
:
Tensile:
Strain Rate, in/min: 2.0
Stress, psi: 108
Elongation,
%:
1070
Strain Rate, in/min: 2.0
Stress, psi: 52
Elongation,
%:
1650
Water Transmission at 24 Hours, mg:
90
180 Bend at -2OC:
No
Cracking
Tensile after 24-hour Water immersion:
Water Pondi ng:
Low Temperature Flexibility:
*Dried and Conditioned
7
Days at 72F (22C) and
50%
RH
SOURCE: Ucar Emulsion Systems: Ucar Latex
123:
Formulation
WB-120
Exterior Paints and Related Products
97
White Exterior
Flat
House Paint
with
Zinc
Oxide
Pounds Gallons
Inqredi ents:
___~
Pigment Grind:
Water 249.1 29.90
Cellosize Hydroxyethyl Cellulose ER-30,000 4.0
0.40
Nuosept 95 2.3 0.25
Propylene G1 ycol 25.9 2.98
Tamol 850 4.0 0.40
Triton Nonionic Surfactant N-101 2.1 0.24
Colloid 640 1.9 0.25
Ti -Pure R-706 200.0 5.90
Minspar 4 100.0 4.63
Nytal 300 75.0 3.16
Letdown
:
Water 75.0 9.00
Ucar Latex 353 251
.O
27.50
Ucar Latex 6390 88.7 10.08
Ucar Filmer IBT 23.8 3.01
Col loi d 640 3.8 0.51
Ammonium Hydroxide, 28% Aqueous Solution 3.0
0.40
Potassium Tripolyphosphate (KTPP) 2.0 0.20
Eagle 417W
50.0
1.11
Paint Properties:
PVC,
%:
41
.1
Volume Solids,
%:
36.0
Weight Solids,
%:
59.6
Weight per Gallon, lb: 11.61
Stormer,
KU:
93
ICI,
poise: 0.9
pH, initial: 9.4
Freeze-thaw Stability,
5
cycles: Pass
Heat-Aged Stability:
1 week at 140F: Pass
2 weeks at 120F: Pass
Roller Stability, 1 week*: Pass
Fi 1
m
Properti es
:
Reflectance,
%:
88.2
Contrast Ratio, 3-mil
film:
0.951
Wet Adhesion, 24-hr., cycles: >2000
Chalk Adhesion:
Dry: Exc
Wet: Exc
Acceptance: Exc
Development
:
Exc
Float: Exc
Color*:
*Tinted with 2% by weight phthalo blue (Huls 888-7124)
SOURCE:
Ucar Emulsion Systems: Ucar Latex 353: Formulation
Suggestion
E-1519
98
Water-Bared Paint Formulations
White Exterior Flat House Paint with
Zinc
Oxide
Ingredients:
Pi
grnent
Or
i
nd
:
Cel losi ze Hydroxyethyl Cellulose QP-4400
Water
Propylene Glycol
Tamol 960
Potassi urn Tripolyphosphate (KTPP)
Triton Nonionic Surfactant CF-10
Col loi d 643
Ti
-Pure R-902
Eagle 417W
Minex 4
Optiwhi te
Attagel
50
AMP-95
Pounds
123.1
98.1
59.0
7.1
1.5
2.5
1
.o
1
.o
225.0
25.0
145.0
50.0
5.0
Letdown
:
NeoCar Latex 6035 378.0
Ucar Filmer IBT 20.0
Skane M-8 1
.o
Colloid 643 1.5
Ammonium Hydroxide, 28% Aqueous Solution 2.0
Cel losize Hydroxyethyl Cellulose QP-4400 43.0
Pai nt Propert
i
es
:
PVC,
%:
45.0
Volume Solids,
%:
37.0
Weight Solids,
%:
54.7
Weight per Gallon, lb: 11.7
Stormer,
KU:
97
ICI,
poise: 0.8-1.0
pH Value: 8.5-9.0
Heat-Aged Stability,
4
weeks at
140F:
Pass
Film Properties:
Reflectance,
%:
89.7
Gloss, 60: 3
Sheen, 85: 4
Contrast Ratio, 3-mil
film:
0.969
ASTM Scrub Cycles, with shim Failure: >lo00
Chalk Adhesion: Exc
Gal 1 ons
14.78
11.78
6.86
0.72
0.15
0.28
0.14
0.13
6.76
0.54
6.68
2.73
0.25
41.77
2.53
0.12
0.21
0.24
5.16
SOURCE:
Ucar Emulsion Systems: NeoCar Polymers: Formulation
Suggestion E-2272
Exterior Paints and Related Products
99
White
Roof
Coating
Materi a1
:
Water
Ammonia (28%)
Potassium Tripolyphosphate
AZO-33 Zinc Oxide
Durami te
Titanox 2160
Bubble Breaker 3295
Bubble Breaker 776-P
Methocel 31 2MS
Texanol
Disperse under high shear for 10-15 minutes.
Add letdown:
Arolon 820-W-49
Analysis:
PMA-100
Pigment Volume Concentration, Percent: 47.5
Pigment/Binder Ratio: 2.26/1
Percent Solids, Weight: 63.18
Percent Solids, Volume: 47.33
Viscosity
@
25C,
KU:
80-90
Gloss:
Flat
Pounds/Gallon: 11.91
VOC
(excluding water):
Grams/Liter: 64.0
Pounds/Gallon: 0.53
pH: 8.8-9.2
Lbs.
Gals.
172.60 20.72
1 .80 0.09
0.90 0.12
1.92 0.09
22.83 0.49
466.65 20.74
24.31 0.73
3.30 0.44
3.30 0.44
4.14 0.36
17.93 2.27
470.89 53.51
SOURCE:
Reichhold Chemicals, Inc.: Arolon 820: Formula 2185-40A
Interior Paints and Related Products
101
Clear High
Gloss
Varnish
Material:
Spensol L51
Ammonium Hydroxide
Surfynol
104H
Byk 321
Colloid 679
Arolon 840-W-39
Mi
cheml ube 02925
Lodyne S107B
Lbs.
Gals.
651.9 74.50
1.9 0.25
4.0
0.50
1.9 0.25
I
.9 0.25
167.5 19.25
31
.1
3.75
1
.o
0.10
Add the above materials in order under good agitation, then add
the following curing agent just prior to use and
mix
well
for
at least 10 minutes.
XAMA-
7 11.4 1.15
Analysis:
Percent Sol ids, Weight
:
30.9
Percent Solids, Volume: 28.0
Viscosity
@
25C #2 Zahn, Secs.: 20
Gloss (60): 100+
Pounds/Gallon: 8.7
VOC
(excluding water): Grams/Liter: 290
pH:
8.5+-0.3
Pounds/Gallon: 2.4
Formulation 2307-22A
Fast-Dry Sealer
Materi a1
:
Spensol L51
Premix and add:
Water
Ammoni um Hydroxi de
Add in following order with agitation:
Arolon 840-W-39
Surfynol 104H
Lodyne SI07
Analysis:
Ratio of Spensol L51 to Arolon 840: 75:25
Percent Solids, Weight: 32.1
Percent Solids, Volume: 29.5
Viscosity
@
25C,
#2 Zahn, Secs.: 23t-4
Pounds/Gallon: 8.73
VOC
(excluding water): Grams/Liter: 286
pH: Bt-0.5
Pounds/Gallon: 2.4
Forrnul at ion 2061
-91A
Lbs.
Gal
s.
687.2 78.63
1.4 0.17
0.4 0.06
176.2 20.25
5.2 0.66
2.2
0.23
S0URCE:Reichhold Chemicals, Inc.: Spensol L51: Formulations
102
Water-Based
Paint
Formulations
Economv Flat Wall Paint
Inqredi ents:
Pi gment
Gri
nd
:
Water
Cellosize Hydroxyethyl Cellulose ER-30,000
Nuosept 95
Tamol 731
Triton Nonionic Surfactant N-101
Tergitol Nonionic Surfactant NP-40
Propylene G1 ycol
Drewplus L-475
Tronox CR-813
ASP NC2
No.
1
White
Celite 281
Letdown
:
Water
Ucar Latex 353
Ucar Filmer IBT
Drewpl us L-475
Paint Properties:
PVC,
%:
70.0
Volume Solids,
%:
29.8
Weight Solids,
%:
50.2
Weight per Gallon, lb: 11.32
Stormer,
KU:
94
ICI,
poise: 0.9
pH, initial: 8.3
Freeze-thaw Stability, 5 cycles: Pass
Heat-Aged Stability, 2 weeks at 120F: Pass
AMP-95
Pounds
484.5
6.0
2.3
4.6
2.2
2.2
1
.o
13.0
1
.o
75.0
200.0
150.0
25.0
Gal lons
58.16
0.55
0.25
0.50
0.25
0.25
0.13
I
.50
0.13
2.34
9.30
6.65
1.30
30.2 3.63
125.4 13.78
8.1
1.03
1.9 0.25
Film Properties:
Reflectance,
%:
91.2
Sheen, 85: 1.1
Contrast Ratio, 3-mil
film:
0.959
ASTM Scrub Cycles, with shim failure, 10%: 102
Color*:
Acceptance: Exc
Development: Exc
*Tinted
with
2% by weight phthalo blue (Huls 888-7214)
or
red iron oxide (Huls 888-1045).
SOURCE:
Ucar Emulsion Systems: Ucar Latex
353:
Formulation
Suggestion
1-2469
Interior Paints and Related
Products
103
Economy Flat Wall Paint
Ingredients:
Pigment Grind:
Water
Cel losize Hydroxyethyl Cellulose ER-30,000
Nuosept 95
Tamol 731
Triton Nonionic Surfactant N-101
Tergitol Nonionic Surfactant NP-40
AMP-95
Propylene Glycol
Drewplus L-475
Tronox CR-813
ASP NC2
No.
1 White
Celite 281
Letdown
:
Water
Ucar Latex 353
Ucar Filmer IBT
Orewplus L-475
Paint Properties:
PVC,
%:
70.0
Volume Solids,
%:
29.8
Weight Solids,
%:
50.2
Weight per Gallon, lb: 11.32
Stormer,
KU:
94
ICI.
ooise: 0.9
Pounds
484.5
6.0
2.3
4.6
2.2
2.2
1
.o
13.0
1
.o
75.0
200.0
150.0
25.0
30.2
125.4
8.1
1.9
Gal lons
58.16
0.55
0.25
0.50
0.25
0.25
0.13
1.50
0.13
2.34
9.30
6.65
1.30
3.63
13.78
1.03
0.25
..
pH, initial: 8.3
Freeze-thaw Stability, 5 cycles: Pass
Heat-Aged Stability, 2 weeks at 120F: Pass
Fi 1
m
Propert
i
es
:
Reflectance,
%:
91.2
Sheen,
85:
1.1
Contrast Ratio, 3-mil
film:
0.959
ASTM Scrub Cycles, with shim failure, 10%: 102
Color*:
Acceptance: Exc
Development
:
Exc
*Tinted
with
2% by weight phthalo blue (Huls 888-7214) or
red iron oxide (Huls 888-1045).
SOURCE: Ucar Emulsion Systems: Ucar Latex
353:
Formulation
Suggestion
1-2460
104
Water-Based Paint Formulations
Good
Quality Interior Flat
with
<50g/L
VOC
Inqredi ents
:
Pi
gment
Gri
nd
:
Water
Propylene Glycol
Proxel GXL
Col loi d 226/35
Triton Nonionic Surfactant N-101
Drewplus L-475
Ucar Polyphobe 102 Rheology Modifier
Sodium Hydroxide
(50%
Solution)
Ti
-Pure R-902
Snowf
1
ake
Minex 4
Letdown
:
Ucar Latex 3796
Ucar Filmer IBT
Drewplus L-475
Ucar Polyphobe 102 Rheology Modifier
Water
Pounds
358.0
10.0
0.5
6.0
2.2
4.0
15.0
2.5
200.0
175.0
175.0
200.0
3.0
4.0
17.3
50.0
Gal 1 ons
43.00
1.16
0.05
0.59
0.25
0.52
1.72
0.19
6.00
7.75
8.05
22.10
0.38
0.52
1.98
6.01
Paint Properties
:
PVC,
%:
63.1
Volume Solids,
%:
34.5
Weight Solids,
%:
55.1
Weight per Gallon,
lb:
12.18
Stormer,
KU:
87
ICI,
poise: 2.1
pH, initial: 9.2
Freeze-Thaw Stabi
1
i
ty, 1 cycle: Pass
Heat-Aged Stability, 4 weeks at
140F:
Pass
Volatile Organic Content,
g/L:
45.6
Fi
1
m
Propert
i
es
:
Ref
1
ectance,
%:
90.0
Sheen, 85: 2
Contrast Ratio, 3-mil
film:*
0.961
ASTM
Scrub Cycles, with shim Failure: 330
Color:*
Acceptance: Excel lent
Development: Excellent
Low Temperature Coalescence
IO-mil
drawdown at 40F: Pass
Mudcracki
ng,
30-mi
1
on
sheetrock: Pass
*Tinted with 2% by weight phthalo blue (Huls 888-7214)
or red iron oxide (Huls 888-1045).
SOURCE:
Ucar Emulsion Systems: Formulation Suggestion
I-2230A
Interior Paints and Related Products
105
Hiah-Quality
Super
Flat Interior Paint
Ingredients:
Pi
Qment Grind:
Water
Propylene G1 ycol
Proxel GXL
Col 1 oi d 226/35
Triton Nonionic Surfactant N-10
Colloid 640
Ucar Polyphobe 102 Rheology Mod
Ti
-Pure R-902
Snowf 1 ake 960
Minex 4
Letdown
:
Ucar Latex 3796
Ucar Filmer IBT
Colloid 640
AMP-95 fier
Ucar Pol yphobe 102 Rheology Modi
f
i
er
Water
Pounds
150.0
25.9
0.5
8.0
2.2
3.5
15.0
5.0
250.0
125.0
125.0
Gal lons
18.02
3.00
0.05
0.78
0.25
0.47
1.72
0.63
7.51
5.54
5.76
419.8 46.64
16.8 2.11
3.5 0.50
7.5 0.86
51.3 6.16
Pai nt Properti es
:
PVC,
%:
43.3
Volume Solids,
%:
43.4
Weight Solids,
%:
61.0
Weight per Gallon, lb: 12.09
Stormer.
KU:
90
ICI,
poise: 2.0
pH, initial: 9.2
Freeze-Thaw Stability, 3 cycles: Pass
Heat-Aged Stability, 4 weeks at 140F: Pass
Fi
1
m
Propert
i
es
:
Reflectance,
%:
92.5
Sheen, 85: 7
Contrast Ratio, 3-mil
film*:
0.962
ASTM
Scrub Cycles, with shim Failure: >2000
Color*:
Acceptance: Excel 1 ent
Development
:
Excel 1 ent
*Tinted with 2% by weight phthalo blue (Huls 888-7214)
or
red iron oxide (Huls 888-1045).
SOURCE:
Ucar
Emulsion
Systems:
Formulation Suggestion I-2227A
106
Water-Based
Paint
Formulations
Interior Clear
Wood
Finish
(RhoDlex CL-l04/Sancure
8151
B1
end
:
Rhopl ex CL-104 (38.5%)
Sancure 815 (35.0%)
Surfynol DF-62
Surfynol 104PG-50
Mix above for 10 minutes before adding the following:
Hexyl Carbi to1
Propylene Glycol
Acrysol RM-1020
Water
Michem 39235
Aqueous Ammonia
(
14%)
Formulation
B
(Rohm and Haas)
Interior Sandina Sealer
(RhoDlex CL-1051
El end
:
Rhopl ex CL-105 (37.0%)
Surfynol DF-62
Water
Aqueous Ammonia (14%)
Mix above for 10 minutes before adding the following:
Propasol
B
Hexyl Carbi to1
Acrysol RM-2020
Water
Aqueous Ammonia (7%)
Surfynol 104DPM
Formulation
C
(Rohm
&
Haas)
Pounds
540.0
148.5
1.4
3.0
20.8
30.0
18.0
66.0
22.3
2.5
Pounds
709.3
1.3
32.9
8.0
45.2
22.3
4.1
30.8
2.6
3.0
Surfynol additives have been shown to provide the following
benef
i
ts
:
*Color uniformity of stains
*Early stain 1 appi ng resistance
*Consistent wetting, flow and leveling on various woods
*Foam control
*Topcoat recoatability and intercoat adhesion
*Gloss retention upon aging
*Tannin bleed resi stance
*Water sensitivity
*Chemical resistance
Formulas
With no detrimental effect upon:
SOURCE:
Air
Products
8,
Chemicals, Inc.: Surfynol Surfactants:
Interior Paints and Related
Products
107
Interior Contractor Flat
Ingredients:
Pigment Grind
Water
Propylene G1 ycol
Tamol 1124
Triton Nonionic Surfactant X-405
Colloid 643
AMP-95
Ti
-Pure R-901
Optiwhite
Durami
te
Celite 281
Letdown
:
Ucar Latex 379G
Ucar Filmer
IBT
Colloid 643
Water
Ucar Polyphobe 10
Water
Paint Properties:
PVC,
%:
71.4
Volume Sol ids,
Wei ght Sol
ids,
Weight per Gal
pti, initial:
8
Pounds
184.0
26.0
10.0
2.0
1.5
2.0
100.0
150.0
190.0
20.0
148.0
8.0
2.5
50.0
Rheology Modi
f
i
er
21
.o
-.
217.5
%:
40.3
%:
29.4
on, lb: 11.3
5-9.0
Gal 1 ons
22.09
3.02
1.01
0.23
0.21
0.25
3.33
8.20
8.41
1.04
16.35
1.01
0.34
6.00
2.41
26.11
Ucar Polyphobe 107:
NVM
lb/100 gal: 5.3
Stormer,
KU:
90/98
ICI,
poise: 0.7
Scrub Cycles: 140
SOURCE:
Ucar Emulsion Systems: Formulation Suggestion
I-2231A
108
Water-Based Paint Formulations
Interior Good
Quality
Flat
for Roller and Brush Application
InQredi ents:
Pigment Grind:
Water
Propylene G1 ycol
Tamol 1124
Triton Nonionic Surfactant X-405
Col loi d 643
AMP-95
Ti
-Pure R-901
Opt
i
whi te
Durami te
Letdown
:
Ucar Latex 379
Ucar Filmer IBT
Colloid 643
Water
Ucar Polyphobe 103 Rheology Modifier
Water
Paint Properties:
Pigment Volume Concentration,
%:
58.0
Volume Solids,
%:
34.4
Weight Solids,
%:
51.9
Weight per Gallon, lb: 11.3
pH, initial: 8.5-9.0
Thickener Comparison:
Ucar Polyphobe 103:
NVM
lb/100 gal:
5.7
Stormer,
KU:
91/98
ICI,
P: 1.5
Scrub Cycles: 1102
Flow/Leveling: Excellent
50-mi 1 Mudcrack: Pass
Roll er/Spatter
:
Mi
ni mal
NVM
lb/110 gal:
7.0
Stormer,
KU:
86/96
ICI,
P:
1.8
Scrub Cycles: 1200
Flow/Leveling: Excel lent
50-mi 1 Mudcrack: Pass
Roll er/Spatter
:
Mi
ni mal
Ucar Polyphobe 102/104 blend:
NVM
lb/100 gal: 3.7/2.3
Stormer.
KU:
95/101
Ucar Polyphobe 102:
~I
~
~I
~
ICI,
P:
1.4
Scrub Cycles: 1200
Pounds
184.0
26.0
9.0
2.0
1.5
2.0
100.0
150.0
190.0
254.0
16.0
2.5
50.0
22.8
119.2
Flow/Leveling: Good
50-mi 1 Mudcrack: Pass
Roll er/Spatter
:
Mi
ni mal
SOURCE:
Ucar Emulsion Systems: Formulation Suggestion
Gal 1 ons
22.09
3.02
0.91
0.23
0.21
0.25
3.33
8.20
8.41
28.07
2.03
0.34
6.00
2.62
14.31
1-2232
Interior Paints and Related Products
109
Interior
Good
Quality Flat
for Roller and Brush Application
Ingredients:
Pigment Grind:
Water
Propylene Glycol
Tamol 1124
Triton Nonionic Surfactant X-405
Colloid 643
Ti-Pure R-901
Opt
i
whi te
Durami te
Letdown
:
Ucar Latex 379
Ucar Filmer
IBT
Colloid 643
Water
Ucar Polyphobe 9831 Rheology Modifier
Water
AMP-95
Pounds
184.0
26.0
9.0
2.0
1.5
2.0
100.0
150.0
190.0
254.0
16.0
2.5
60.3
12.5
119.2
Gal 1 ons
22.09
3.02
0.91
0.23
0.21
0.25
3.33
8.20
8.41
20.07
2.03
0.34
7.20
1.40
14.31
Paint Properties:
Pigment Volume Concentration,
%:
58.0
Volume Solids,
%:
34.4
Weight Solids,
%:
51.9
Weight per Gallon,
lb:
11.3
Stormer,
KU:
95
ICI,
Poise: 1.6
pH Value: 8.5-9.0
Volatile Organic Content, g/L: 139
Sheen, 85: 1.8
Flow and Leveling: Good
Sag Resistance, mils: 7
Film Properties:
SOURCE:
Ucar
Emulsion Systems: Ucar Polyphobe
9831
Rheology
Modifier: Formulation Suggestion
1-2240
110
Water-Based Faint Formulations
Interior
Good
Quality Flat
Ingredients:
Pi gment
Gri
nd
:
Water
Propylene G1 ycol
Proxel GXL
Tamol 1124
Triton Nonionic Surfactant X-405
Colloid 643
Ti
-Pure R-901
Opti
whi te
Ourami te
Letdown
:
Ucar Latex 3796
Ucar Filmer IBT
Col loid 643
Water
Ucar Pol yphobe 103 Rheology Modi
f
i
er
Water
Paint Properties:
PVC,
%:
58.0
Volume Solids,
%:
34.4
Weight Solids,
%:
51.9
Weight per Gallon, lb: 11.3
pH,
initial: 8.5-9.0
AMP-95
Thickener Comparison: Ucar
NVM,
lb/100 gal
Stormer,
KU
ICI,
poise
Scrub Cycles
Flow/Level
i
ng
50-mi 1 Mudcracki ng
Pounds
184.0
26.0
0.5
9.0
2.0
1.5
2.0
100.0
150.0
190.0
254.0
16.0
2.5
50.0
22.8
119.2
Polyphobe Ucar
02
7.0
Gal 1 ons
22.09
3.02
0.05
0.91
0.23
0.21
0.25
3.33
8.20
8.41
28.07
2.03
0.34
6.00
2.62
14.31
Pol yphobe
03
5.7
86/96
1.8
1200
Exc
Pass
91 /98
1.5
1102
Exc
Pass
SOURCE: Ucar Emulsion Systems: Formulation Suggestion
I-2232A
Interior Paints and Related
Products
111
Interior Semi gloss Formulation
Ingredients:
Pigment
Gri
nd:
Water
Ucar Polyphobe 102 Rheology Modifier
Ammoni um Hydroxi de, 28% Aqueous Sol uti on
Propylene G1 ycol
Proxel GXL
Tamol 1124
Col loi d 643
Triton Nonionic Surfactant N-57
Tronox CR-828
Burgess No. 98
Letdown
:
Water
Ucar Polyphobe 102 Rheology Modifier
Butyl Carbitol Solvent
Ucar Filmer IBT
Ucar Latex 379G
Ucar Latex 6030
Colloid 643
Byk 346
Ammoni um Hydroxi de, 28% Aqueous Sol uti on
Pounds
125.0
19.6
1.8
43.2
2.3
7.3
1.9
2.1
250.0
19.7
24.8
2.2
23.8
11.9
346.8
184.0
2.8
1.1
1.8
Gal 1 ons
15.0
2.3
0.3
5.0
0.2
0.7
0.3
0.2
7.3
0.9
3.0
0.3
3.0
1.5
38.3
20.9
0.4
0.1
0.3
Paint Properties:
Pigment Volume Concentration,
%:
22.5
Volume Solids,
96:
36.4
Weight per Gallon, lb: 10.7
Stormer,
KU:
83
ICI,
Poise: 1.9
pH Value: 8.7
Freeze-Thaw Stability, cycles passed: 3
Heat-Age Stability, 120F. weeks passed: 2
Ratio of Ucar Latexes 379:6030: 70:30
Film Properties:
Gloss, 60: 64
Gloss, 20: 18
Contrast Ratio, 6-mil wet drawdown: 0.972
Reflectance,
%:
91.9
Block Resistance: 9
Flow and Leveling: Good
Low Temperature Coalescence: 10
Washability, stain removal*: 10
(crayon, felt pen, lipstick, pencil)
%
gloss retained: 92
*Washed with Fantastik; lO=complete stain removal
Wet Adhesion, gloss alkyd: Exc
SOURCE
:
Ucar Emulsion Systems:
1-2473
Ucar
Latex
0030:
Formulation
112
Water-Based
Pain?
Formidations
___~
Interior
Vinyl
Acrylic
Eggshell
for Roller
and
Brush Application
Inqredi ents:
Pigment Grind:
Water
Propylene
G1
ycol
Tamol 1124
Triton Nonionic Surfactant X-100
Colloid 643
Proxel GXL
Ti
-Pure R-900
Omyacarb
UF
AMP-95
ASP-1 70
Letdown
:
Ucar Latex 379
Ucar Filmer IBT
Col loid 643
Ucar Polyphobe 9831 Rheology Modifier
Water
Paint Properties:
AMP-95
Pigment Volume Concentration,
%:
36.4
Volume Solids,
%:
37.4
Weight Solids,
%:
54.4
Weight per Gallon, lb: 11.3
Stormer,
KU:
95
ICI,
Poise:
1.2
pH
Value: 8.5-9.0
Volatile Organic Content, g/L: 121
Film Properties:
Gloss, 60: 35
Flow and Leveling: Good
Sag Resistance, mils: 12
Pounds
100.0
26.0
8.0
2.0
1.5
1.5
2.0
230.0
100.0
50.0
420.0
12.0
2.5
2.0
11
.o
168.0
Gallons
12.00
3.02
0.81
0.23
0.21
0.15
0.25
6.91
4.42
2.33
46.41
1.52
0.34
0.25
1.27
20.07
SOURCE:
Ucar Emulsion Systems: Ucar Polyphobe
9831
Rheology
Modi
f
i
er: Formulation Suggestion
1-2241
Interior
Vinyl
Acryl
i
c Eqashel
1
for Roller and Brush Application
Ingredients:
Pigment
Gri
nd
:
Water
Propyl ene G1 ycol
Tamol 1124
Triton Nonionic Surfactant
Colloid 643
Proxel GXL
Ti
-Pure R-900
Omyacarb UF
AMP-95
ASP-
1
70
x-1
00
Pounds
100.0
26.0
8.0
2.0
1.5
1.5
2.0
230.0
100.0
50.0
Letdown
:
Ucar Latex 379 420.0
Ucar Filmer IBT 12.0
Colloid 643 2.5
AMP-95 2.0
Ucar Pol yphobe 102 Rheology Modi
f
i
er 30.0
Water 149.0
Paint Properties:
Pigment Volume Concentration,
%:
36.4
Volume Solids,
%:
37.4
Weight Solids,
%:
54.4
Weight per Gallon, lb: 11.3
pH, initial: 8.5-9.0
Thickener Comparison:
Ucar Polyphobe 114:
NVM lb/100 gal: 5.0
Stormer,
KU:
93
ICI,
P:
0.5
Flow/Leveling: Poor
Sag Resistance: 24+
Ucar Polyphobe 102:
NVM
lb/l00 gal:
7.5
Stormer,
KU:
92
ICI,
P: 1.8
Flow/Level ing: Excellent
Sag Resistance: 12
Ucar Polyphobe 102/114 blend (4:l):
NVM
lb/100 aal
:
4.0 lb
of
Ucar Poly. 102
Storme;,
KUT
97
ICI,
P:
1.6
F1 ow/Level
i
ng
:
Very Good
Sag Resistance: 14
Gallons
12.00
3.02
0.81
0.23
0.21
0.15
0.25
6.91
4.42
2.33
46.41
1.52
0.34
0.25
3.45
17.89
Interior Paints and Related Products
113
SOURCE:
Ucar Emulsion Systems: Formulation Suggestion 1-2237
114
Water-Based Paint Formulations
Interior
Vinyl
Acrylic Semigloss
I
nared
i
en
t
s
:
Pigment Grind:
Water
Polywet ND-35
Ti
-Pure R-902
Drewpl us L-475
Letdown
:
Ucar Latex 367
Water
Ucar Filmer
IBT
Nuosept 95
Triton Nonionic Surfactant GR-5M
Drewpl us L-475
Water (adjust according to Polyphobe
Ucar Polyphobe 114 Rheology Modifier
AMP-95
Pounds
104.9
4.0
205.0
2.0
423.0
33.3
23.8
2.0
1
.o
5.0
4.0
level) 214.5
26.5
Gal lons
12.59
0.39
6.16
0.28
47.00
4.00
3.01
0.21
0.12
0.64
0.56
25.75
3.05
Paint Properties:
Pigment Volume Concentration,
%:
20.4
Volume Solids,
96:
40.3
Weight Solids,
%:
54.2
Weight per Gallon, lb: 10.5
Thickener Compari son
:
Ucar Polyphobe 114:
NVM
lb/100 gal: 6.6
Brookfield, 0.3,
P:
680
ICI,
P:
0.5
60 Gloss: 79
Ucar Polyphobe 102:
NVM
lb/100 gal: 10.7
Brookfield,-0.3,
P:
186
ICI,
P: 2.2
60 Gloss: 74
Ucar Polyphobe 103:
NVM
lb/100 gal
:
8.2
Brookfield, 0.3,
P:
336
ICI,
P:
1.5
60 Gloss: 69
Ucar Polyphobe 107;
NVM
lb/100 gal: 5.1
Brookfield, 0.3,
P:
226
ICI,
P:
0.7
60 Gloss: 67
NVM
lb/100 gal: 5.6
Brookfield, 0.3,
P:
2,086
ICI,
P:
0.7
60
Gloss:
70
Ucar Polyphobe
106HE:
SOURCE:
Ucar Emulsion Systems: Formulation Suggestion 1-2239
Interior Paints and Related Products
115
Intumescent Interior White
Fi
re-Retardant Paint
I
ngred
i
en
t
s
:
Pigment Grind:
Water
Potassium Tripolyphosphate (KTPP)
Surfactol 365
Ucar Latex 367
Colloid 677
Phos-Chek
PI30
Aero Melamine (powdered grade)
Di
pentaerythri to1 (powdered grade)
Nuosept 6351
Ti
-Pure R-900
Chlorez 700
Pounds
290.0
3.0
4.0
75.0
3.0
260.0
80.0
75.0
1
.o
60.0
40.0
Gal 1 ons
34.8
0.3
0.4
8.2
0.3
17.3
6.8
6.4
0.1
1
.8
2.9
Letdown
:
Cellosize Hydroxyethyl Cellulose
QP-15,OOOH
(1.5%
aqueous solution)
45.0
5.2
Ucar Latex 367 145.0
16.0
Colloid 677
1
.o
0.1
Procedure:
the order listed. Completely disperse each ingredient before
adding the next. When the pigment grind slurry is complete,
agitate for an additional five minutes; transfer to a pebble
mill
and grind to Hegman 3. Under agitation, prepare the final
letdown in the order listed. Under agitation, add the pigment
grind slowly to the letdown. Note: Protect thickener solutions
with preservative during processing and storage.
Paint Properties:
Under agitation, add all ingredients of the pigment grind in
Pigment Volume Concentration,
%:
74
Total Solids,
%
by weight: 60
Weight per Gallon, lb: 10.8
Stormer.
KU:
75-80
Contrast Ratio: 0.87
SOURCE: Ucar Emulsion Systems: Ucar Latex
367:
Formulation
Suggestion
1-1338
116
Water-Based
Paint
Formulations
Low
VOC
Interior Flat
_______
Pounds Gallons
Inqredi ents:
Pigment Grind:
Water
Kathon LX
Tamol 1124
Triton Nonionic Surfactant
N-101
Drewpl us L-475
Ucar Polyphobe 102 Rheology Modifier
Sodi um Hydroxide
Ti-Pure R-902
Durami te
Iceberg
Water
Letdown
:
Ucar Latex 379
Water
Drewpl us L-475
Ucar Filmer
IBT
Ucar Polyphobe 102 Rheology Modifier
Paint Properties:
Pigment Volume Concentration,
%:
64.9
Volume Solids,
%:
32.3
Weight Solids,
%:
53.1
Weight per Gallon, lb: 12.1
Stormer,
KU:
92
VOC,
grams per liter: 26.09
Film Properties:
Gloss, 60: 2
Sheen, 85: 3
Contrast Ratio, 6-mil wet drawdown: 0.977
Reflectance,
%:
91
.8
Scrub Resistance, cycles passed: 161
333.3 40.00
1.7
0.20
5.1
0.52
2.0 0.23
2.0 0.26
15.0
1.73
3.0
0.15
190.0 5.70
185.0 8.21
155.0 7.07
50.0 6.00
200.7 22.18
39.4 4.73
2.5 0.33
7.7 0.96
15.0
1.73
SOURCE:
Ucar Emulsion Systems: Formulation Suggestion
1-2238
Interior Paints
and
Related
Products
11
7
-
Solvent Free Interior Satin Paint
Material:
Grind:
Water
KTPP (100%)
Tamol 731 (Rohm and Haas)
Triton CF-10 (Rohm and Haas)
Kathon
LX
1.5%
(Rohm and Haas)
FCA (Foam Control Agent)
Ti-Pure R-900 (DuPont)
Nytal
300
(R.T.Vanderbilt)
Calci um Carbonate
Letdown
:
Rovace SF-091 (Rohm and Haas)
Rovaque OP-62
LO
(Rohm and Haas)
FCA (Foam Control Agent)
Acrysol RM-2020 (Rohm and Haas)
Acrysol TT-935 (Rohm and Haas)
Sodium Carbonate
Water
Properties:
Pigment Volume Content,
%:
37.0
%
Nonvolatile (by volume): 34.0
Stormer Viscosity,
K.U.:
95+-5
IC1
Viscosity. Poise: 1.1+-2
Gloss at 60,-%: 13.0
Recommended Product:
Agitan 315: Efficient. Fine
Alternative Products:
Agitan 260: Efficient, cost
Agitan 731: Efficient, zero
SOURCE: King Industries:
Formu
!&
260.0
1.5
7.0
2.5
1.7
1
.o
170.0
40.0
70.0
372.2
45.0
2.0
15.0
12.5
24.0
57.5
%wt
31.20
0.07
0.76
0.28
0.20
0.13
5.10
1.68
3.11
41.50
5.22
0.26
1.65
1.42
2.52
6.90
tuni ng
wi
11
provide cost benefits
.
effective.
voc
.
ation WR-39-3
118 Water-Based
Paint
Formulations
White Interior Eqsshell
Inqredients:
~~
Pounds Gal lons
Pigment Grind:
Water 226.7 27.21
Ucar Polyphobe 9831 Rheology Modifier 8.5 0.97
Nuosept 145 2.3 0.25
Tamol 731A
Triton Nonionic Surfactant N-57
AMP-95
Propylene Glycol
Col loid 640
Tronox CR-800
Opt
i
wh
i
te
Burgess No. 98
Letdown
:
AMP-95
Ucar Filmer
IBT
Water
Ucar Latex 353
Col loid 640
Paint Properties:
PVC,
%:
35.8
Volume Solids,
%:
38.2
Weight Solids,
%:
52.4
Weight per Gallon,
lb:
11.04
Stormer,
KU:
95
ICI,
poise: 1.4
pH, initial: 9.0
Freeze-thaw Stability,
5
cyc
Heat-Aged Stability, 2 weeks
F
lm
Properties:
Reflectance,
%:
91.4
Gloss, 60: 6.3
Sheen, 85: 22.6
Contrast Ratio, 3-mil
film:
.969
Color*:
Acceptance
:
Exc
Development: Exc
*Tinted with 2% by weight phthalo
iron oxide (Huls 888-1045).
11.5 1.25
2.3 0.25
2.0 0.26
51.8 6.00
1.9 0.25
225.0 6.54
100.0 5.46
25.0 1.15
2.0 0.27
22.5 2.85
78.7 9.45
341
.O
37.47
2.8 0.37
es: Pass
at 120F: Pass
SOURCE:
Ucar
Emulsion
Systems:
Formu
blue (Huls 888-7124)
or
red
ation Suggestion 1-1520
120
Water-Based
Paint
Formulations
Green Lacquer
Insredients:
Pi
ament
Gri
nd
:
Water
Ethylene Glycol
Dispersant
(
1
)
Tergitol Surfactant
NP-10
Antifoam (2)
Phthalo Green (3)
Medium Chrome Yellow
(4)
Let Down:
Ucar Vehicle 443
Butyl Carbitol Solvent
Tri
butoxyethyl Phosphate
Phthalo Green
(3)
Deionized Water
Pounds
45.00
0.65
6.26
0.62
1
.oo
50.00
33.04
Gal lons
5.40
0.07
0.68
0.07
0.13
4.95
0.67
666.11 75.19
13.26 1.67
13.26 1.58
51.50
5.10
26.55 3.19
Suppl
i
ers
:
(1)
Dispersant
-
Colloid 107 (Colloids) or equivalent.
(2)
Antifoam
-
Colloid 675 (Colloids) or equivalent.
(3)
Phthalo Green
-
Ti
nt-Ayd WD-2744
Di
spersi on (Daniel
(4)
Medium Chrome Yellow
-
X-3356
C.P.
Medium
Y
(Ciba-Geigy)
Products) or equivalent.
or equivalent
.
Lacquer Properti as
:
by Weight: 37
by Volume: 31
Pi gment/Bi nder Rat
i
o
:
0.25/ 1
Solids,
%:
pH: 8.5
Viscosity,
No.
4 Ford Cup, sec: 25
SOURCE:
Ucar Emulsion Systems: Ucar Vehicle 443: Formulation
Suggestion LP-3812
Lacquers
121
Foam Control
with
Agitan Additives
in
a
Hiah Gloss
DIY
Waterborne Lacquer
The choice of coalescing agents can significantly influence
the generation of foam in a waterborne formulation as well as
affect the performance of the foam control agent (FCA).
Component:
Rhoplex CL-104 (Rohm and Haas)
DC-14 (Dow Corning Additives)
FCA
(Foam Control Agent)
Michem 39235 (Michelman)
Adjust pH to 7-8
Aqueous Ammonia 28%
Propylene Glycol
Coalescent
Water
Adjust to viscosity
Water
j&
%Wt
642.8 76.83
24.7 2.95
1.3 0.16
21
.e
2.61
3
24.7
37.6
29.2
51.5
0.36
2.95
4.49
3.49
6.16
Propert
i
es
:
%
Nonvolatile (by weight): 30.7
%
Nonvolatile (by volume): 29.1
Viscosity #2 Zahn, 25C (seconds): 20-26
Theoretical
VOC
(pounds/gallon): 2.07
Theoretical
VOC
(grams/l
i
ter)
:
249
This study has demonstrated that different coalescents can
pH, 25C: 7.5-8.0
significantly affect foam generation and hence the performance
of the foam control agent. However, Agitan 295 performed
equally well in both systems, regardless
of
the coalescing
agent used.
For optimum foam prevention and
film
properties, Agitan 305
is recommended with the Texanol, while Agitan 731 is recommended
for the DPnB.
SOURCE:
King Industries:
WR-32:
FCA's for Waterborne Wood
Formulations
122
Water-Based Paint Formulations
White Lacauer
Inaredients:
Pigment
Gri
nd
:
Ucar Vehicle 443
Di
spersant (1
)
Surfactant (2)
Tergitol Surfactant
NP-10
Antifoam (3)
Titanium Dioxide (4)
Pebble
Mill
overnight.
Let Down:
Ucar Vehicle 443
Antifoam
(3)
Proposol Solvent
B
Tri
butoxyethyl Phosphate
Mar-Resi stant Aid
(5)
Ammonium Benzoate, 10% Aqueous Solution
Dei oni zed Water
Pounds
149.9
5.9
2.1
2.1
0.9
187.4
421.3
0.9
40.9
20.4
0.9
10.0
150.8
Gal lons
17.2
0.7
0.3
0.2
0.1
5.5
48.2
0.1
5.6
2.4
0.1
1.1
18.1
Suppliers:
(1) Dispersant
-
Disperbyk (Byk-Mallinckrodt) or equivalent.
(2) Surfactant
-
Surfynol 104
(Air
Products) or equivalent.
(3) Antifoam
-
Hodag PX-218 (Hodag) or equivalent.
(4) Titanium Dioxide
-
Zopaque RCL-9
(SCM)
or equivalent.
(5)
Mar-Resistant Aid
-
Byk 301 (Byk-Malllinckrodt) or
equivalent.
Lacquer Properties:
Pigment/Binder Ratio: 0.8/1
Total Solids,
%:
42.4
pH:
8.6
Viscosity,
No.
4 Ford Cup, sec:
Initial: 20
After 10 days at 140F: 20
SOURCE: Ucar Emulsion Systems: Ucar Vehicle
443:
Formulation
Suggestion
LP-3846
Lacquers
123
White Lacquer
Inaredi ents:
Pi gment
Gri
nd
:
Ethylene Glycol
Dispersant (1
)
Tergitol Surfactant
NP-10
Antifoam (2)
Ammonium Hydroxide, 28% Aqueous
Deionized Water
Ti
tani um Dioxide (3)
Pounds
3.16
6.31
1.59
0.23
Solution 0.44
28.20
156.52
Gal 1 ons
0.34
0.70
0.18
0.03
0.05
3.39
4.59
Grind for 15 minutes at high speed in a high-shear mixer.
Let
Down:
Ucar Vehicle 443
Tri
butoxyethyl Phosphate
Filmer (4)
Butyl Carbitol Solvent
Ammonium Benzoate
Deionized Water
546.84 62.00
4.60
0.55
11.19 1.42
11.20 1.41
0.74 0.07
210.25 25.29
Suppl
i
ers:
(1)
Dispersant
-
Disperbyk (Byk-Mgllinckrodt) or equivalent
(2) Antifoam
-
Colloid 675 (Colloids) or equivalent.
(3) Titanium Dioxide
-
Titanox 2060
(NL
Industries) or
(4) Filmer
-
Texanol (Eastman)
or
equivalent.
equivalent.
Lacquer Properties:
Pigment/Binder Ratio: 0.67/1
Solids,
%:
by Weight: 38.5
by Volume: 28.1
pH: 8.5
Viscosity.
No.
4 Ford Cup, sec: 35
SOURCE:
Ucar Emulsion Systems: Ucar Vehicle 443: Formulation
Suggestion LP-3813
Primers
125
fi
Halox
BW-100
Grind:
Water
Propylene G1 ycol
Dowicil 75
Colloid 111
St rodex PK-95G
Surfynol 104E
Drewplus L-475
Texanol
Pol yphobe 102
Aqua Ammonia (28%)
Lbs./100 Gals. Gms/Liter
250.0 300.0
15.0 18.0
1
.o
1.2
5.0
6.0
3.5 4.2
4.0 4.8
2.0 2.4
10.0 12.0
16.0 19.2
4.0 4.8
Add the following at high speed and disperse to 4+ Hegman grind.
Ti
-Pure R-902
Halox BW-100
Beaverwhi te 325
Snowf 1 ake
Letdown
:
CL 27NA
Drewpl us L-475
175.0 210.0
100.0 120.0
50.0
60.0
185.0 222.0
340.0 408.0
2.0 2.4
Add grind portion under agitation and mix until uniform.
Premix the following 2 raw materials and add under good agitation
DO
NOT
AERATE!
Water
Pol yphobe 106E
Mix until uniform.
Formula Constants:
%
Pi
gment/Wt
.
:
42.91
%
Pi
gment/Vol
.
:
20.07
%
Solids/Wt.: 57.79
%
Solids/Vol.: 39.51
%
PVC:
50.79
VOC,
lbs./gal.: 1.01
VOC.
g/L: 120.97
25.0
30.0
2.0 2.4
Formula Properti 8s:
Density lbs./gal.: 11.90
Density g/L: 1,427.4
KU
Visc.
I3
R.T.:
85-90
pH
I3
R.T.:
8.5-9.0
SOURCE: Halox Pigments: SugQested Formulation DOW/BW-100
126
Water-Based Paint Formulations
Alkvd Modified Latex Primer
Ingredient:
Pigment Grind:
Water
Busperse 39/Dispersant
Bubreak 448/Defoamer
(Premix next 2 items)
Water
QP-15000 Cellosize/Hydroxyethyl
Igepal CTA 639/Surfactant
Aroplaz 1271/Long
Oi
1 A1 kyd
Butrol 23/Modified Barium Meta-
borate
Ti-Pure R-SOO/Titanium Dioxide-
Rutile
Mi
ca-325
Atomi te/Calci um Carbonate
Nytal 300/Talc-Magnesium Silicate
Let Down:
Rhoplex MV-23/Acrylic Emulsion
Texanol/Ester Alcohol
Ethylene Glycol
Water
Pai nt Propert
i
es
:
Total Vehicle 60.27
Pigment 39.73
Volatile 42.67
Organic Solvent 7.59
Non-Volati le 57.33
Non-Volati
1
e Vehicle 17.60
Density (lb/U.S.
gal):
11.99
Specific Gravity: 1.44
P.V.C.:
43.42%
P/B Ratio: 2.258
Spread
@
1 Mil: 624 F2
Coating
VOC:
220 G/L
Material VOC: 109 G/L
Cell ulose
-
Lb
100.10
8.01
3.00
25.02
1
.oo
6.01
42.04
100.10
200.19
25.02
75.07
75.07
483.46
5.00
30.03
20.02
w
83.10
16.90
61.07
10.58
38.93
22.02
Gal
12.02
0.74
0.44
3.00
0.09
0.68
5.01
3.25
6.01
1.06
3.32
3.17
54.94
0.63
3.23
2.40
Wt%
8.35
0.67
0.25
2.09
0.08
0.50
3.51
8.35
16.69
2.09
6.26
6.26
40.32
0.42
2.50
1.67
SOURCE:
Buckman Laboratories: Formulat
on
Sugges
ion:
KR-01
Primers
127
Ancamide
2353
Curina
Aaent Anti-Corrosive Primer
Preliminary Formulation
Part
A:
Liquid DGEBA Epoxy
MPA-1078
(Rheox)
Mix well, then add at high speed:
Ti
Pure
R-900
(
DuPont)
10
Wollastekup
AS
(Nyco)
Disperse to
5
Hegman and
125F.
Reduce speed and add:
!&J
233.7
4.0
25.0
370.0
Xylene (Ashland)
45.0
Part
B:
Ancamide
2353
(Air Products)
MPA-1078
(Rheox)
Beetle
216-8
(Cyanamid)
125.54
4.0
15.0
Mix well at high speed, then add:
Red Iron Oxide
5-3100
(Mineral Pigments)
60.0
Beaverwhite
325
(Cyprus)
96.7
Phospl us
5-0866
(Mi
neral Pigments)
141.4
Disperse to
5
Hegman and
125F.
Reduce speed and add:
Diacetone Alcohol (Union Carbide)
Super High F1 ash Naphtha (Ash1 and)
31.3
106.8
Gal
24.093
0.541
0.751
15.289
6.207
15.212
0.541
1.724
1.441
4.204
5.065
3.997
14.691
Propert
i
es
:
Volume Sol ids:
71.8%
VOC:
<2.1
lb/gal
PVC:
39.7%
Mixing Ratio:
1:l
by Volume
CPVC:
54.6%
Pot Life, hr:
3
PVC/CVPC
:
0.725
Dry to Touch, hr:
1
Weight/gallon. Part
A:
14.45
Dry Through, hr:
6
Weight/gallon, Part
B:
12.45
Weight/gal lon:
13.45
SOURCE:
Air
Products and Chemicals, Inc.: Ancamide
2353
Curing
Agent: Table
9
Formulation
I28
Water-Based Paint Formulations
Anquami ne
401
/Semi
-sol
id
Epox
Di
spersi
on
___
Lead and Chromate Free Red IronYOxide Primer
Part
A*
Dow XUS19000.01 Epoxy Resin
Benzyl Alcohol
Water
Part
B:
Anquamine 401 Curing Agent
Water
Glacial Acetic Acid (Air
Pr
Red
Iron
Oxide**
LVT
400
Talc (Barrett)
Wallastokup
IOES
(Nyco)
Zeospheres 400
(3M)
Halox SZP 391
Dowanol
PM
Solvent (Dow)
Dowanol PnP Solvent (Dow)
&
@&
223.79 23.11
11.17 1.28
213.66 25.60
(Air
Products) 111.95
80.05
oducts) 2.10
62.98
125.94
139.95
62.98
76.96
32.18
33.59
12.25
9.59
0.24
I
.57
5.29
5.78
3.43
3.07
4.23
4.55
*Alternately use Epi-Rez 3515-W-60 at same loading
**Alternatively use
Ti02
for off-white primer
Typical Properties:
Wt
Solids
(%):
65.96
Volume Solids
(%):
51.17
PVC
(%):
37.4
Resin Stoichiometry:
1
.6:1
VOC
(lb/gal): 1.21
VOC
(g/l): 145
Anticorrosive Primer Properties:
Pot Life, hr:
4
Mix Ratio:
1:l
Tack Free Time, hr:
1.0
Hard Dry Time, hr:
6
VOC,
lb/gal: 1.2
Volume Solids,
%:
51
PVC,
%:
37
Cross
Hatch Adhesion: 5
1/4" Mandrel Bend: Fai 1
Di
rect Impact Resi stance,
i
n-1
bs:
20
Di
rect Impact Resi stance,
i
n-1
bs:
(5
SOURCE:
Air
Products and Chemicals, Inc.: Anquamine
401
Curing
Agent: Formulation
3
Primers
129
Anquami ne
401
/Sol
id
Resi
n
Di
spersi on
Lead and Chromate Free Red Iron Oxide Primer
Part
A:
Epi-Rez 3520-WY-55 Epoxy Resin (Shell)
Benzyl Alcohol
Surfynol
DF-58
Defoamer (Air Products)
Water
Red Iron Oxide
Barium Sulfate
lOES
Wollastokup (Nyco)
Halox
SW-1116
Zeosphere 4007 (3M)
Water Ground Mica
!=&
342.6
8.9
4.0
61.6
73.0
72.8
109.4
100.0
73.0
10.3
High speed disperse to a texture
of
N.S.,
then add:
Epi -Rez 3520-WY-55 Epoxy Resi n (She1 1
)
129.3
Water 22.1
Part
8:
Anquamine 401 Curing Agent (Air Products) 60.7
Water 111.8
Typical Properties:
Wt
Solids
(%I:
63.1
Volume Solids
(%):
47.3
PVC
(%):
35.1
Resin Stoichiometry (on equivalents): 1.6:1
VOC
(lb/gal): 1.02
voc
(g/l): 122.5
Pot Life, hr: 4
Mix Ratio: 4:l
Tack Free Time, hr: 0.5
Hard Dry Time, hr: 6
VOC,
lb/gal:
1.0
Volume Solids,
%:
47
PVC,
%:
35
Cross Hatch Adhesion: 4
Pencil Hardness, overnight: HB
Pencil Hardness,
7
days:
H
1/4” Mandrel Bend: Fail
Direct Impact Resistance, in-lbs: 35
Reverse Impact Resistance, in-lbs:
t5
Anticorrosive Primer Properties:
SOURCE:
Air
Products and Chemicals, Inc.
:
Anquamine 401
Agent: Formulation
4
37.65
1.03
0.48
7.39
1.79
1.99
4.52
4.20
3.65
0.44
14.21
2.65
6.58
13.42
Curing
130
Water-Based Paint Formulations
Corrosion Inhibitive Primer
Material:
j&
Add to mixer with agitation:
Water 98.6
Bubreak 448--Defoamer 2.0
Busperse 39--Dispersant
5.0
Igepal CTA-639
2.0
Premix and add the following:
Natrosol 250HR 2.0
Water 6.0
Stir in the following pigments:
Atomi te
135.0
Ti -Pure R-900
100.0
Busan
11-M1
50.0
High speed disperse to minimum
5.0
NS
grind
Let down with the following materials:
Aquamac
700
570.0
Texanol 69.0
Butrol 35--Flash rust inhibitor 7.0
Parameters: Properties:
Weight Solids: 52.9% Viscosity:
80-85
KU
Volume Solids: 40.5% DH:
8.4-8.6
Gals
11.83
0.30
0.46
0.23
0.40
0.72
5.97
3.08
1.82
65.82
8.75
0.63
Pi gment Weight
:
27.4%
Gloss
(a
60:
18-22
PVC: 27.9%
P/B Ratio:
1.08
VOC Level: 174 g/L
Metal Wash Primer
With today‘s concern over coatings containing chromate pig-
ments, there is a need for a chromate-free metal wash primer.
Buckman Laboratories has developed a metal wash primer made
with Busan
1141,
which
is
a non-lead, non-chromate anticorrosive
pigment. This formula
is
based on the military specification
coating MIL-P-15328C entitled “Primer (Wash) Pretreatment Blue.”
This specification is the same
as
the
U.S.
Navy Formula
117-8
for metals. The Busan 11-M1 based primer has performed well in
tests
versus
the traditional zinc chromate primer. The formula
is as follows:
Resin Component
(80
gal lonsl
:
Lbs/100 Gals
Polyvinyl -Butyral Resin (Ucar XYHL)
56
Busan
ll-Ml
50
Ti-Pure
R-900,
Titanium Dioxide
50
Copper-Phthalocyanine Blue
17
Butyl Alcohol, Normal 125
Isopropyl Alcohol
341
Water
15
Acid Component
(20
aallons):
Phosphoric Acid,
85%
28
Water 25
Isopropyl Alcohol
99
Package separately: The mixed container must be used within
SOURCE: Buckman Laboratories: Suggested Formulations
8
hours after mixing.
Primers
131
Cost Effective
2K
Water-Base Epoxv Primer
Usina
Halox
SW-111
Component A: Lbs./100 Gals. Grams/Li ter
Add the following
in
order listed:
€pi-Rez 5522-WY-55 450.0 540.0
Di
acetone Alcohol 7.0 8.4
Water 100.0 120.0
Nopco NDW 2.0 2.4
Mix for 5 minutes and add the following while mixing at high
speed
:
R.I.O.
R-4098
Halox SW-111
Wol 1 astokup 1 OES
Sparmi te
100.0
50.0
150.0
100.0
120.0
60.0
180.0
120.0
High speed disperse
to
5+ Hegman grind. Then add the following
slowly while mixing. Do not aerate!
Epi rez 5522-WY-55
Water
Component
B:
Mix at low speed:
€pi -Cure 8290-Y-60
Nacorr 1754
30.0 36.0
25.0 30.0
Lbs. /lo0 Gals. Grams/L
i
t
er
60.0
72.0
3.0 3.6
Add
the following raw materials in order listed while mixing at
high speed:
Zeeospheres 400
325 Mesh
W.G.
Mica 100.0
10.0 120.0
12.0
High speed disperse to 4+ Hegman grind. Then add the following
slowly while mixing. Do not aerate!
Water
Mix ratio:* Component
A
-
Component
B
-
*TO obtain optimum resu
prior to application.
Formula Constants:
%
Pi gment/Wt.
:
41.65
%
Pigment/Vol.: 18.78
%
Solids/Wt.: 65.81
%
Sol ids/Vol
.
:
49.66
%
PVC: 37.81
P/B
Ratio: 1.72
VOC,
lbs./gal.: 1.25
voc,
g/L: 150.00
40.0
48.0
80% by volume.
20% by volume.
ts, allow 20-30 minutes induction
t
me
Formula Properties
:
Density lbs./gal.: 12.25
Density g/L: 1,470.0
Set-to-touch: 30 minutes
Dry Hard: Overnight
SOURCE: Halox Pigments: Suggested Formulation
I32
Water-Based Paint
Formulations
Di
ppi
na
Primer
Ingredients:
Pi
oment Grind:
Oeioni zed Water
Ammoni um Hydroxi de, 28% Aqueous Sol uti on
Dispersant (1
)
Tergitol Surfactant
NP-10
Antifoam (2)
Ti
tani um Dioxide (3)
Barytes (4)
Strontium Chromate
(5)
Let Down:
Ucar Vehicle 443
Antifoam
(2)
Butyl Cellosolve Solvent
Butyl Carbitol Solvent
Hexamethoxymethylmelami ne (6)
Ammonium Benzoate, 10% Aqueous Solution
Ammonium Hydroxide, 28% Aqueous Solution
Oeioni zed Water
Suppliers:
Pounds
41.6
0.2
1.6
3.2
0.7
50.0
53.1
57.7
500.0
0.8
51.5
20.6
54.7
8.5
6.5
127.1
Gal lons
5.00
0.02
0.22
0.36
0.09
1
.so
1.45
1.87
57.52
0.11
6.86
2.60
5.47
0.93
0.74
15.26
or equi valent
.
(Oavis/MPC) or equivalent.
Cyme1 303 (American Cyanamid)
(1)
Dispersant
-
Bykumen
WS
(Byk-Mallinckrodt) or equivalent.
(2)
Antifoam
-
Hodag PX-218 (Hodag) or equivalent.
(3) Titanium Dioxide
-
Ti-Pure R-960 (Du Pont) or equivalent.
(4) Barytes
-
Sparmite (Pfizer)
(5) Strontium Chromate
-
5-1365
(6)
Hexamethoxymethylmelamine
-
or equivalent.
Primer Properties:
Solids,
%
by
wt:
37.4
pH: 9.5
Viscosity, Brookfield, cP: 800
Add Water to 18 sec (#3 Zahn Cup) for dipping.
Primer Performance:*
Bake Cycle, min: Salt Spray:
Flash Time: 10 Hours Exposed: 565
Bake at 200F: 2.5 Rusting Rating:
9
Final Bake at 300F: 10 Blister Rating:
9M
Pencil Hardness:
2H
Creepage, in: 1/8
Gloss,
60:
30
Impact Resistance, in-lb:
Direct: 45
Reverse:
5
*Substrate
-
Bonderite 1000
SOURCE:
Ucar Emulsion Systems: Ucar Vehicle
443:
Formulation
Suggestion
C-2030
Primers
133
Experimental General Purpose Tannin-Stain Resistant
Water-Base Primer Usina Halox Xtain
A
Grind:
Water
Natrosol 250
MR
Aqua Ammonia (28%)
Ethylene G1 ycol
Tamol 681
Triton
CF-10
Foamaster VL
Halox Xtain
A
Snowf 1 ake
R-902
Lbs.
/lo0 Gals. Gms/Li ter
100.00 120.00
0.75 0.90
1
.oo
1.20
30.00
36.00
15.00 18.00
3.00 3.60
2.00 2.40
150.00 180.00
15.00 18.00
220.00 264.00
High speed disperse to 4+
NS
grind.
Water 25.00 30.00
Letdown
:
Mor-Lok 1035
Skane M-8
Aqua Ammonia (28%)
Texanol
Foamaster VL
467.00 560.40
2.00 2.40
1
.oo
1.20
5.00 6.00
1
.oo
1.20
Add grind portion under agitation and mix until uniform.
QR-708
Water
Add the following while mixing and mix until uniform
5.50
79.00
Properties:
lbs./gal.: 1
Formula Constants:
%
Pi
gment/Wt
.
:
34.36
%
Pigment/Vol
.
:
15.03
%
Solids/Wt.: 55.81
%
Solids/Vol.: 40.73
%
PVC:
36.89
VOC,
lbs./gal.: 1.10
VOC,
gms./l.: 132.04
Formula
Density
Density
PH
@
R.
KU
Visc
SOURCE:
Halox
Pigments: Suggested Formu
.23
gms./i.: 1,346.7
.:
9.0-9.5
@
R.T.:
95-100
ation
MOR-1035-A
6.60
94.80
134
Water-Based Paint Formulations
ExDerirenta1 Hi
ph
Performance Tanni n-Stai
n
Resistant
Water-Base Primer Usina Halox Xtain
A
Grind: Lbs./100 Gals. Gms/Liter
Water 125.00 150.00
Natrosol 250
MR
Aqua Ammonia (28%)
Ethyl ene G1 ycol
Tamol 681
Triton CF-10
Foamaster VL
Halox Xtain
A
Snowf
1
ake
High speed disperse to 4+
NS
grind
Water
Letdown
:
Mor-Lok 1043
Skane M-8
Aqua Ammonia (28%)
Texanol
Foamaster VL
R-902
0.75
1.00
30.00
18.00
3.00
2.00
150.00
5.00
277.00
25.00
434.00
2.00
1
.oo
4.75
1
.oo
0.90
1.20
36.00
21 -60
3.60
2.40
180.00
6.00
332.40
30.00
520.80
2.40
1.20
5.70
1.20
Add grind portion under agitation and mix until uniform.
Add the following while mixing and mix until uniform.
QR-708
Water
Formula Constants:
%
Pi
gment/Wt
.
:
37.60
%
Pi
gment/Vol
.
:
17.11
%
Solids/Wt.: 57.21
%
Solids/Vol.: 41.18
%
PVC:
41.55
VOC,
lbs./gal.: 1.13
VOC,
gms./l.: 134.92
5.50 6.60
66.00 79.20
Formula Properties:
Density
1
bs. /gal.
:
11.51
Density gms.
/l.
:
1,381.2
KU
Visc.
@
R.T.: 90-95
pH
@
R.T.:
9.0-9.5
SOURCE:
Halox Pigments: Suggested Formulation MOR-1043-A
Primers
135
Experimental Waterbase Acrylic Red Iron Oxide Primer
Grind:
Water
Methyl Carbi to1
Tamol 165
Triton CF-10
Drew L-493
Snowf
1
ake
AMP-95
R.I.O.
R0-4097
Lbs./100 Gals. Gms/Liter
63.0 75.6
52.0 62.4
10.0 12.0
3.0 3.6
3.0 3.6
1
.o
1.2
50.0 60.0
250.0 300.0
0
40.0
Halox SZP-391
33.
High speed disperse to 4+
NS
grind.
Water 25.
Letdown
:
Mai ncote HG-54
Texanol
Dibutyl Phthalate
Drew L-493
Aqua Ammonia (28%)
Raybo 60
510.
4.
12
3
1
5
Add grind portion under agitation and mix until un
Acrysol RM-1020
Water
Mix
until uniform.
Formula Constants:
%
Pigment/Wt.: 31.58
%
Pigment/Vol.: 13.81
%
Solids/Wt.: 52.35
%
Solids/Vol.: 38.97
?6
PVC: 35.41
VOC,
lbs./gal.: 1.72
VOC.
g/L: 206.40
0
30.0
0
612.0
0
9
5
5
0
form.
10.0
26.0
Formula Properties:
Density lbs./gal.: 10.63
Density g/L: 1,275.9
KU
Visc.
B
R.T.:
90-95
pH
@
R.T.: 8.0-9.0
4.8
15.5
4.2
1.8
6.0
12.0
31.2
SOURCE: Halox Pigments: Suggested Formulation HG54-391
136
Water-Based
Paint
Formulations
Experimental Waterbase Acrylic
Grind:
Water
Methyl Carbi to1
Tamol 165
Triton
CF-10
Drew L-493
Red Iron Oxide
Snowf
1 ake
Halox BW-191
Let
Down:
Mai ncote
HG54
Texanol
Oi
butyl Phthalate
Drew L-493
Ammoni um Hydroxi de
Sodium Nitrite
Water
Ucar Thickener SCT
2
8%
200
Red
Iron
Oxide Primer
~__
Pounds
_____
Gallons
63.00
7.56
52.00 6.11
12.30 1 .26
3.00 0.34
1
.oo
0.14
57.40 1.34
192.60 8.56
100.00 4.21
510.00
60.00
4.00
0.50
12.90 1.48
3.60
0.50
1.70 0.24
8.40
1.01
49.00
5.90
7.50
0.85
Density lbs/gal: 10.78
%
Wt.
Solids: 53.5
%
Vol. Solids: 40.0
%
PVC:
35.0
Viscosity: 90-95
KU
@
77F
SOURCE:
Halox Pigments: Suggested Formulation
Primers
137
ExDerimental Waterbase Acrylic Red
Iron
Oxide Primer
Grind:
Water
Methyl Carbitol
Tamol 165
Triton CF-10
Drew L-493
Snowflake
AMP-95
R.
I.
0.
R0-4097
Halox CW-491
L
b.s Jl_O
0.
G31-s
..
Gm
s
/
L
1
t_er
63.0 75.6
52.0 62.4
10.0 12.0
3.0 3.6
3.0 3.6
1
.o
1.2
50.0
60.0
225.0 270.0
66.0
79.2
High speed disperse to 4+
NS
grind
Water 25.0
30
t
0
Letdown
:
Mai ncote HG-54
Texanol
Dibutyl Phthalate
Drew L-493
Aqua
Ammonia
(28%)
Raybo
60
.310.0 612.0
4.0
4.0
12
9
15.5
3.5
4.2
1.5
1.8
5.0
6.0
Add grind portion under agitation and mix until un7form.
Acrysol
RM-1020
Water
Mix anti
i
uniform
Formula Constants:
%
Pigment/Wt.: 31 .99
%
Pigment/Vol
.
:
13.93
%
Solids/Wt.: 52.62
%
Solids/Vol.: 39.05
%
PVC: 35.66
VOC,
lbs./gal: 1.70
VOC,
g/L: 204.00
10.0 12.0
26.0
31
.2
Formula Properties:
Density lbs./gal.: 10.71
Density
g/L:
1,285.1
KU
Visc.
@
R.T.:
95-100
pH
@
R.T.:
8.0-9.0
SOURCE:
Halox Pigments: Suggested Formulation
HG54-491
138
Water-Based Paint Formulations
Exterior House Paint Primer
I
flared>
entss:
Pigment Grind:
Water
Ucar Polyphobe 102 Rheo. Mod.
Ammonium Hydroxide, 28% Aqueous Solution
Nuosept 95
Col loi d 226/35
Propylene Glycol
Colloid 640
Triton Nonionic Surfactant N-101
Kronos 2310
Halox BW-100
Nicron 400
Letdown
:
Water
)
Ucar Polyphobe 102 )Premix
Ucar
Latex 625
Colloid 640
Butyl Carbi to1 Sol vent
NuoCi de 404-D
Triton Nonionic Surfactant
CA
Ammonium Hydroxide, 28% Aqueous Solution
Paint Properties:
Pigment Volume Concentration,
%:
32.0
Volume Solids,
%:
40.0
Weight Solids,
%:
54.5
Viscosity, equilibrated:
Stormer,
KU:
90
ICI,
Poise: 1.45
Freeze-Thaw Stability, cycles passed: 3
Heat-Aged Stability, 120F, weeks passed: 2
Film
Properties:
Contrast Ratio, 6-mil wet drawdown: 0.96
Ref 1 ectance,
%:
88.3
Sheen, 85: 19.9
Tannin Stain Resistance:
Cedar and Redwood: Very Good
Pounds
150.4
8.7
1.9
2.3
10.2
25.9
1.9
2.1
125.0
100.0
113.5
8.3
8.7
508.6
1.9
12.7
10.3
2.1
1.9
Gal lons
18.05
1
.oo
0.25
0.25
1
.oo
3.00
0.25
0.25
3.65
4.37
4.78
1
.oo
1
.oo
57.80
0.25
1.60
1
.oo
0.25
0.25
SOURCE: Ucar
Emulsion Systems:
Ucar
Latex
625:
Formulation
Suggestion
E-2456
Primers
139
Exterior House Paint Primer Based On Ucar Latex
163
I
nqred
i
ent
s
:
Pigment Grind:
Water
Cellosize Hydroxyethyl Cellulose
Nuosept 95
Col 1 oi d 226/35
Colloid 640
Triton Nonionic Surfactant N-101
Propylene Glycol
Tronox CR-828
Nicron 400 Talc
Halox
EW-100
~~
Pounds Gal lons
244.7 29.37
ER-30,000
3.5 0.32
2.3 0.25
10.5
I
.oo
1.9 0.25
2.1 0.25
25.9 3.00
125.0 3.65
113.5 4.76
100.0 4.37
Letdown
:
Ucar Latex 163 437.5 49.16
Ucar Filmer IET 12.7 1.60
Colloid 640 1.9 0.25
NuoCi de 404-D 10.3 1
.oo
Triton Nonionic Surfactant
CA
2.1 0.25
Ammonium Hydroxide, 28% Aqueous Solution 3.8 0.50
Paint Properties:
Pigment Volume Concentration,
%:
32.0
Volume Solids,
%:
40.0
Weight Solids,
%:
54.0
Weight per Gallon, lb: 11.0
Stormer,
KU:
86
ICI.
poise:
1
.O
pH, initial: 8.5
Freeze-Thaw Stability, 3 cycles: Pass
Heat Stability, 2 weeks at 120F: Pass
Film Properties:
Reflectance,
%:
88.3
Sheen, 85: 11.6
Contrast Ratio, 6-mil bar: 0.96
Tannin Stain Resistance cedar and redwood: Very Good
SOURCE:
Ucar Emulsion Systems: Formulation Suggestion E-2457
140
Water-Based Paint Formulations
General
Purpose
Latex Maintenance
Primer
-
Ingredients:
Pigment Grind:
Water
Busperse 39/Dispersant
Bubreak 448/Defoamer
!&
105.91
8.47
3.18
(Premix next
2
items)
Water 26.48
QP-15000 Cellosize/Hydroxyethyl
Cell
ul
ose
1.06
Igepal CTA 639/Surfactant 6.35
Aropl az 1271 /Long Oi
1
A1 kyd 40.47
Butrol 23/Modified Barium MetaboratelO5.91
Ti -Pure R-SOO/Ti tani um Dioxide-
Rutile 211.83
Mi ca-325/Potassi um A1 umi num Si
1
i
cate 26.48
Atomite/Calcium Carbonate 17.71
Nytal 3OO/Talc-Magnesium Silicate 17.71
Let Down:
Rhoplex MV23/Acrylic Emulsion 511.57
Texanol/Ester Alcohol
5.30
Ethylene Glycol 31 .77
Water
21
.18
Paint Properties:
%wt
.__
%VOl
Total Vehicle
66.65
87.45
Pi gment 33.35 12.55
Volatile 47.08
64.15
Organic Solvent 8.08 10.71
Non-Volati le 52.92 35.85
Non-Volatile Vehicle 19.56
23.20
Density (lb/U.S. gal):
11.41
Specific Gravity:
1
.37
P.V.C.: 35.00%
P/B Ratio: 1.705
Spread
I3
1
Mil:
575
F2
Coating VOC: 237
G/L
Material VOC:
111
G/L
Gal
12.71
0.79
0.47
3.18
0.09
0.72
4.82
3.44
6.36
1.13
0.78
0.75
58.13
0.67
3.41
2.54
Wt%
9.28
0.74
0.28
2.32
0.09
0.56
3.55
9.28
18.56
2.32
1.55
1.55
44.82
0.46
2.78
1
.86
SOURCE:
Buckman Laboratories: Formulation Suggestion:
KR-02
Primers
141
General
PurposeJL0.w Cost Water-Base
Primer
Grind:
Water
Butyl Cellosolve
Tamol 165
Troysol LAC
Drew L-493
AMP-95
Lbs./100 Gals. Gmsiliter
150.0 180.0
29.0 34.8
15.0 18.0
3.0
3.6
3.0 3.6
1
.o
1.2
Add the following at high speed and disperse to
5
Hegman grind.
Y.I.O.
YO-2087
Halox CW-491
Nytal 400
Letdown
:
Water
Mai ncote PR-71
Dibutyl Phthalate
Aqua Ammonia (28%)
Add grind portion under agitation and mix unt
add the following in order listed:
Ethanol 95%
Raybo 60
Add slowly while mixing at high speed.
Do
not
QR-700
Acrysol RM-1020
Mix until uniform.
50.0
60.0
100.0 120.0
250.0
300.0
93.0 111 .6
380.0
456.0
5.7
6.8
3.0
3.6
1
uniform. Then
14.5
17.4
5.0
6.0
aerate!
5.0
6.0
2.0
2.4
Formula Constants:
%
Pi gment/Wt
.
:
36.05
%
Pigment/Vol.: 16.29
%
Solids/Wt.: 54.20
%
Solids/Vol
.
:
31 .35
%
PVC: 42.63
VOC,
lbs. /gal.
:
1.54
VOC,
g/L: 184.68
Formula Properties:
Density 1
bs.
/gal.
:
11 .09
Density g/L: 1,331.0
KU
Visc.
@
R.T.:
90-95
pH
@
R.T.:
9.0-9.5
SOURCE:
Halox Pigments: Suggested Formulation PR-71/491A
142
Water-Based Paint Formulations
Hiqh Performance Bare Metal Primer
Gri
nd
:
Water
Butyl Cellosolve
Tamol 165
Troysol LAC
Drew L-493
AMP-95
Lbs./100 Gals. Gms/Liter
92.0 110.0
35.0 42.0
10.0 12.0
2.0 2.4
3.0
3.6
1
.o
1.2
Add the following at high speed and disperse to 5 Hegman grind.
Y.I.O.
YO-209
Halox SZP-391
Nytal 400
Letdown
:
Water
Mai ncote PR-7
Dibutyl Phtha
Aqua Ammonia ate
28%)
50.0 60.0
50.0 60.0
125.0 150.0
112.0 134.5
470.0 564.0
7.0 8.4
3.0 3.6
Add grind portion under agitation and mix until uniform. Then
add the following in order listed.
Ethanol 95%
Raybo
60
18.0 21.6
5.0 6.0
Add slowly while mixing at high speed.
Do
not aerate!
QR-708
Acrysol RM-1020
Mix until uniform.
Formula Constants:
%
Pi
gment/Wt.
:
22.51
%
Pi
gment/Vol
.
:
8.76
%
Solids/Wt.: 47.26
%
Sol
i
ds/Vol
.
:
35.78
%
PVC:
24.48
VOC,
lbs./gal.: 1.85
VOC,
g/L: 222.13
12.0 14.4
5.0
6.0
Formula Properties:
Density Lbs
.
/gal.
:
10.00
Density g/L: 1,199.7
KU
ViSc.
@
R.T.: 90-95
PH
@
R.T.: 9.0-9.5
SOURCE:
Halox Pigments: Suggested Formulation PR-71/391BM
Primers
143
Hitah
Performance Galvanized Metal Primer
Grind:
Water
Butyl Cellosolve
Tamol
165
Troysol LAC
AMP-95
Drew
L-493
Lbs./100
Gals. Gms/Liter
92.0 110.0
35.0
42.0
10.0
12.0
2.0 2.4
3.0 3.6
1
.o
1.2
Add the following at high speed and disperse to
5
Hegman grind.
Y.I.O. YO-2087
Halox
SZP-391
Shi
eldex
Nytal
400
Letdown
:
Water
Mai ncote
PR-71
Dibutyl Phthalate
Aqua Ammonia
(28%)
50.0
60.0
50.0 60.0
25.0 30.0
100.0
120.0
106.5 128.0
470.0 564.0
7.0 8.4
3.0
3.6
Add grind portion under agitation and mix until uniform. Then add
the following in order listed:
Ethanol
95%
Raybo
60
18.0
21 .6
5.0
6.0
Add slowly while mixing at high speed.
Do
not aerate!
OR-708
Acrysol
RM-1020
Mix until uniform.
Formula Constants:
%
Pi
gment/Wt
.
:
22.63
%
Pi gment/Vol
.
:
9.37
%
Solids/Wt.:
47.50
%
Solids/Vol.:
36.59
%
PVC:
25.75
VOC, lbs./gal.:
1.83
VOC, g/L:
219.19
12.0 14.4
5.0
6.0
Formula Properties:
Density lbs./gal.:
9.95
Density g/L:
1,193.2
KU
Visc.
@
R.T.:
90-95
pH
@
R.T.:
9.0-9.5
SOURCE:
Halox Pigments: Suggested Formulation PR-71/391GM
144
Water-Based Paint Formulations
High Performance
2K
Water-Base Epoxy Primer
Component
A:
Add the following in order listed
Oiacetone Alcohol
Water
Nopco
NDW
Mix
for
5
minutes and add the fol
speed.
Eai-Rez 5522-WY-55
R.I.O.
R-4098
Halox SZP-391
Wol 1 astokup
1
OES
Sparmi te
Lbs. /lo0 Gals. Gms(L1 ter
450.0
540.0
7.0 8.4
100.0 120.0
2.0
2.4
owing while mixing at high
100.0 120.0
50.0 60.0
150.0 180.0
100.0 120.0
High speed disperse to 5+ Hegman grind. Then add the following
slowly while mixing.
DO
NOT AERATE'
Epi-Rez
5522-WY-55
Water
Component
8:
Mix at low speed:
Epi -Cure 8290-Y-60
Nacorr 1754
30.0 36.0
25.0
30.0
Lbs. /lo0 Gal
s.
Gms/Li
ter
60.0
72.0
3.0 3.6
Add the following raw materials in order listed while mixing at
high speed:
Zeeospheres
400
100.0 120.0
325 Mesh
W.G.
Mica
10.0
12.0
High speed disperse to a 4t Hegman grind. Then add the following
slowly while mixing.
DO NOT
AERATE!
Water
40.0
48.0
Mix Ratio:* Component
A:
80%
by volume.
Component
8:
20% by volume.
*To
obtain optimum results, allow 20-30 minutes induction time
prior to application.
Formula Constants:
%
Pigment/Wt.
:
41.63
%
Pigment/Vol.: 18.70
%
Solids/Wt.: 65.77
%
Sol
i
ds/Vol
.
:
49.5%
%
PVC:
37.71
P/B
Ratio: 1.72
VOC,
lbs./gal.: 1.32
VOC,
g/L:
158.40
Formul a Properti es
:
Density lbs./gal.: 12.25
Density g/L: 1,470.0
Set-to-touch: 30 minutes
Dry Hard: Overnight
SOURCE:
Halox Pigments: Suggested Formulation Epi-Rez/BBl
Primers
145
Hiah
Performance
2K
Water-Base
EDOXV
Primer
Using
Halox
SZP-391
Component
A:
Lbs./lOO Gals. Grams/Li ter
Add the following in order listed:
Waterpoxy 1401
Ektasolve EP 375.0 450.0
30.0
36.0
Mix for 5 minutes and add the following while mixing at high
speed.
R.I.O.
R-4098
Halox SZP-391
Wollastokup 10ES
Nytal 400
100.0
75.0
100.0
150.0
120.0
90.0
120.0
180.0
High speed disperse to 5+ Hegman grind. Then add the following
slowly while mixing. Do not aearate!
Deionized water
240.0
288
*
0
Component
0:
Mix at low speed.
Waterpoxy 701
Ektasolve EP
Lbs./100 Gals. Grams/Li ter
80.0
5.0 96.0
6.0
Mix ratio:* Component
A
-
90% by volume.
Component B
-
10% by volume.
*To
obtain optimum results, allow 20-30 minutes induction time
prior to application.
Formula Constants:
%
Pi gment/Wt
.
:
36.75
%
Pigment/Vol.
:
15.80
%
Solids/Wt.: 60.10
%
Sol
i
ds/Vol
.
:
43.96
%
PVC: 35.93
P/B Ratio: 1.57
VOC,
lbs./gal.: 1.57
voc,
g/L: 188.40
Formula Properties:
Density
1
bs. /gal
.
:
11 .56
Density g/L: 1,387.2
Set-to-touch: 30 minutes
Dry Hard: Overnight
SOURCE: Halox Pigments: Suggested Formulation
146
Water-Based Paint Formulations
High Performance
2K
Water-Base Epoxy Primer
Usinq
Halox SZP-391
Component
A:
Lbs./100 Gals. Grams/Li ter
Add
the following in order listed:
Epi-Rez 5522-WY-55 450.0 540.0
Di
acetone Alcohol 7.0 8.4
Water 100.0 120.0
Nopco NDW 2.0 2.4
Mix
for
5 minutes and add the following while mixing at high
speed
:
R.1
.O.
R-4098
Halox SZP-391
Wollastokup lOES
Sparmi te
100.0
50.0
150.0
100.0
120.0
60.0
180.0
120.0
High speed disperse to 5+ Hegman grind. Then add the following
slowly while mixing. Do not aerate!
Epi
-Rez
5522-WY-55
Water
Component
8:
Mix at low speed:
€pi -Cure 8290-Y-60
30.0 36.0
25.0 30.0
Lbs./100 Gals. Grams/Li ter
60.0
72.0
3.6 Nacorr 1754 3.0
Add the following raw materials in order listed while mix
high speed:
Zeeospheres 400 100.0
325 Mesh
W.G.
Mica
10.0
ng at
20.0
12.0
High speed disperse to 4+ Hegman grind. Then add the following
slowly while mixing. Do not aerate!
Water 40.0 48.0
Mix Ratio:* Component
A
-
80% by volume.
Component
B
-
20% by volume.
*To obtain optimum results, allow 20-30 minutes induction
time prior to application.
Formula Constants: Formula Properties:
96
Pi gment/Wt.
:
41.63 Density lbs./gal: 12.25
%
Pigment/Vol
.
:
18.70 Density g/L: 1,470.0
%
Solids/Wt.: 65.77 Set-to-touch: 30 minutes
%
Sol ids/Vol
.
49.58 Dry Hard: Over n
i
gh
t
%
PVC: 37.71
P/B Ratio: 1.72
VOC,
lbs./gal.
:
1.32
voc,
g/L:
158.40
SOURCE:
Halox Pigments: Suggested Formulation
Primers
147
Hiqh Solids Red
Iron
Oxide
EDOXY Primer
Materi a1
:
Part
A:
Epon Resin
874-CX-90
Beetle 216-8
Shell Xylene
Shell MIBK
PGME Acetate
Zinc Phosphate 5-0852
10
ES
Wollastokup
Sparmi te
Mi
croMi ca
C-3000
Copperas R-5098
High Speed Disperse to a Texture of 5-6
N.S
Bentone SD-2
Part
B:
Epi-Cure Curing Agent 3140
Shell Xylene
She1 1 n-Butanol
Composite Blend:
Part
A
Part
B
Parts
A
and B: Viscosity: 85
K.U.
Typical Coating Properties:
Total weight solids, percent: 81.2
Total vol ume sol ids, percent: 65.4
PVC, percent: 35.0
Induction time, minutes: 30
Volatile Organic Compounds (VOC):
Pounds per gallon: 2.43
Grams per liter: 292
Fi
1
m
ProDert
i
es
:
Pounds
263.0
12.0
75.5
60.4
15.1
176.5
176.5
233.5
38.8
38.7
9.3
132.0
42.9
18.4
1099.3
193.3
Gal lons
28.85
1.41
10.49
9.10
1.86
6.74
7.29
6.35
1.36
0.90
0.65
16.32
5.95
2.73
75.00
25.00
(Drawdown on
CRS.
Cured for 7 days at 77F, 55% R.H.)
Pigment: binder ratio: 1.72
Curing agent phr, on solids: 56
Pot life (hrs; from 85-130
KU):
6
Pounds/gallon: 12.92
Dry
film
thickness: 1.5 mils
Set-to-touch dry, hrs.: 1.0
Cotton-free dry, hrs.: 7.5
Through-dry, hrs.:
18.0
Pencil hardness:
H
Impact resistance, (Di
r.
/Rev.
)
:
52/4
Flexibility: Pass 1/4"
Adhesion:
SA
Salt spray testing (500 hrs): 2F-2M
Water resistance (500 hrs at 160F): 4M
SOURCE: Shell Chemical Co.: Starting Formulation
No.
1819:
Epon
Resin 874-CX-Q0/Epi -Cure Curing Agent 31 40
148
Water-Based Paint Formulations
House Paint Primer
Ingredients:
Pigment Grind:
Water
Cellosize Hydroxyethyl Cellulose ER-30,000
Nuosept 95
Propylene Glycol
Col 1 oi d 226/35
Triton Nonionic Surfactant N-101
Colloid 650
Ti
-Pure R-902
325 Mesh White Waterground Mica
Nytal 300
Letdown
:
Ucar Latex 624
Ucar Filmer IBT
NuoCide 404D
Colloid 650
Ammonium Hydroxide, 28% Aqueous Solution
Pai nt Propert
i
es
:
Pigment Volume Concentration,
%:
30.0
Volume Solids,
%:
32.6
Viscosity, equi 1
i
brated:
Stormer,
KU:
80
ICI,
poise: 0.7
Weight per Gallon,
lb:
10.54
Pounds
283.8
3.5
2.3
25.9
6.4
2.2
1.9
150.0
25.0
100.0
426.7
10.7
10.3
2.0
2.0
Gal 1 ons
34.07
0.32
0.25
3.00
0.62
0.25
0.25
4.50
1.07
4.21
48.49
1.35
1
.oo
0.37
0.25
Freeze-Thaw Stability, 3 cycles: Pass
Heat-Aged Stability,
2
weeks at 120F: Pass
Film
Properties:
Contrast Ratio, 6-mil wet drawdown: 0.948
Ref
1 ectance,
%:
88.7
Sheen, 85:
7.0
Flow and Leveling, brushed: Good
Wet Adhesion: Excellent
Chalk Adhesion: Excellent
SOURCE:
Ucar Emulsion Systems: Ucar Latex 824: Formulation
Suggestion E-2425
Primers
149
Lead
Material:
Part
A:
Epi -Rez 5522-WY-55 Res
Di
acetone Alcohol
Col 1 oi d 640 Defoamer
Water
R0-4097 Kroma Red
Sparmi te
lOES
Wollastokup
Halox
SW-111
and Chromate Free Primer
n
High speed disperse to a texture
of
6-7
N.S.
Epi -Rez 5522-WY-55 Resin
15% Sodium Nitrite Solution (Water)
Water
Part B:
Epi-Cure 8290-Y-60 Curing Agent
Water
Zeeosphere 400
Water Ground Mica, 325 mesh
High speed disperse to a texture
of
4-5
N.S.
Composite Blend: Viscosity
Part
A
114
K.U.
Part B 101
K.U.
Parts
A
and B 106
K.U.
&
330.0
7.0
3.5
80.0
100.0
23.1
150.0
100.0
147.0
8.0
8.7
60.0
11.0
100.0
10.0
957.3
234.7
Gals
37.21
0.89
0.41
9.60
2.45
0.63
6.19
4.20
16.43
0.95
1 .04
6.80
1 .32
5.00
0.43
80.00
20.00
SOURCE:
Shell
Resins: Starting Formulation
No.
1818
I50
Water-Based
Paint
Formulations
Lead
and
Chromate Free Red
Iron
Oxide Primer
Material
:
Part
A:
Epi -Rez 5522-WY-55 Resin
Oiacetone Alcohol
Col
1
oi
d
640 Defoamer
Water
R0-4097 Kroma Red
Sparmi te
1
OES
Wol
1
astokup
Halox SW-111
High speed disperse to a texture of 5-6
P.C.S
Epi -Rez 5522-WY-55 Resin
Water
Part
8:
Epi-Cure 8290-Y-60 Curing Agent
Water
Zeeosphere Type 400
Water Ground Mica, 325 mesh
High speed disperse to a texture of 4-5
P.C.S
Water
Composite
B
Part
A
Part
B
Parts
A
and
SOURCE:
She
end
:
8
Viscosity
82
K.U.
101
K.U.
85
K.U.
!=,&
330.0
7.0
3.5
80.0
100.0
100.0
150.0
50.0
147.0
16.6
60.0
11.0
100.0
10.0
53
984
234
1
Resins: Starting Formulation
No.
180
Gals
37.21
0.89
0.41
9.60
2.45
2.73
6.19
2.10
16.43
1.99
6.80
1.32
5.00
0.43
6.45
80.00
20.00
Primers
151
Lead and Chromate Free Waterborne
EPOXY
Primer
Materi a1
:
Part
A:
Epi -Rez 5522-WY-55 Resin
Di
acetone A1 coho1
Colloid 640 Defoamer
Water
R0-4097 Kroma Red, Red Iron Oxide
Sparmite Barium Sulfate
lOES
Wollastokup
Halox SW-111
Zeeosphere 400
Water Groumd Mica, 325 Mesh
High speed disperse to texture
of
5-6
N.S.
€pi -Rez 5522-WY-55 Resin
15% Aqueous Sodium Nitrite Solution
Water
Part 9:
Epi-Cure 8292-Y-60 Curing Agent
Water
Composi te 81 end
:
Vi
scosi ty
Part
A
122
K.U.
Part
B
(#4 Ford cup,
Parts
A
and
B
68
K.U.
Typical Coating Properties:
15.1 Seconds)
Total Weight Solids,
%:
62.1
Total Volume Solids,
%:
46.3
P.V.C.,
%:
34.9
Induction Time, minutes: 30
Volatile Organic Compounds (VOC):
Pounds/Gallon: 1.23
Grams/Liter: 148
Resin Composition
(on
solids):
Epoxy Resin,
%:
07.6
Curing Agent,
%:
12.4
Pounds
330.0
7.0
3.5
60.0
71.1
71.1
106.7
100.0
71 .1
7.5
147.0
8.0
6.3
60.0
11c.o
989.3
170.0
Gal 1 ons
37.21
0.89
0.41
7.20
1.74
1.94
4.40
4.20
3.55
0.32
16.43
0.95
0.76
6.80
13.20
80.00
20.00
SOURCE: Shell Chemical Co.: Starting Formulation No. 1818:
Epi-Rez 5522-WY-55 Resin/Epi-Cure 8292-Y-60 Curing Agent
152
Water-Based Paint Formulations
Lead Based .Primer
Mater1 a1
:
Part
A:
2-Propoxyethanol
Triton
X-100
Surfactant
Tamol 731 Surfactant
9-148 Defoamer
Bentone LT, 3% in water
Blend well and add:
Red Iron Oxide
Basic Lead Silico Chromate
Cell te 499 Diatomaceous Earth
Maonesi um
Si
11
cate
Pounds
11.6
3.5
3.5
4.0
75.0
100.0
100.0
25.0
25.0
Gal 1 ons
1.50
0.39
0.38
0.48
8.95
2.34
2.93
1.30
1 .05
-
Increase disperser speed to 3,000
RPM.
Achieve grind fineness
of
6-7 PCS. Add under reduced agitation:
Epi -Rez 3520-WY-55 Resin 260.0 30.00
Tap Water 297.0 35.68
Part B:
Epi-Cure 8536-MY-60 Curing Agent
Composite B1 end
:
Part
A
Part 8
124.5
15.00
904.6 85.00
124.5
15.00
Typical Coating Properties:
Viscosity: Part
A:
65
KU
Part 8: 90
KU
Parts
A
and 8: 94
KU
Wei ght/Gall lon:
IO.
29
Application:
Brush:
As
is
Spray: Reduce
10
parts paint to 1 part water to a viscosity
of
80
Krebs Units
P.V.C., %:
25.2
Vehicle Non-Volatile,
%:
28.4
Total Volume Solids,
%:
30.2
Total Weight Solids,
%:
46.4
Resin Composition: Epoxy Resin,
%:
67
Volati 1
e
Composition: Pounds Gal 1 ons
Water 465.0 55.81
Curing Agent,
%:
33
Organic 85.2 11.20
Dry Characteristics (Room Temperature Cure):
Set to touch: 30-60 minutes
Dry to handle:
60
minutes
Dry hard:
4
hours
Dry to recoat: 20 hours
SOURCE:
Shell Chemical Co.
:
Starting Formulation No. 1809:
Epi-Rez
3520-WY-55
Resin/Epi-Cure
8536-MY-60
Curing Agent
Primers
153
Lead
Silico
Chromate Primer
Material
:
Part
A:
Epi -Rez 5522-WY-55 Resin
Di
acetone
A1
coho1
Triton X-100 Surfactant
Water
Colloid 640 Defoamer
RO-4097 Kroma Red, Red Iron
Zeeospheres Type 400
Basic Lead Silico Chromate
Oxide
Pebble
mill
approximately 18 hours
Epi
-Rez 5522-WY-55 Resin
Water
Part 8:
Epi -Cure 8290-Y-60 Curing Agent
Water
Zeeospheres Type 400
High speed disperse to a texture of 6 PC
Pounds
200.0
6.6
5.0
84.8
3.5
104.4
194.6
83.5
266.8
10.2
45.3
35.0
150.0
Water 26.4
Composi
te
81 end
:
Viscosity
Part
A
87
K.U.
Part B 140
K.U.
Parts
A
and B 90
K.U.
Typical Coating Properties:
Total Weight Solids,
%:
67.1
Total Volume Sol ids,
%:
51.4
P.V.C.,
%:
43.1
Volatile Organic Compounds (VOC):
Pounds/Gal
1
on
:
1
.01
Grams/Liter: 121
Induction Time, minutes: 30
Resin Composition (based on solids)
:
Epoxy Resin,
%:
90.0
Curing Agent,
%:
10.0
Total,
%:
100.0
Reduction for Conventional Spray (by volume):
Parts
A
and
B:
20 parts
Water:
1
part
959.4
256.7
Gal
1
ons
22.35
0.84
0.56
10.18
0.41
2.45
9.73
2.45
29.81
1.22
5.13
4.20
7.50
3.17
80.00
20.00
SOURCE: Shell Chemical Co.: Starting Formulation
No.
1813:
€pi-Rez 5522-WY-55 Resin/Epi-Cure
8290-Y-60
Curing Agent
154
Water-Based Paint Formulations
Low
Sheen Gray Primer
Materi a1
:
Part
A:
Epi -Rez 5522-WY-55 Resin
Water
Part
8:
Epi -Cure 8290-Y-60 Curing Agent
Kronos 2020
SP
Black
4
Powder
Patcote 847 Def
Part
A
Part
B
Parts
A
Typical
Tota
Tota
PVC
,
Vola
Water
High Speed
D
Water
Composite Blend
and
B
Coati nQ
amer
sperse to 7-8
N.S.
Texture.
Vi
scosi ty
48
K.U.
76
K.U.
62
K.U.
Prooert
i
es
:
Weigh: Sol;ds,
%:
51.1
Weight Solids,
%:
39.5
%:
14.2
ile Organic Compounds (VOC):
Pounds/Gallon:
1
.51
Grams/Liter: 181
Induction Time, minutes: 30
Pounds
522.1
69.4
82.1
191
.o
0.3
2.0
25.0
126.2
592.5
426.6
Gal 1 ons
58.34
8.33
9.30
5.58
0.02
0.28
3.00
15.15
66.67
33.33
Resin Composition (based on solids):
Epoxy Resin,
%:
85.0
Curing Agent,
%:
15.0
Reduction for Conventional Spray (by volume):
(Viscosity
=
55
K.U.)
Parts
A
and
B:
11 parts
Water:
1
part
SOURCE:
Shell Chemical Co.: Starting Formulation
No.
1812:
€pi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60
Primers
155
Material
:
Water
Igepal CO-630
Tamol 731
Foamaster VL
Surfynol 104H
Diethylene Glycol
Titanox 2101
Raven 1020
Halox BW-191
QP-4400
#on-Lead/Non-Chromate
Primer
Monomethyl Ether
Lbs.
83.89
2.54
0.87
10.70
1.10
1.66
35.32
58.50
0.65
148.69
High speed Cowles 15-20 minutes to a 3-4 Hegman grind.
Add letdown:
Arolon 820-W-49 540.36
Premix:
Dalpad
A
Water
Premix:
Aroplaz 1271
Cobalt Hydrocure
I1
Calci um Hydrocem
Zi
rconi um Hydrocem
Then add:
Surfynol 104H
Skane M-8
Premi x
:
OR-708
Water
13.24
58.26
37.99
3.79
3.79
1.88
3.31
2.20
0.17
2.26
Gals.
10.06
0.29
0.07
1.23
0.14
0.21
4.14
1.75
0.03
6.27
61.40
1.43
6.99
4.54
0.49
0.46
0.22
0.17
0.15
0.02
0.26
Analysis:
Pigment Volume Concentration, Percent: 18.85
Pigment/Binder Ratio: 0.69/1
Percent Sol ids, Weight
:
50.54
Percent Solids, Volume: 34.52
Viscosity
C
25C,
KU:
85-89
Gloss
(60):
Flat
Pounds/Gallon: 10.08
VOC
(excluding water):
pH: 8.7-9.2
Grams/Liter: 70.8
Pounds/Gallon: 0.6
SOURCE:
Reichhold Chemicals, Inc.: Arolon 820: Formula 2025-80-1
156
Water-Based Paint
Formulations
Primer for Factory-Pri med Hardboard Si di
ng
Ingredients:
Pigment Grind:
Water
Tergitol Nonionic Surfactant
NP-10
Tamol 731
Foamaster VF
Ti
-Pure R-960
ASP
400
Letdown
:
Ucar Vehicle 462
Ucar Acrylic 515
Cyme1 325
Foamaster VF
Nuocide 960
Arcosolve
PP
Solvent
Propylene Glycol
Pounds
164.3
6.0
17.6
2.6
96.5
289.4
325.0
118.2
31.3
0.9
5.1
31 .3
35.3
Gallons
19.8
0.6
1.9
0.3
2.9
13.5
37.0
13.0
3.0
0.1
0.6
3.0
4.3
Paint Properties:
Pigment Volume Concentration,
%:
42
Crosslinker, phr: 12
Cosolvent, phr: 15
Volume Solids,
%:
40
Weight per Gallon, lb: 11.2
SOURCE:
Ucar Emulsion Systems: Ucar Vehicle
462:
Suggested
Formu 1 at
i
on
Primers
157
Primer
20323D
Based on Phosguard
J-Om
and 10
ES
Wollastocoat
Henkel
‘s
Waterpoxy 1401 :701 _Sysrem
Component
A:
Waterpoxy 1401
Ektasolve
EP
10
ES
Wol lastocoat
Red Iron Oxide 5-3106
Phosguard 5-0853
Disperse to
5
n.s.u., reduce speed and add:
Methyl Amyl Ketone
Water
Component
8:
Waterpoxy 701
Ektasolve
EP
Formulation Constants:
&
452.05
10.44
255.50
137.40
147.89
55.00
74.60
100.00
10.40
Non Volatile by Weight: 0.70
VOC
grms/litre:
Non Volatile by Volume: 0.53
VOC
lbs./gal.:
PVC
:
0.36 Weight/Gallon Comp
A:
CPVC
:
0.46 Weight/Gallon Comp
0:
PVC/CPVC
:
0.79 Mixing Ratio:
Pigment Content: 0.44 Weight per Gallon:
NVV
by
Wt.
of
Vehicle: 0.47
SOURCE:
Nyco Minerals, Inc.: Primer
20323D
Gals
49.95
1
.38
10.56
3.30
5.22
8.09
8.96
11.17
1.37
236.82
1.98
12.96
8.80
6.97
12.43
1.58
Water-Based Paint Formulations
Primer 203236 Based on Phosguard 5-0813
and 10
ES
Wollastocoat
Henkel
‘s
Waterpoxy 1401 :701 System
Component
A:
Waterpoxy 1401
Ektasolve EP
10
ES
Wollastocoat
Red Iron Oxide 5-3106
Phosguard 5-0813
Disperse to 5 n.s.u., reduce speed and add:
Methyl Amyl Ketone
Water
Component
B:
Waterpoxy 701
Ektasolve EP
Formulation Constants
Lbs
452.05
10.44
255.50
137.40
130.49
55.00
74.60
100.00
10.40
PVC
:
0.36 Wei ght/Gai
CPVC
:
0.46 Weight/Gal
PVC/CPVC
:
0.79 Mixing Rat
Pigment Content; 0.43 Weight per
NVV by
Wt.
of
Vehicle: 0.47
Non Volatile by Weight: 0.70
VOC
grms/litre:
Non Volatile by Volume: 0.53
VOC
lbs./g 1.
:
on Comp
A:
12.76
on Comp
9:
8.80
0:
6.97
Gallon: 12.26
Gals
49.95
1.38
10.56
3.30
5.22
8.09
8.96
11.17
1.37
236.82
1.98
SOURCE:
Nyco Minerals, Inc.: Primer
203230
Primers
159
Primer
20596F
Based on Heucophos
ZPZ
~~
and
10
ES
Wollasto-
__~_
Henkel's
-
Waterpoxy
1401:701
System
Component
A:
Waterpoxy
1401
Ektasolve EP
10
ES Wol
1
astocoat
Red Iron Oxide
5-3106
Heucophos ZPZ
Disperse to
5
n.s.u., reduce speed and add:
Methyl Amyl Ketone
Water
Component
0:
Waterpoxy
701
Ektasolve EP
Formulati
on
Constants
Lbs
&lls
452.05 49.95
10.44 1 .38
255.50 10.56
137.40 3.30
152.48 5.22
55.00
8.09
74.60 8.96
100.00 11.17
10.40 1.37
Non Volatile by Weight:
0.70
VOC grms/litre:
236.82
Non
Volatile by Volume:
0.53
VOC
1
bs. /gal
.
:
1.98
PVC
:
0.36
Weight/Gallon Comp
A:
13.01
cpvc:
0.55
Weight/Gallon Comp
6: 8.80
PVC/CPVC
:
0.67
Mixing Ratio:
6.97
Pigment Content:
0.44
Weight per Gallon:
12.48
NVV by Wt.
of
Vehicle:
0.47
SOURCE:
Nyco
Minerals, Inc.: Primer
20596F
I60
Water-Based Paint Formulations
Primer
205966
Based On HeucoDhos ZMP
and
10
ES
Wollastocoat
Henkel's Waterpoxy
1401:701
System
Component
A:
Waterpoxy
1401
Ektasolve
EP
10
ES
Wollastocoat
Red Iron Oxide
5-3106
Heucophos
ZMP
Disperse to
5
n.s.u., reduce speed and add:
Methyl Amyl Ketone
Water
Component
B:
Waterpoxy
701
Ektasolve
EP
Formulation Constants
&
Gals
452.05 49.95
10.44
1
.38
255.50 10.56
137.40 3.30
152.48 5.22
55.00 8.09
74.60 8.96
100.00 11.17
10.40 1.37
Non Volatile by Weight:
0.70
VOC
grms/litre:
236.82
PVC
:
0.36
Weight/Gallon Comp
A:
13.01
CPVC:
0.53
Weight/Gallon Comp
8:
8.80
PVC/CPVC
:
0.68
Mixing Ratio:
6.97
Pigment Content
:
0.44
Weight per Gallon:
12.48
NVV
by
Wt.
of
Vehicle:
0.47
SOURCE:
Nyco Minerals, Inc.: Primer
205966
Non Volatile by Volume:
0.53
VOC
lbs./gal.:
1.98
Primers
161
Primer 21102E Based on
Molycoat
212
and 10
AS
Wollastocoat
Henkel's Waterpoxy 1401:701 System
Component
A:
Waterpoxy 1401
Ektasolve EP
10 AS Wollastocoat
Red Iron Oxide 5-3106
Molywhite 212
Disperse to 5 n.s.u., reduce speed and add:
Methyl Amyl Ketone
Water
Component
9:
Waterpoxy 701
Ektasolve EP
&
452.05
10.44
255.50
137.40
130.39
55.00
74.60
100.00
10.40
Formulation Constants
Non Volatile by Weight: 0.70 VOC grms/litre:
Non Volatile
bv
Volume: 0.53
VOC
lbs./aal. 3:
&3&
49.95
1.38
10.56
3.30
5.22
8.09
8.96
11.17
1.37
236.82
1.98
PVC
:
0.36 Weight/Gailon Comp
A:
12.76
CPVC
:
0.55
Weight/Gallon Comp 8: 8.80
PVC/CPVC
:
0.66 Mixing Ratio: 6.97
Pigment Content: 0.43 Weight per Gallon: 12.26
NVV by
Wt.
of
Vehicle: 0.47
SOURCE: Nyco Minerals, Inc.: Primer 21102E
162
Water-Based Paint Formulations
Primer 21
105H
Based on Phosauard
5-0815
and
10
ES
Wollastocoat
Henkel's Waterpoxy
1401:702
System
Component
A:
Waterpoxy 1401
Ektasolve
EP
10
ES
Wol lastocoat
Red
Iron
Oxide 5-3106
Phosguard 5-081 5
Disperse to 5 n.s.u., reduce speed and add:
Methyl Amyl Ketone
Water
Component
0:
Waterpoxy 702
Ektasolve
EP
Formulation Constants
!&
Gals
452.05 49.95
10.44 1.38
255.50 10.56
137.40 3.30
139.19 5.22
55.00 8.09
74.60 8.96
45.28 5.27
23.41 3.08
Non
Volatile by Weight: 0.69
VOC
grms/litre: 237.36
Non Volatile by Volume: 0.51
VOC
lbs./gal.: 1.98
PVC
:
0.39 Weight/Gallon Comp
A:
12.86
CPVC
:
0.50 Weight/Gallon Comp
B:
8.23
PVC/CPVC
:
0.79 Mixing Ratio: 10.47
Pigment Content
:
0.45 Weight per Gallon: 12.45
NVV
by
Wt.
of
Vehicle: 0.44
SOURCE:
Nyco Minerals, Inc.:
Primer
21105H
Primers
163
Primer
211051
Based
On
Nalzin
2
and
10
ES
Wollastocoat
Henkel
's
Waterpoxy
1401
:702
System
Component
A:
Waterpoxy
1401
Ektasolve EP
10
ES
Wol lastocoat
Red Iron Oxide
5-3106
Nalzin
2
Disperse to
5
n.s.u., reduce speed and add:
Methyl Amyl Ketone
Water
Component
8:
Waterpoxy
702
Ektasolve
EP
Formulation Constants
&
452.05
10.44
255.50
137.40
172.32
55.00
74.60
45.28
23.41
Non Volatile by Weight:
0.70
VOC
grms/litre:
Non Volatile by Volume:
0.51
VOC
lbs./gal.:
PVC
:
0.39
Weight/Gallon Comp
A:
CPVC
:
0.54
Weight/Gallon Comp
8:
PVC/CPVC
:
0.73
Mixing Ratio:
Pigment Content
:
0.46
Weight per Gallon:
NVV
by
Wt.
of
Vehicle:
0.43
SOURCE:
Nyco
Minerals, Inc.: Primer
211051
Gals
49.95
1.38
10.56
3.30
5.22
8.09
8.96
5.27
3.08
237.36
1.98
13.23
8.23
10.47
12.80
164
Water-Based Paint Formulations
Primer 21109C Based
on
Strontium Chromate
and
10
ES
Wollastocoat
Henkel's Waterpoxy 1401:702 System
Component
A:
Waterpoxy 1401
Ektasolve
EP
10
ES
Wollastocoat
Red Iron Oxide 5-3106
Strontium Chromate
Disperse to
5
n.s.u., reduce speed and add:
Methyl Amyl Ketone
Water
Component
B:
Waterpoxy 702
Ektasolve
EP
Formulation Constants
*L
453.17
10.47
256.20
137.75
166.40
55.10
74.79
68.04
35.18
Non Volatile
bv
Weiaht: 0.69
VOC
arms/litre:
CPVC
:
0.54 Wei ght/Gal
1
on
PVC/CPVC
:
0.70
Mixing Ratio:
Pigment Content: 0.45 Weight per Ga
NVV
by
Wt.
of
Vehicle: 0.44
50.07
1.38
10.59
3.31
5.27
8.10
8.98
7.91
4.64
250.17
2.09
Non Volatile
b;
Volhe: 0.51
VOC
ibs./gal.:
PVC
:
0.38 Weight/Gallon Comp
A:
13.16
Comp
B:
8.23
6.99
lon: 12.54
SOURCE:
Nyco Minerals, Inc.: Primer
21109C
Primers
165
Rapid
Dry Waterborne
Epoxy
Primer
Material
:
Part
A:
Epi
-Rez 5522-WY-55 Resin
Di
acetone A1 coho1
Colloid 640 Defoamer
Water
R0-4097 Kroma Red, Red Iron Oxide
lOES Wollastokup
Halox SW-111
High Speed Disperse to a Texture of 5-6
N.S
Epi -Rez 5522-W-55 Resin
Epi
-Rez 3540-WY-55 Resin
15% Aqueous solution of sodium nitrite
Water
Part B:
Epi-Cure 8290-Y-60 Curing Agent
Water
Zeeosphere 400 type
Water Ground Mica, 325 Mesh
High Speed Disperse to a texture of 4-5
N.S
Water
Glacial Acetic Acid
Composite Blend: Viscosity
Part
A
64
K.U.
Part
0
70
K.U.
Parts
A
and
B
62
K.U.
Typical Coating Properties:
Total Weight Solids,
%:
59.1
Total Volume Solids,
%:
43.8
P.V.C.,
%:
36.2
Induction Time, minutes:
30
Volatile Organic Compounds (VOC):
Pounds/Gallon: 1.19
Grams/Liter: 142.8
Res4 n ComDosi
ti
on
:
Epoxy Resin,
%:
89.6
Curing Agent,
%:
10.4
Reduction to Spray Viscosity: None required
Pounds
258.7
5.4
2.7
59.4
77.6
116.6
116.6
114.3
74.1
6.2
79.7
46.7
8.6
77.0
7.7
78.5
0.4
911.4
219.7
Gal 1 ons
28.92
0.69
0.32
7.13
1.90
4.81
4.90
12.77
8.24
0.74
9.58
5.29
1.03
3.89
0.33
9.42
0.04
80.00
20
*
00
SOURCE: Shell Chemical
Co.:
Starting Formulation
No.
1814:
Epi-Rez
5522-WY-55
Resin/Epi-Rez
3540-WY-55
Resin/
Epi-Cure
8290-Y-60
Curing Agent
166
Water-Based Paint Formulations
Rapid
Dry
Waterborne Epoxy Primer
Material Part
A:
Epi-Rez 5522-WY-55 Waterborne Resin
Epi-Rez 3540-WY-55 Waterborne Resin
Colloid 640
Water
Bentone
LT
High Speed Mix for 15 minutes
Water
Di
acetone Alcohol
R0-4097 Kroma Red, Red Iron Oxide
Halox SW-111
Sparmi te
325 Mesh Wet Ground Mica
399 Lo-Mi cron
High Speed Disperse to a texture
of
5-6
N.S.
Pounds Gal
1
ons
205.0 22.78
___~
61.9 6.88
5.0 0.60
140.0 16.81
3.0 0.20
30.0 3.60
7.8 1
.oo
65.5 1.60
93.8 3.94
46.7 1.28
46.9 2.00
85.0 3.78
Epi-Rez 5522-WY-55 Resin 18.8 2.09
15% Aqueous solution of potassium nitrite 8.0 0.95
Water 104.0 12.49
Material Part 8:
Epi -Cure 8292-Y-60 Curing Agent
Ektasolve
EP
Water
27.0 3.08
37.9 5.00
99.3 11.92
Composite Blend: Viscosity
Part
A
102
K.U.
921.4 80.00
Part 8 10.5 secs (Ford #4) 164.2
20.00
Parts
A
and 8 68
K.U.
Typical Coating Properties:
Resin/Curing Agent Ratio (solids basis):
Epoxy Resin: 88.1
Curing Agent: 11.9
Total weight solids,
%:
47.6
Total volume solids,
%:
33.2
P.V.C.,
%:
40.8
Induction time, minutes: 30
Volatile Organic Compounds (VOC):
Pounds/gal
1
on
:
1 .95
Grams/liter: 234
SOURCE:
Shell Chemical
Co.:
Starting Formulation
No.
1821:
Epi-Rez
5522-WY-55
Waterborne Resin/Epi-Rez 3540-WY-55
Waterborne Resin/Epi-Cure
8292-Y-60
Curing Agent
Primers
167
Red Inhibitive Maintenance Primer
Inaredi ents:
Pigment Grind:
Water
Bentone LT
Methyl Carbitol Solvent
Tamol 681
Nuosept 95
DeeFo HG-12
Triton Nonionic Surfactant CF-10
Ammonium Hydroxide, 28% Aqueous Solution
Acrysol RM-2020
Heucophos
ZBZ
Atomite
Letdown
:
Methyl Carbitol Solvent
Acrysol SCT-275
Ucar Vehicle 435
Ucar Filmer
IBT
Troysan Polyphase AF-1
Foamex 825
Sodium Nitrite, 15% Aqueous Solution
Ammonium Hydroxide, 28% Aqueous Solution
5-3103
Adjust to minimum pH 8.7
Pounds
151.5
1
.o
25.5
18.2
2.3
2.1
2.2
1.8
17.2
50.0
75.0
145.8
8.5
8.6
505.1
11.4
4.9
2.1
9.0
1.8
Gallons
18.19
0.06
3.00
2.00
0.25
0.25
0.25
0.25
2.00
1.20
2.51
6.46
1
.oo
1
.oo
58.06
1.44
0.50
0.25
1.08
0.25
Paint Properties:
Pigment Volume Concentration (PVC),
%:
30.0
Total Solids,
%:
by volume: 34.0
pH Value, initial: 8.7
Viscosity:
Stormer.
KU:
80
ICI,
poise: 0.7
Weight per Gallon, lb: 10.4
Freeze-Thaw Stability,
3
cycles: Pass
Heat Stability, 2 weeks at 140F: Pass
SOURCE:
Ucar Emulsion Systems: Ucar Vehicle
435:
Formulation
SugQestion M-2452
168
Water-Based Paint Formulations
Red Iron Oxide Corrosion Resistant EPOXY Primer
(Two
Component System)
Ingredients:
-
Lb
(Prepare Part
#l
&
Part #2 separately)
Part
#l
Epotuf 37-618/Epoxy Resin Hardener 147.91
Xylol/Xylene 95.36
Ye1 ki ns-TS/Soya Lecithin 3.89
Butrol 23/Modified Barium Meta-
borate 194.62
Red Iron Oxide 194.62
Nytal 300/Talc-Magnesium Silicate 18.49
Part
#2:
Epotuf 38-501/Epoxy Resin
Methyl Isobutyl Ketone
Xylol /Xylene
272.91
70.06
105.10
Mix two components in 1:l ratio and wait for
paint application.
Pigment
Vol ati
1
e
Organi
c
Solvent
Non-Vol at
i
1 e
Non-Volatile Veh
Density (lb/U.S.
Specific Gravity
P.V.C.: 47.19%
P/B
Ratio: 1.323
Paint Properti
es
:
%Wt
%vel
Total Vehicle 63.03 87.92
36.97 12.08
35.09 74.41
35.09 74.41
64.91 25.59
cle 27.94 13.52
gal): 11.03
1.32
18.96 13.41
13.19 8.65
0.46 0.35
6.32 17.65
4.98 17.65
0.78 1.68
30.29 24.74
10.49 6.35
14.54 9.53
30 minutes before
Spread
@
1
Mil:
411 F2
Coating
VOC:
464 G/L
Material
VOC:
464 G/L
SOURCE: Buckman Laboratories: Formulation Suggestion:
KQ-23
Primers
169
Red Iron Oxide Primer
Material
:
Part
A:
2-Propoxyethanol
Triton X-100 Surfactant
Tamol 731 Surfactant
91
48 Defoamer
Bentone LT, 3% in water
Blend well and add:
Red Iron Oxide
Celite 499 Diatomaceous Earth
Magnesi um
Si
1
i
cate
Pounds Gallons
11.6 1.50
3.5 0.39
3.5 0.38
4.0 0.48
75.0 8.95
~___
100.0 2.34
25.0
I
.30
100.0 4.22
Disperse to a grind fineness
of
6-7 P.C.S., then add under
agitation:
Epi -Rez 3520-WY-55 Resin
Tap Water
Part
B:
Epi -Cure 8536-MY-60 Curi ng Agent
Composite 81 end
:
Part
A
Part 8
276.0 30.00
295.0 35.44
124.5 15.00
893.6 85.00
124.5 15.00
Typical Coating Properties:
Viscosity: Part
A:
68 Krebs Units
Part B: 90 Krebs Units
Parts
A
and B: 98 Krebs units
Pounds/Gal lon: 10.18
Application:
Brush: as is
Spray: Reduce 10 parts paint to 1 part water to a viscosity
of 83 Krebs Units
P.V.C.,
%:
25.2
Vehicle Non-Volatile,
%:
29.2
Total Volume Solids,
%:
31.3
Total Weight Solids,
%:
45.3
Resin Composition: Epoxy Resin,
%:
67
Vol ati 1 e Composi
ti
on Pounds Gallons
Water 467.0 56.14
Curing Agent,
%:
33
Organics 85.2 11.20
Volatile Organic Compounds (VOC):
Pounds/Gallon: 2.05
Grams/Liter: 246
SOURCE: Shell Chemical Co.: Starting Formulation No. 1806:
Epi-Rez
3520-WY-55 Resin/Epi-Cure 8536-MY-60 Curing Agent
170
Water-Based Paint Formulations
Red
Iron
Oxide
Primer
Ingredients:
-
Lb
Pi Oment
Or
i
nd
:
Water 117.69
Busperse 39/Dispersant 5.65
Bubreak 448/Defoamer 2.82
Zinc
Sul
fate-Heptahydrate 1.88
Igepal CTA 639/Surfactant 2.82
(Mix 10 minutes and add)
Butrol 23/Modi
f
i
ed Bari um Meta-
borate 47.08
Red Iron Oxide 94.15
Nytal 300/Talc-Magnesi
um
Si 1
i
cate 94.15
Let Down:
(Premix all the following ingredients and th
Beckosol 13-402/Water Reducible
A1 kyd 282.46
Butyl Cellosolve 84.74
Ammonium Hydroxide-28% 22.60
Water 233.50
Act
i
v-8/Dri er 0.94
Zi
rconi urn 6%/Dri er 5.65
Cobalt Naphthenate-G%/Drier 1.88
Antiskinning Agent 1.88
Paint Properties:
%vel
Total Vehicle 76.27 91.98
Pigment 23.73 8.02
Volatile 54.56 68.54
Organic Solvent 19.43 26.38
Non-Volati le 45.44 31.46
Non-Volatile Vehicle 21.72 23.44
Density (lb/U.S. gal): 10.00
Speci
f
i
c Gravity
:
1 .20
P.V.C.: 25.50%
P/B Ratio: 1.093
Spread
@
1
Mil:
505
F2
Coating
VOC:
403 G/L
Material VOC: 233 G/L
en
__
Ga 1
14.13
0.53
0.42
0.11
0.32
1.53
2.41
3.97
add to
32.84
11.28
3.01
28.03
0.12
0.26
0.79
0.25
Wt%
11.77
0.56
0.28
0.19
0.28
4.71
9.42
9.42
the grind)
28.25
0.47
2.26
23.35
0.09
0.19
0.56
0.19
SOURCE:
Buckman Laboratories: Formulation Suggestion: KP-10
Primers
171
Red
Iron
Oxide Water Reducible Alkvd Primer
Inqredients:
-
Lb
Pigment Grind:
Water 154.98
1
Busperse 39/Dispersant 5.81
Bubreak 448/Oefoamer 2.91
Igepal CTA 639/Surfactant 2.91
Zinc
Sulfate-Heptahydrate 1.94
Butrol 23/Modified Barium Meta-
borate 48.43
Red Iron Oxide 98.86
Nytal 300/Talc-Magnesium Silicate 193.72
Gal
18.60
0.54
0.43
0.33
0.12
1.57
2.48
8.17
Wt%
14.64
0.55
0.27
0.27
0.18
4.57
9.15
18.30
Let Down:
(Premix all the following ingredients and then add to the grind.)
Cargill 7464/Water Reducible Alkyd 248.93 28.78 23.51
Secondary Butyl Alcohol 86.21 12.81 8.14
Ammonium Hydroxide-28% 9.69 1.29 0.91
Water 200.50 24.07 18.94
Cobalt Naphthenate-6%/Orier 1.94 0.26 0.18
Zi
rconi um 6%/Dri er 3.87 0.54 0.37
Pai
nt
Properti
as:
Total Vehicle 67.
ao
87.66
Pigment 32.20 12.34
Volati 1 e 49.71 67.42
Organic Solvent 16.14 24.74
Non-Vol at
i
1 e 50.29 32.58
Non-Volatile Vehicle 18.08 20.24
Density (lb/U.S. gal): 10.59
Specific Gravity: 1.27
P.V.C.: 37.88%
P/B Ratio: 1.781
Spread
I3
1
Mil:
523 F2
Coating
VOC:
357 G/L
Material
VOC:
205 G/L
SOURCE:
Buckman Laboratories: Formulation Suggestion: KP-09
I72 Water-Based Paint Formulations
Rust Inhibitive Chromate Primer
Material:
Water
Tamol
731
Triton
CF-10
Nopco NDW
Ethylene Glycol
Dowicil
75
Kelecin
1081
Mix at low speed:
Titanox
2101
Zinc Chromate
Y539D
Oncor
M50
Mica
325
Snowf
1
ake
Lampblack
#877
QP-4400
Lbs.
Gals
.
136.0 16.33
16.0 1.85
3.0 0.34
2.0 0.27
26.0 2.80
0.5 0.02
2.0 0.24
200.0 6.01
15.0 0.52
30.0
0.88
33.0 1.41
100.0 4.43
4.0 0.37
1.2
0
:1 1
Grind under high shear
15-20
minutes.
NOTE:
Do
not allow temperature to exceed
llOF
during grind.
Under low speed add letdown:
Nopco
NDW
1.5
0.20
Arolon
820-W-49 500.0 57.08
Ammon
i
a
7.0 0.84
Diethylene Glycol Monobutyl Ether
6.0 0.76
Diethylene Glycol Monobutyl Ether Acetate
6.0 0.73
Prebl end
:
Aroplaz
1271
or
1272
Triton
CF-10
Water
25.7 3.08
1.3 0.15
4.0 0.48
Analysis:
Pigment/Binder Ratio:
1.37/1
Pounds/Gallon:
11.33
Percent Nonvolatile, Weight:
58.5
Percent Nonvolatile, Volume:
43.4
Pigment Volume Concentration, Percent:
31
.O
pH:
8.8
Viscosity
@
25C,
KU:
75-78
60/20
Gloss: Flat
Grind Hegman:
4-5
VOC
(excluding water):
Grams/Li ter
:
11
3.0
Pounds/Gallon:
0.94
SOURCE: Reichhold Chemicals, Inc.: Arolon
820:
Formula
5-3
Primers
173
Solvent Resistant, Water-Reducible
EPOXV
Primer
Material
:.
Part
A:
Epi -Rez 5522-W-55 Resin
Di
acetone A1 coho1
Triton X-100 Surfactant
Water
Colloid 640 Defoamer
R0-4097 Kroma Red, Red Iron Oxide
Zeeospheres Type 600
Pebble
mill
approximately 18 hours
Epi -Rez 5522-WY-55 Resin
Water
Part
6:
Epi-Cure 8290-Y-60 Curing Agent
Water
Composite Blend: Viscosity
Part
A
64 K.U.
Part
0
58
K.U.
Parts
A
t
B
85
K.U.
Pounds
200.0
6.6
5.0
84.8
3.5
104.4
307.1
187.2
39.5
118.3
55.0
938.1
173.3
Gal
1
ons
22.35
0.84
0.56
10.18
0.41
2.45
17.55
20.92
4.74
13.40
6.60
80.00
20.00
Typical Coating Properties:
Total Weight Solids,
%:
62.6
Total Volume Solids,
%:
49.2
P.V.C.,
%:
40.7
Volatile Organic Compounds (VOC):
Pounds/Gal 1 on
:
1 .37
Grams/Li ter
:
164
Induction Time, minutes: 30
Resin Composition (based on solids):
Epoxy Resin,
%:
75.0
Curing Agent,
%:
25.0
Total,
%:
100.0
Reduction for Conventional Spray (by volume):
Parts
A
and
6:
36
parts
Water:
1
part
SOURCE: Shell Chemical Co.: Starting Formulation
No.
1808:
Epi-Rez 5522-W-55 Resin/Epi-Cure
8290-Y-60
Curing Agent
174
Water-Based Paint Formulations
TT-P-1975
Federal SDecification Metal Primer
Inqredients:
Pigment Grind:
Water
Cell osi ze Hydroxyethyl Cell ul ose ER-15M
Dispersant
(1
)
Nonionic Surfactant
(2)
Ethylene Glycol
Buffer
(3)
Antifoam
(4)
Preservative
(5)
Titanium Dioxide
(6)
Inhibitive Pigment
(7)
Mica
(8)
Calcium Carbonate
(9)
Pounds
266.4
1
.o
15.2
2.7
26.8
2.0
2.4
2.7
133.9
89.2
35.7
46.5
Gal lons
32.0
0.1
1.7
0.3
2.9
0.3
0.3
0.3
3.9
2.7
1.5
2.1
Let Down:
Butyl Carbitol Solvent--Premix with:
7.2 0.9
Ucar Thickener
SCT-275
8.2
1
.o
Ucar Latex
163 423.6 47.6
Antifoam
(4) 4.8 0.6
Mildewcide
(IO)
5.8
0.6
Ammonium Hydroxide,
28%
Aqueous Solution
9.0 1.2
Suppl
i
ers
:
(1) Dispersant
-
Colloid
lllM
(Colloids) or equivalent.
(2)
Nonionic Surfactant
-
Triton CF-10 (Rohm and Haas) or
(3)
Buffer
-
AMP
95
(Angus) or equivalent.
(4)
Antifoam
-
Colloid
770
(Colloids) or equivalent.
(5)
Preservative
-
Nuosept
95
(Huls) or equivalent.
(6)
Titanium Dioxide
-
Ti-Pure
R-900
(DuPont) or equivalent.
(7)
Inhibitive Pigment
-
Nalzin
2
(NL Chemicals) or equivalent
(8)
Mica
-
325
WG
Mica
(KMG
Minerals) or equivalent.
(9)
Calcium Carbonate
-
Snowflake (Thompson, Weinman) or
equivalent.
equi Val ent
.
(IO)
Mildewcide
-
Polyphase AF-1 (Troy) or equivalent
Paint Properties:
Pigment Volume Concentration
(PVC),
%:
27.9
Total Solids,
%
by Volume:
36.5
SOURCE: Ucar Emulsion Systems: Ucar Latex
163:
Formulat
Suggestion LP-2085
on
Rimers
175
Universal Primer
Inqredients:
Pi
gment Grind:
Water
Methyl Carbitol Solvent
Ammonium Hydroxide, 28% Aqueous Solution
Tamol 165
Surfynol
CT-111
Drewpl us L-475
Aerosi 1 R-972
Ti
-Pure
R-900
Microtalc
MP
12-50
Busan 11-MI
Water
Letdown
:
Butyl Carbitol Solvent
Ucar Latex 461
Ucar Filmer
IBT
)
Premix
Santicizer 160
)
Sodium Nitrite
)
Premix
Water
1
Water
Ammoni um Hydroxide, 28% Aqueous Sol uti
on
Ucar Polyphobe 102 Rheology Modifier
Pai nt Properti
es
:
Arcosolv
PNB
1
Pigment Volume Concentration,
%:
22.4
Volume Solids,
%:
38.0
Weight Solids,
%:
49.5
Weight per Gallon, lb: 10.2
Stormer,
KU:
85
ICI,
Poise: 0.9
pH value: 8.5-9.5
Freeze-Thaw Stability, cycles passed: 5
Heat-Age Stability, 120F, weeks passed: 4
VOC,
grams per liter: 225
Pounds
51 .5
50.4
2.0
8.1
4.0
2.0
3.0
121
.o
61
.7
50.0
60.8
21.2
521.2
10.1
10.1
2.3
2.4
20.2
10.7
1.5
5.5
Gallons
6.18
5.93
0.26
0.92
0.48
0.27
0.19
3.57
2.74
2.08
7.30
2.66
59.91
1.37
1.27
0.24
0.14
2.42
1.28
0.20
0.59
Film Properties:
Sheen, 85: 5 max
Prohesion Corrosion Weathering Cycle, hours passed: 800
Cleveland Humidity, hours passed: 800
Tanning/Stai ni ng Resistance: Good
Tape Adhesion
(ASTM
0-33): Excellent
Salt Fog, hours: 48 max
SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-18138
176
Water-Based Paint Formulations
Universal Primer
Non-Li
fti
ng
and
High
Salt Spray Resistance
Insredients:
Aroplaz 3859-2-80
Calcium Chem-All
8%
Premix:
Red Iron Oxide 5-3106
Phosguard
5-0806
10
AS
Wollastocoat
399 Talc
Methyl Isobutyl Ketone
Disperse to 135F and
5
n.s.u.
MPA-1078
To1 uene
VM
&
P Naphtha
Aroplaz 3859-2-80
Cobalt Chem-A1 1 12%
Zi
rconi um Chem-All 12%
nButyl Alcohol
Skino #2
PM
Acetate
&
Gals
245.30 27.72
6.00
0.81
9.00 1.13
100.00 2.40
138.60 5.20
121
.oo
5.00
103.50 4.60
133.30 19.99
13.50 1.86
68.80 11.24
123.20 13.92
1
.25 0.15
3.75 0.47
25.80 3.82
3.00 0.39
16.53 2.16
Formulation Constants
Non Volatile by Weight: 0.69
VOC
grams/litre: 410.71
Non Volatile by Volume: 0.48
VOC
lbs./gal.: 3.43
PVC
:
0.35 Weight per Gallon: 11.03
CPVC:
0.45
Pi
gment Content: 0.42
PVC/CPVC
:
0.79
1.
Can be re-coated with powerful solvent-containing topcoats.
2.
Very high salt spray resistance
-
3000 hours at 3 mils.
3. Fast drying in thin films.
4. Must be fully cured before top coated.
5. Ready to spray without dilution.
6.
Touch dry in approximately
8
minutes.
SOURCE:
Nyco Minerals,
Inc.:
Suggested Formulation
Non-lifting epoxies, urethanes, and alkyds.
Primers
177
Water-Base
Acrylic
Universal Primer Using
Halox SZP-391
&
EJW-100
Grind: Lbs./100 Gals. Gms/Liter
Add the following in order listed while mixing at low speed:
Water
125.0 150.0
Nopco
NDW
1.5
1.8
Natrosol
250MBR
1
.o
1.2
Aqua Ammonia
28%
1
.o
1.2
Mix for
5
minutes then add the following raw material in order
listed:
Ethylene G1 ycol
Tamol
681
Triton
CF-10
Ti
-Pure
R-902
Zinc Oxide
Halox
SZP-391
Halox BW-100
Snowf 1 ake
High speed disperse to
5+
Hegman grind
Letdown
:
Rhopl ex
MV-23
Texanol
Skane
M-8
Nopco
NDW
30.0 36.0
18.5 27.8
3.0 3.6
150.0 180.0
10.0 12.0
50.0
60.0
50.0
60.0
130.0 156.0
490.0 588.0
8.0
9.6
2.0 2.4
1
.o
1.2
Add grind portion under agitation and mix until uniform. Then
slowly add the following raw material while mixing at high
speed.
Do
not aerate!
OR-708
Thickener
5.5
6.6
Mix until uniform and add the following:
Water
58.0
70.0
Mix until uniform.
Formula Constants:
%
Pigment/Wt.
:
34.55
%
Pigment/Vol.:
14.76
%
Solids/Wt.:
54.55
96
Sol
i
ds/Vol
.
:
38.71
46
PVC:
38.14
VOC.
lbs./gal.:
1.14
VOC,
g/L:
136.82
Formula Properties:
Density 1
bs.
/gal.
:
11
.35
Density g/L:
1
,367.4
KU
Visc.
@
R.T.: 90-95
pH
@
R.T.:
9.0-9.5
SOURCE:
Halox Pigments: Suggested Formulation MV-23/391-100
178
Water-Based Paint Formulations
Water-Base Acrylic Universal Primer Using
Halox SZP-391
(L
Xtain
A
Qri
nd: Lbs./100 Gals Gms/Liter
Add
the following in order listed while mixing at low speed.
Water
Nopco
NDW
Natrosol 250MBR
Aqua Ammonia 28%
125.0 150.0
1.5 1.8
1
.o
1.2
1
.o
1.2
Mix for 5 minutes then add the following raw material in order
listed:
Ethylene G1 ycol
Tamol 681
Triton CF-10
Ti -Pure R-902
Zinc Oxide
Halox
SZP-391
Halox Xtain
A
Snowf
1
ake
High speed disperse to 5+ Hegman grind
Letdown
:
Rhopl ex MV-23
Texanol
Skane M-8
Nopco
NDW
30.0 36.0
18.5 27.8
3.0
3.6
150.0 180.0
10.0 12.0
50.0
60.0
5.0 6.0
175.0 210.0
490.0 588.0
8.0 9.6
2.0 2.4
1
.o
1.2
Add grind portion under agitation and mix until uniform. Then
slowly add the following raw material while mixing at high
speed. Do not aerate!
QR-708 Thickener 5.5 6.6
Mix until uniform and add the following:
Water 58.0 70.0
Mix until uniform.
Formula Constants:
%
Pi
gment/Wt
.
:
34.56
%
Pigment/Vol
.
:
14.81
%
Solids/Wt.: 54.57
%
Soli
ds/Vol
.
:
38.76
%
PVC: 38.20
VOC,
lbs./gal.: 1.14
VOC,
g/L: 136.69
Formula Properties:
Density lbs./gal.: 11.35
Density g/L: 1,367.4
KU
Visc.
@
R.T.: 90-95
pH
@
R.T.: 9.0-9.5
SOURCE: Halox Pigments: Formulation MV-23/3BlXA
Primers
179
Waterborne
Black
Iron
Oxide
Primer
Based
on
EDotuf
37-143/37-680
(Formula
No.
3019-38A)
Component
A:
Arcosolv PTB
Dowanol PPH
Add following in order under agitation:
Epotuf 37-680
BK-5099
Wollastokup 10
ES
High speed disperse to
5
N.S.
Add following under agitation:
Epotuf 37-680
Arcosolv PTB
Tap Water
Lbs
183.82
38.54
10.79
85.85
285.60
214.59
25.73
92.72
Component
8:
Mix following under high-speed agitation unti 1 uniform:
Epotuf 37-143 77.43
Mineral Spirits 24.71
Aromatic 150 24.71
Tap Water 33.32
Weight/Gallon
(Lbs.):
10.98
Percent Solids (Wt.): 55.56
Percent Solids (Vol.): 38.67
PVC
(%I:
35.88
VOC
(Lbs./Gallon): 2.50
SOURCE:
Reichhold Chemicals, Inc.: Formula
No.
3019-38A
Gals
20.75
5.28
1.23
2.07
11
.80
24.22
3.52
11.13
8.80
3.85
3.35
4.00
180
Water-Based Paint Formulations
Waterborne Red Iron
Oxide
Primer
Based on EDotuf 37-143/37-680
Iformula
No.
2954-76A)
Component
A:
Arcosolv
PTB
Dowanol PPH
Add following in order under agitation:
R5098 Red Iron Oxide
Wollastokup
10
ES
High speed disperse to
5
N.S.
Add following under agitation:
Epotuf 37-680
Epotuf 37-680
Arcosolv
PTB
Tap Water
Lbs
172.36
34.47
10.34
87.04
290.42
209.42
24.99
112.88
Component
0:
Mix following under high-speed agitation until uniform:
Epotuf 37-143 72.91
Mineral Spirits 24.13
Aromatic
150
24.13
Tap Water 39.07
Weight/Gallon (Lbs.): 11.02
Percent
Sol
ids (Wt.
)
:
54.89
Percent Solids (Vol.): 37.68
PVC
(%I:
37.25
VOC
(Lbs./Gallon): 2.46
SOURCE:
Reichhold Chemicals, Inc.: Formula
No.
2954-76A
Gals
19.45
4.72
1.18
2.03
12.00
23.64
3.42
13.55
8.28
3.76
3.28
4.69
Primers
181
Waterborne Red Oxide Epoxy Primer
Materi a1
:
Part
A:
Epi -Rez 5522-WY-55 Resin
Di
acetone A1 coho1
Col
1
oi d 640 Defoamer
Water
R0-4097 Kroma Red, Red Iron Oxide
Sparmite Barium Sulfate
1OES Wollastokup
Halox SW-111
Zeeosphere 400
Water Ground Mica, 325 Mesh
High Speed Disperse to a Texture
of
5-6
N.S
€pi -Rez 5522-WY-55 Resin
Water
Part
8:
€pi-Cure 8290-Y-60 Curing Agent
Water
Composi te
61
end: Viscosity
Part
A
Part
B
Parts
A
and
B
70
K.U.
Typical Coating Properties:
Total Weight Solids,
%:
62.0
Total Volume Solids,
%:
46.2
P.V.C.,
%:
35.0
Induction Time, minutes: 30
Volatile Organic Compounds (VOC):
Pounds/Gallon: 1.23
Grams/Li ter: 148
Resi n Composi
ti
on
:
Epoxy Resin,
%:
87.6
Curing Agent,
%:
12.4
Total,
%:
100.0
Pounds
330.0
7.0
3.5
60.0
71.1
71
.I
106.7
100.0
71 .1
7.5
147.0
14.2
60.0
110.0
989.2
170.0
Gal lons
37.21
0.89
0.41
7.20
1.74
1.94
4.40
4.20
3.55
0.32
16.43
1
.71
6.80
13.20
80.00
20.00
Source: Shell Chemical Co.: Starting Formulation
No.
1810:
Epi-Rez
5522-WY-55
Resin/Epi-Cure
8290-Y-60
Curing Agent
182
Water-Based Paint Formulations
Waterborne Yellow Iron Oxide Primer
Based on
EDotuf
37-143/37-680
(Formula
No.
3019-396)
Component
A:
Arcosolv PTB
Dowanol PPH
Add following in order under agitation:
Epotuf 37-680
YD-2288
Wollastokup 10
ES
High speed disperse
to
5
N.S.
Add following under agitation:
Epotuf 37-680
Arcosolv PTB
Tap Water
&
183.41
38.45
10.77
69.43
284.95
214.11
25.88
93.71
Component
8:
Mix following under high-speed agitation until uniform:
Epotuf 37-143 77.25
Mineral
Spi
ri
ts 24.55
Aromatic 150 24.55
Tap Water 33.90
Weight/Gallon
(Lbs.):
10.81
Percent Sol ids (Wt.
)
:
54.80
Percent Solids (Vol.): 38.50
PVC
(%):
35.89
VOC
(
Lbs
.
/Gal 1 on)
:
2.50
SOURCE:
Reichhold Chemicals. Inc.: Formula
No.
3019-398
Gals
20.70
5.72
1.22
2.07
11.77
24.17
3.55
11.25
8.78
3.82
3.33
4.07
Primers
183
Water Reducible Alkyd Yellow Iron Oxide Primer
Using
Halox SZP-391
Grind:
Chempol
10-0091
Butyl Cel losolve
DMEA
Aqua Ammonia
(28%)
Y.I.O. YO-2087
Halox
SZP-391
Beaverwhi te
325
Snowf
1
ake
Bentone
SD-1
Disperse at high speed to
4+
NS
grind.
Letdown
:
Chempol
10-0091
DMEA
Aqua Ammonia
(28%)
Cobalt Hydro-Cure
5%
Cal ci um Hydro-Cure
5%
Zirconium Hydro-Cure
12%
Active
8
Byk
301
n-Butanol
Add slowly while mixing.
Water
Lbs./100
Gals. Gms/Liter
200.0 240.0
55.0
66.0
4.0 4.8
4.0 4.8
75.0
90.0
33.0 40.0
75.0
90.0
75.0
90.0
1
.o
1.2
50.0
4.0
4.0
2.0
3.5
2.0
1
.o
1
.o
25.0
60.0
4.8
4.8
2.4
4.2
2.4
1.2
1.2
30.0
400.0 480.0
Formula Constants:
%
Pi
gment/Wt
.
:
25.67
%
Pigment/Vol
.
:
10.24
%
Solids/Wt.:
44.75
%
Soli ds/Vol
.
:
31.35
%
PVC:
32.65
VOC,
lbs./gal.:
2.93
VOC,
g/L:
351.68
Formula Properties:
Density lbs./gal.:
10.15
Density g/L:
1,217.8
KU
Vi
sc.
@
R.T.
:
80-85
pH
@
R.T.:
9.0-9.5
SOURCE:
Halox Pigments: Suggested Formulation
WRA-301
184
Water-Based
Paint
Formulations
Water Reducible Alkyd Yellow
Iron
Oxide
Primer
Usins Halox
CW-491
Grind:
Chempol 10-0091
Butyl Cellosolve
DMEA
Aqua Ammonia (28%)
Halox CW-491
Y.I.O.
YO-2087
Beaverwhi te 325
Snowf
1
ake
Bentone SD-1
Disperse at high speed to 4+
NS
grind.
Letdown
:
Chempol 10-0091
DMEA
Aqua Ammonia (28%)
Cobalt Hydro-cure 5%
Calcium Hydro-cure 5%
Zirconium Hydro-cure 12%
Active 8
Byk 301
n-Butanol
Add slowly while mixing.
Water
Mix until uniform.
Formula Constants:
%
Pigment/Wt.: 25.67
%
Pi gment/Vol
.
:
10.24
%
Solids/Wt.: 44.75
%
Sol
ids/Vol
.
:
31 .35
%
PVC: 32.65
VOC,
lbs./gal.: 2.93
VOC,
g/L: 351.68
Lbs./lOO Gals. Gms/Liter
200.0 240.0
55.0 66.0
4.0 4.8
4.0
4.8
75.0 90.0
33.0 40.0
75.0 90.0
75.0 90.0
1.0 1.2
50.0
4.0
4.0
2.0
3.5
2.0
1
.o
1
.o
25.0
60.0
4.8
4.8
2.4
4.2
2.4
1.2
1.2
30.0
400.0
480.0
Formula Properties:
Density lbs./gal.: 10.15
Density g/L: 1,217.8
KU
Visc.
@
R.T.:
80-85
pH
C
R.T.:
9.0-9.5
SOURCE: Halox Pigments: Suggested Formulation WRA-491
Primers
I85
Water Reducible EDoxv-Ester Red Iron Oxide Primer
Grind:
W/R
Epoxy Ester Resin
Butyl Cell os01 ve
Aqua Ammonia
(28%)
Red Iron Oxide
Halox SZP-391
Talc
AMP-95
Lbs/100
Gals. Gms/Liter
340.0 408.0
25.0 30.0
3.0 3.6
3.0 3.6
100.0 120.0
42.0 50.4
791
.O
229.2
High speed disperse to
4+
NS
Grind
Letdown
:
W/R
Epoxy Ester Resin
Butyl Cel losol ve
Aqua Ammonia (28%)
Cobalt Hydrocure (13%)
Manganese Hydrocure (12%)
Activ
8
N-Butanol
Byk 301
Add
slowly while mixing and mix until uniform.
125.0
25.0
3.0
2.5
2.5
1
.o
25.0
2.0
150.0
30.0
3.6
3.0
3.0
1.2
30.0
2.4
Water 175.0 210.0
Formula Constants:
%
Pi
gment/Wt.
:
31 .24
%
Pigment/Vol.: 12.15
%
Solids/Wt.: 52.28
%
Solids/Vol.: 34.70
%
PVC:
34.70
VOC,
lbs./gal.: 4.13
voc,
g/L:
494.87
Formula Properties:
Density lbs./gal.: 10.65
Oensity g/l.: 1,278.4
KU
Visc.
@
R.T.: 80-85
pH
@
R.T.:
9.0-9.5
SOURCE:
Halox Pigments: Suggested Formulation WREE39lH
186
Water-Based Paint
Formulations
Water Reducible Eooxv-Ester Red Iron Oxide Primer
Grind:
W/R
Epoxy Ester Resin
Butyl Cellosolve
Aqua Ammonia (28%)
Red Iron Oxide
Halox CW-191
Talc
AMP-95
Lbs./100 Gals. Gms/Liter
340.0 408.0
25.0 30.0
3.0 3.6
3.0 3.6
100.0 120.0
42.0
50.0
190.0 228.0
High speed disperse to 4+
NS
grind.
Letdown
:
W/R
Epoxy Ester Resin
Butyl Cellosolve
Aqua Ammonia (28%)
Cobalt Hydrocure (12%)
Manganese Hydrocure (12%)
Active 8
N-Butanol
BYK
301
Add slowly while mixing and mix until uniform.
125.0 150.0
25.0 30.0
3.0 3.6
2.5 3.0
2.5 3.0
1
.o
1.2
25.0 30.0
2.0 2.4
Water
175.0
210.0
Formula Constants:
%
Pi
gment/Wt
.
:
31
,55
%
Pi
gment/Vol
.
:
12.35
%
Sol ids/Wt.
:
52.54
%
Solids/Vol.: 34.90
%
PVC:
35.39
VOC,
lbs./gal.: 4.12
VOC,
g/L: 493.60
Formul a Properti
8s
:
Density lbs./gal.: 10.64
Density g/L: 1,276.4
KU
Visc.
@
R.T.:
80-85
pH
@
R.T.:
9.0-9.5
SOURCE:
Halox Pigments: Suggested Formulation WREE491
Primers
187
Water Reducible Epoxy-Ester
Red
Iron
Oxide Primer
Using Halox
CW-491
Grind:
W/R
Epoxy Ester Resin
Butyl Cellosolve
Aqua Ammonia (28%)
Red Iron Oxide
Halox CW-491
Talc
AMP-95
Lbs. /lo0 Gals. Gms/Li ter
340.0 408.0
25.0 30.0
3.0 3.6
3.0 3.6
100.0 120.0
42.0
50.0
190.0 228.0
High speed disperse to 4+
NS
grind.
Letdown
:
W/R
Epoxy Ester Resin
Butyl Cellosolve
Aqua Ammonia
(28%)
Cobalt Hydrocure (12%)
Manganese Hydrocure (12%)
Active
8
N-
But ano 1
Byk 301
Add slowly while mixing and mix until uniform.
125.0
25.0
3.0
2.5
2.5
1
.o
25.0
2.0
150.0
30.0
3.6
3.0
3.0
1.2
30.0
2.4
Water 175.0 210.0
Formula Constants:
%
Pi
gment/Wt
.
:
31
.55
%
Pi
gment/Vol
.
:
12.35
%
Solids/Wt.: 52.54
%
Solids/Vol.: 34.90
%
PVC:
35.39
VOC,
lbs./gal.: 4.12
VOC,
g/L: 493.60
Formula Properties:
Density lbs./gal.: 10.64
Density g/L: 1,276.4
KU
Visc.
@
R.T.:
80-85
pH
@
R.T.:
9.0-9.5
SOURCE:
Halox Pigments: Suggested Formulation WREE491
188
Water-Based
Paint
Formulations
White. Corrosion Resistant Latex Primer
I
nnredi ent
s
:
Pigment
Gri
nd:
Water
Busperse 39/Dispersant
Bubreak 448/Defoamer
Igepal CTA 639/Surfactant
Cellosize QP-l500O/Hydroxyethyl
Water
Butrol 23/Modified Barium Meta-
Ti
-Pure R-SOO/Titanium Dioxide-
Atomite/Calcium Carbonate
Mica-325 Mesh/Water Ground
Let Down:
Rhopl ex MV-23/Acryl
i
c
Emu1
si
on
Texanol/Ester Alcohol
Ethylene Glycol
Water
Pai nt Propert
i
es
:
Total Vehicle 63.19
Pigment 36.81
Volatile 44.32
Organic Solvent 4.23
Non-Volatile 55.68
Non-Volatile Vehicle 18.87
Density (lb/U.S gal): 11.61
Specific Gravity: 1.39
P.V.C.:
40.65%
P/B
Ratio: 1.951
Spread
@
1
Mil:
617 F2
Coating
VOC:
134
G/L
Material
VOC:
59 G/L
Cell ul ose
borate
Rutile
!&
Gal
100.12 12.02
10.01 0.93
3.00 0.44
3.00 0.34
2.00 0.17
25.03 3.00
100.12 3.25
150.19 4.51
150.19 6.65
25.03 1.07
500.62 56.89
7.01 0.89
30.04 3.23
55.07 6.61
%vel
84.36
15.64
61 .52
5.63
38.48
22.84
a
8.62
0.86
0.26
0.26
0.17
2.16
8.62
12.93
12.93
2.16
43.10
0.60
2.59
4.74
SOURCE:
Buckman Laboratories: Formulation Suggestion: KP-08
Primers
189
White Inhibitive Maintenance Primer
Inaredi ents
:
Pigment Grind:
Water
Eentone LT
Methyl Carbitol Solvent
Tamol 681
Nuosept 95
DeeFo HG-12
Triton Nonionic Surfactant CF-10
Ammonium Hydroxide, 28% Aqueous Solution
Acrysol RM-2020
Tronox CR-828
Heucophos
ZBZ
Atomi te
Letdown
:
Methyl Carbitol Solvent
Acrysol SCT-275
Ucar Vehicle 435
Ucar Filmer IET
Troysan Polyphase AF-1
Foamex 825
Sodium Nitrite, 15% Aqueous Solution
Ammonium Hydroxide, 28% Aqueous Solution
Pounds
151.5
1
.o
25.5
18.2
2.3
2.1
2.2
1.8
17.2
100.0
50.0
125.7
8.5
8.6
505.1
11.4
4.9
2.1
9.0
1.8
loris
8.19
0.06
3.00
2.00
0.25
0.25
0.25
0.25
2.00
2.93
1.67
5.57
1
.oo
1
.oo
58.06
1.44
0.50
0.25
1.08
0.25
Adjust to minimum
pH
8.7
Pai
nt
Properti es
:
Pigment Volume Concentration (PVC)
,
%:
30.0
Total Solids,
%:
by volume: 34.0
pH Value, initial: 8.7
Viscosity:
Stormer,
KU:
80
ICI,
poise: 0.8
Weight per Gallon, lb: 10.5
Freeze-Thaw Stability, 3 cycles: Pass
Heat Stability, 2 weeks at 140F: Pass
SOURCE:
Ucar
Emulsion Systems: Ucar Vehicle
435:
Formulation
Suggestion M-2451
Sealants and Related
Compounds
191
Ancamide
2353
Curina
Aaent Aluminum Mastic
Prel
i
mi
nary Formulation
Part
A:
Liquid DGEBA Epoxy
MPA-1078
(Rheox)
10
Wollastekup AS (Nyco)
Disperse to
6
Hegman and
130F:
Epodil
L
(Air
Products)
High Flash Naphtha
Beetle
216-8
(Cyanamid)
Lansford
L243
(Si
1 berl ine)
Diacetone Alcohol (Union Carbide)
Cabosil TS
720
(Cabot)
Part
8:
Ancamide
2553
(Air
Products)
-
Lb
Gal
307 31.7
8
1.0
250 10.3
35 4.0
120 16.5
25 2.8
125 10.2
24 3.0
10 0.4
169
20
Properties:
Volume Solids:
71 .9%
VOC:
t2.5
lb gal
PVC:
20.0%
Mixing Ratio
4:l
by Volume
CPVC:
47.1%
Pot Life, hr
5
PVC/CPVC:
0.426
Dry to Touch, hr:
3
Weight/gallon, Part
A:
11.29
Dry Through, hr:
7
Weight/gallon, Part
B:
8.45
Wei ght/gal lon:
10.73
SOURCE: Air
Products and Chemicals, Inc.: Ancamide
2353
Curing
Agent: Table
10
Formula
192
Water-Based Paint Formulations
Clear Sealant
Inaredi ents
:
Ucar Latex 100
Tergitol Nonionic Surfactant NP-4
Nopco
NXZ
Proxel GXL
Ucar Filmer
IBT
Cosan 158
Propylene Glycol
Ucar Thickener 146
Ammonium Hydroxide, 28% Aqueous Solution
Acrysol SCT-275
Weight%
95.15
0.16
0.36
0.24
0.85
0.42
0.85
0.48
0.64
0.85
Mi
xi ng Procedure:
A
high-shear, low-speed vacuum mixer of the double-bladed
planetary type or the double-bladed sigma type is recommended.
Charge the latex to the mixer. Add the remaining ingredients
slowly in the order listed to the mixer with agitation. The
mix
will
thicken when the NH40H is added.
Stir
for five minutes
and then add associative thickener. Mixing time should be >30
mi
nutes.
Sealant Properties:
Nonvolati les,
%
by weight: 61.9
pH Value: 8.8
Viscosity, Brookfield,
P:
24,000
Semco Gunnability, g/sec: 28
ASTM
C731: Pass
Tooling Time, min:
>5
Boeing Slump, in:
0.0
Elongation at Break,
%:
1000
Tensile Strength, max, psi
:
230
Time for 180-mil Bead to
Dry
Clear, days:
7
Shore
"A"
Hardness,
7
days at
50%
R.H.:
48
SOURCE:
Ucar Emulsion Systems: Ucar Latex 100: Formulation
Suggestion CC-1010
Sealants and Related Compounds
193
High-Qual
i
ty
Exterior Latex Caulk
Ingredients:
Colloid 677
Propyl ene G1 yco
Tergitol Nonion
Composi
ti
on
T
Potassium Tripo
Tamol 983
Ti
-Pure R-900
Ucar Latex 100
Santicizer 160
Organofuntional
Camel Carb
Snowf
1
ake
Camel Cal
Mineral Spi
ri
ts
Nuosept 95
Skane M8
Acrysol
SCT-275
c Surfactant NP-40
yphosphate
(KTPP)
Silane A-187
Ammoni um Hydroxi de, 14% Aqueous
Sol uti on
Caulk Properties:
Total Solids,
%:
bv weiaht: 84.7
Pounds
1.8
13.6
5.5
3.0
0.5
0.9
12.7
418.0
0.5
109.0
0.6
521.6
172.7
58.2
22.7
1.8
2.3
5.5
Gallons
0.3
1.6
0.6
0.1
0.0
0.1
0.4
46.9
0.1
11.8
0.1
23.0
7.7
2.6
3.5
0.2
0.3
0.7
Wt%
0.13
1.01
0.40
0.22
0.04
0.07
0.94
30.94
0.03
8.07
0.05
38.63
12.78
4.31
1.68
0.13
0.17
0.40
-
by volume: 74.4
Weight per Gallon, theoretical, lb: 13.5
Viscosity, Brookfield,
P:
Ini
ti
a1
:
2800
After
5
freeze-thaw cycles: 2150
Pigment Volume Concentration,
%:
45
Boeing Slump: None
OF
Bend: Pass
Shore
"A"
Hardness, 72F at
50%
R.H.
:
1-day: 10
3-day: 33
7-day:
50
initial: 9.5
after
5
freeze-thaw cycles: 9.0
Stress-Strain Properties:
32F
-
OF
tensile strength, max, psi 54 67 330
elongation at break,
%
230 155 87
Semco Gunnability, g/sec:
Adhesion Properti es
:
180 Peel Adhesion*,
pli
Substrate
Drv
24-hr. Water Soak
G1 ass 20.7 (COH) 15.1
(COH)
A1 umi num 21.9 (COH) 13.2
(COH)
Concrete 20.5 (COH) 12.7 (AO/COH)
Hypal on Sheet 13.8 (COH) 12.9 (COH)
*
COH=cohesi ve fai 1 ure
A0
=adhesive fai 1 ure
SOURCE:
Ucar Emulsion Systems: Ucar Latex 100: Formulation
Suggestion CP-1001
194 Water-Based Paint Formulatiom
Patchina Colwund (Brushina Grader
Inqredients:
Pi gment
Gri
nd
:
Ucar Latex 163
Wetting Agent (1) Slurry of:
Water
Ammonium Hydroxide, 28% Aqueous Solution
Antifoam (2)
Dispersant (3)
Preservative (4)
Calcium Carbonate
(5)
Mica (6)
Titanium Dioxide (7)
Mi
1 dewci de (9)
Let Down:
Coarse Silica (10)
Mineral Spi
ri
ts
Ammonium Hydroxide, 28% Aqueous Solution
Ethylene Glycol
Suppl
i
ers:
*Post Added
Pounds
667.5
1.7
8.3
1.5
3.9
3.1
0.8
90.0
25.8
65.6
4.5
286.7*
3.4
3.4
17.6
Gallons
75.0
0.2
1
.o
0.2
0.5
0.3
0.1
4.0
1.1
2.1
0.3
12.2
0.6
0.5
1.9
Wetting Agent
-
Surfynol 104 (Air Products) or equivalent.
Antifoam
-
Colloid 770 (Colloids) or equivalent.
Dispersant
-
Colloid 226/35 (Colloids) or equivalent.
Preservative
-
Cosan 101 (Cosan) or equivalent.
Calcium Carbonate
-
Duramite (Thompson, Weinman)
or
equivalent.
Mica
-
325
WG
Mica
(KMG
Minerals) or equivalent.
Titanium Dioxide
-
Ti-Pure R-901 (DuPont) or equivalent.
Silica
-
Celite 281 (Johns-Manville) or equivalent.
Mildewcide
-
Nopcocide N-96 (Diamond Shamrock) or
equivalent.
Coarse Silica
-
Ruff Buff (Tammsco) or equivalent.
Patching Compound Properti 8s:
Pigment Volume Concentration (PVC)
,
%:
31 .7
Total Solids,
%:
by Volume: 60.4
by Weight: 71.6
SOURCE:
Ucar Emulsion Systems: Ucar Latex
163:
Formulation
Suggestion V-2084
Sealants
and
Related
Compounds
195
Patchins Compound
(Trowel
Gradel
Inaredients:
Pigment Grind:
Ucar Latex
163
Wetting Agent
(1)
Slurry of:
Water
Ammonium Hydroxide,
28%
Aqueous Solution
Tergitol Nonionic Surfactant NP-40
Antifoam
(2)
Dispersant
(3)
Preservative (4)
Calcium Carbonate
(5)
Mica
(6)
Titanium Diox
Silica
(8)
Mildewcide
(9
Let Down:
Coarse
Si
1 ica
Pounds
685.3
8.6
1.7
1
.l
1.7
3.5
0.8
219.3
-----
Gallons
77.0
1
.o
0.2
0.1
0.2
0.3
0.1
9.7
----
25.8
1.1
64.4
2.1
64.6 3.4
5.1 0.3
34.5 1.6
3.4 0.5
Mineral
Spiri ~
Ammonitim
Hvdrnxida.
3R%
Aatienus
Snlutinn
3.4 0.5
.
.......
-
.
.
.
-
...
.
.
,
-.
-. . .
-
-
,
- -
.
-
. .
-
- -
-
-
- -
-
.
-
-
. -.
.
-.
.
Ethylene Glycol
17.2
1.9
Suppliers:
(1)
Wetting Agent
-
Surfynol 104
(Air
Products) or equivalent
(2)
Antifoam
-
Colloid
770
(Colloids) or equivalent.
(3)
Dispersant
-
Colloid
226/35
(Colloids) or equivalent.
(4) Preservative
-
Cosan
101
(Cosan) or equivalent.
(5)
Calcium Carbonate
-
Duramite (Thompson, Weinman) or
(6)
Mica
-
325
WG
Mica
(KMG
Minerals) or equivalent.
(7)
Titanium Dioxide
-
Ti-Pure
R-901
(DuPont) or equivalent.
(8)
Silica
-
Celite
281
(Johns-Manville) or equivalent.
(9)
Mildewcide
-
Nopcocide
N-96
(Diamond Shamrock) or
(10)
Coarse Silica
-
Ruff Buff (Tammsco) or equivalent.
equivalent.
equivalent.
Patching Compound Properties:
Pigment Volume Concentration
(PVC),
%:
29.7
Total Solids,
%:
by Volume:
59.9
by Weight:
70.7
SOURCE:
Ucar Emulsion
Systems:
Ucar
Latex
163:
Formulation
Suggestion
V-2083
1%
Water-Based
Paint Formulations
Pi Qlented Caulk Formulation
based on
2:l
Vinyl
Acrvlic/Acrvlic Blend
Inaredi ents:
Ucar Latex
161
Ucar Latex
163
Triton Nonionic Surfactant
X-405
Nopco
NXZ
Propylene G1 ycol
Ammonium Hydroxide,
14%
Aqueous Solution
Cosan
234
Acrysol SCT-200
Santicizer
160
Silane
A-187
Mineral Spi
ri
ts
Pounds
269.5
127.7
5.0
1.6
12.5
0.4
6.0
0.5
99.8
0.6
20.8
Blend
10
minutes, then add the following:
Tamol
850 1.2
Composi
ti
on
T
3.3
Ti
-Pure
CR-800
14.0
Wi
ngdal e White
576.2
Potassium Tripolyphosphate (KTPP)
0.5
Microwhite
25 254.0
Ammonium Hydroxide,
28%
Aqueous Solution
0.8
Gallons
30.12
14.40
0.60
0.20
1.50
0.05
0.70
0.06
10.70
0.07
3.20
0.15
0.40
0.81
25.50
0.02
11.40
0.12
Disperse at high speed until uniform in consistency (typically
Typical Properties:
Total Solids,
%:
10-30
minutes)
.
by weight:
83.9
by volume:
73.6
Pigment
:
Bi
nder Ratio:
3.2:
1
Plasticizer on Latex Solids,
96:
44.9
SOURCE: Ucar Emulsion Systems: Ucar Latex
161:
Formulation
JDD-995
Sealants and Related
CompoundF
197
Premi um-Performance. Medium-F1 exi
bi
1
i
ty
Caul
k
Inaredients:
Ucar Latex 163
Surfactant (1)
Surfactant (2)
Plasticizer (3)
Tooling Agent (4)
Ethylene Glycol
Water
Cal ci um Carbonate (5)
Ti
tani
um
Dioxide (6)
Ammonium Hydroxide, 28%
Sol uti on
Pounds
485.0
6.5
8.5
93.5
19.0
12.5
32.5
583.0
10.0
0.5
Aqueous
Gallons
54.5
0.7
0.4
10.1
2.9
1.4
3.9
25.8
0.3
---
K%
38.8
0.5
0.7
7.5
1.5
1
.o
2.6
46.6
0.8
---
Suppl
i
ers
:
(1) Surfactant
-
Triton X-405 (Rohm and Haas) or equivalent.
(2) Surfactant
-
Composition
R
(Merck) or equivalent.
(3)
Plasticizer
-
Santicizer 160 (Monsanto) or equivalent.
(4) Tooling Agent
-
Varsol No.
1
(Exxon) or equivalent.
(5)
Calcium Carbonate
-
Atomite (Thompson, Weinman) or
(6) Titanium Dioxide
-
Ti-Pure R-901 (DuPont) or equivalent.
equivalent.
Seal ant Propert
i
es
:
Total Solids,
%
by
wt:
79.0
Weight per Gallon (theoretical), lb: 12.5
Filler/Latex Solids Ratio: 2.1/1.0
Plasticizer (on total binder solids),
%
by
wt:
26.0
Shore
"A"
Hardness (4 wks at 73F,
50%
RH):
27
Tensile Strength (2
wks
at 73F,
50%
RH),
psi:
13
Elongation (2 wks at 73F, 50%
RH),
%:
460
180 Peel Adhesion (per in):
Pinewood:
9
(adhesive)
Aluminum: 11 (cohesive)
Glass: 12 (cohesive)
Extrusion: Good gunnability
ASTM
Shrinkage (28 days at 73F,
50%
RH)
Slump at Room Temperature: None
Recovery (25% Extension
RT
for
1/2
hr),
SOURCE: Ucar Emulsion Systems: Ucar Latex
Suggestion
K-2080
%:
<25
%:
>80
63:
Formulation
198
Water-Based
Paint
Formulations
Sealant A~plication
Inqredients:
Ucar Latex 163
Surfactant (1)
Plasticizer (2
Tool
i
ng Agent
Water
Ethvlene Glvco
3)
Calcium carbonate
(4)
Extender
(5)
Surfactant (6)
Titanium Dioxide
(7)
Weiqht%
33.00
0.70
9.00
2.00
1.50
1
.oo
48.00
3.00
1
.oo
0.80
Suppl
i
ers
:
(1)
Surfactant
-
Triton
X-405
(Rohm and Haas) or equivalent.
(2)
Plasticizer
-
Benzoflex 9-88 (Velsicol)
or
equivalent.
(3)
Tooling Agent
-
Varsol
No.
1
(Exxon) or equivalent.
(4)
Calcium Carbonate
-
Atomite (Thompson, Weinman) or
(5)
Extender
-
Barytes
No.
1 (Williams) or equivalent.
(6) Surfactant
-
Composition
T
(Merck) or equivalent.
(7)
Titanium Dioxide
-
Ti-Pure R-901 (OuPont) or equivalent.
equivalent.
Sealant Properties:
Nonvolatiles,
%:
83.3
Filler/Latex Solids Ratio: 2.6/1.0
Plasticizer to Latex Solids,
%:
31.2
Weight per Gallon, lb: 12.5
24-hr Extrusion Rate, g/sec: 3
Shore
"A"
Hardness,
1
month: 22
Tensile Strength, psi: 8
Elongation,
%:
158
Accelerated Weathering,
XW,
Wooden Channel, 1000 hr:
Very good
SOURCE: Ucar Emulsion Systems: Ucar Latex
163:
Formulation
Suggestion
K-2079
Sealants
and
Related
Compouna!s
199
Translucent Caulk Formulation
Inaredients: Lb/100 Gal Gallons
Ucar Latex 105 758.16 89.09
Antifoam (1) 0.59
0.08
Ucar Filmer IBT 6.18 0.87
Ammonium Hydroxide, 28% Aqueous Solution 5.88 0.78
Ethylene Glycol 9.81 1.06
Nonionic Surfactant (2) 1.96 0.26
Dispersant (3) 1.96 0.22
Silica (4) 24.52 1.34
Plasticizer (5) 53.94 5.83
Union Carbide Organofunctional Silane A-187 3.92 0.44
Preservative (6) 2.94 0.39
Tergitol Nonionic Surfactant NP-10 2.94 0.35
Suppl
i
ers
:
(1) Antifoam-Nopco
NXZ
(Henkel) or equivalent.
(2) Nonionic Surfactant
-
Surfynol 104E (Air Products) or
(3) Dispersant
-
Disperse-Ayd W-22 (Daniel) or equivalent.
(4) Silica
-
Cab-0-Si1 L-90 (Cabot) or equivalent.
(5)
Plasticizer
-
Santicizer 160 (Monsanto) or equivalent.
(6) Preservative
-
Nuosept 95 (Huls) or equivalent.
equi Val ent
.
Typical Properti
8s:
pH Value: 7.2
Total Solids,
%:
by Weight: 60.2
by Volume: 55.1
Brookfield Viscosity,
P:
31,000
Typical Performance Properties:
Boei ng S1 ump: Passed
Semco Gunnability, g/sec: 32
After 5 Freeze-Thaw Cycles: 11
After 14-day Heat Aging: 34
7-day dry: 30
14-day dry:
30
Shore
A:
ASTM C679 Tack: Passed
ASTM C794 180 Peel Adhesion, pli
:
Dry Glass: 33.8
Dry Aluminum: 31.3
Wet Glass (7-day immersion): 15.0
Wet Aluminum: 14.0
ASTM
C793: Passed
SOURCE: Ucar Emulsion Systems: Ucar Latex
Suggestion CT-2002
05:
Formu ation
200
Water
-Based
Paint Formulations
Translucent Caulk Formulation
Ingredients:
Ucar Latex
169
Nopco
NXZ
Ammonium Hydroxide,
28%
Aqueous
Ethylene G1 ycol
Surfynol
104E
Daniels
WO-22
Cab-0-Si 1
L-90
Santicizer
160
Organof uncti onal
Si
1 ane
A-1
87
Nuosept
95
Tergitol Nonionic Surfactant
NP-
Pounds
758.5
0.6
Sol uti on
6.3
14.4
2.1
2.1
26.4
58.2
4.2
3.2
,lo
3.2
Typical Properti
8s
:
Total Solids,
%
by weight:
63.5
pH:
7.2
Viscosity, Poise:
31,000
Tensile, psi, maximum:
64
Elongation at break,
%:
990
Water Absorption,
%,
7
days:
31.6
Formulation
CT-2012
ASTM
C-920
Pigmented Caulk Formulation
Ingredients:
Santicizer
160
Potassi um Tripolyphosphate (KTPP)
Triton Nonionic Surfactant
X-405
Oaxad
30-30
Pounds
106.1
1.8
13.5
Proxel GXL
Cosan
101
Ucar Latex
169
Snowf
1
ake
Ti
-Pure
R-902
Mineral Spirits
Organofunctional
S
Ammoni um Hydroxide
Methocel
856
Propylene G1 ycol
Acrysol
ASE-60
1.8
1
.o
1.5
481.1
532.7
12.9
25.1
lane
A-187 1.2
28%
Aqueous Solution
1.3
2.1
14.6
9.3
Gal 1 ons
87.90
0.09
0.84
1.56
0.28
0.24
1.44
6.28
0.47
0.42
0.38
Gallons
11.46
0.08
1.53
0.19
0.13
0.19
55.48
23.65
0.39
3.97
0.14
0.17
0.18
1.68
1.06
Typical Properti
8s
Total Solids,
%:
Tensile, psi, maximum:
90
Pigment:Binder:
1.8:l
Shore
A
Hardness:
30
SOURCE:
Ucar Emulsion Systems: Ucar Latex
169:
Suggested
by weight:
79.5
Elongation at Break,
%:
270
by volume:
70.7
Water Absorption,
%,
7
days:
11.3
Formu
1
at
i
ono
Sealants and Related
Compounds
201
Trans1 ucent Seal ant
Inqredi ents:
Ucar Latex 100
Nopco
NXZ
Ucar Filmer IBT
Ammoni um Hydroxi de, 14% Aqueous
Propyl ene G1 ycol
Surfynol 104
Di
sperse-ayd W-22
Cab-0-Si1 LM-130
Organofunctional Silane A-187
So
1
uti on
Pounds
815.50
0.68
7.13
13.53
11.32
2.22
2.29
28.04
3.36
42
28
Nuisept 95 3.
Tergitol Nonionic Surfactant
NP-10
3
Caulk Properties:
Total Solids,
%
by weight: 61.2
pH Value: 9.4
Weight per Gallon, theoretical, lb:
Viscosity, Brookfield,
P:
27,800
Boeing Slump: None
Semco Gunnability, g/sec:
initial: 24
after
5
freeze-thaw cycles: 24
glass:
>50
a1 umi num: >50
Hunter
Lab
Color:
L:
+93.24
a:
-0.59
180 Peel Adhesion, Dry, pli:
b: -0.78
3.5
Gallons
92.67
0.09
1
.oo
1.71
1.31
0.30
0.26
1.53
0.39
0.36
0.39
Wei qht%
91.47
0.08
0.80
1.52
1.27
0.25
0.25
3.16
0.40
0.40
0.40
YIE:
-0.93
ASTM
C732 Weathering-500 Hours: no cracking
no discoloration
no adhesion
loss
SOURCE:
Ucar Emulsion Systems: Ucar Latex 100: Formulation
Suggestion
CT-2008
202
Water-Bared Paint Formulatwns
Vi
nyl
Acrvl
i
c
Seal
ant
I
n
g
r
ed
i
en
t
s
:.
Ucar Latex
161
Kathon
LX
(1.5%)
(1)
Tamol
850
Ethylene Glycol
Santicizer
160
Mineral Spirits
Natrosol
250
MXR
Potassi um Tripolyphosphate (KTPP)
Camel Fil
Ti
-Pure
R-902
Triton Nonionic Surfactant
X-405
Ammonium Hydroxide,
28%
Aqueous Solution
Typical Properties:
Total Solids,
%:
by weight:
82.2
by volume:
78.2
Pigment Volume Concentration (PVC):
46.9
Pigment:Binder Ratio:
3:l
Plasticizer on Latex Solids,
%:
40.0
Elongation at Break,
%:
722.0
Boeing Slump: Pass
ASTM
C-731:
Pass
ASTM
C-732
Weathering: No bond loss
ASTM
C-734
OF
Bend: Pass
ASTM
C-736
Extension-Recovery: Pass
Water Absorption,
7
days,
%:
41.9
Pounds
450.0
1.3
1.3
12.4
99.0
20.0
3.0
1
.o
729.4
15.0
9.1
0.5
Gal 1 ons
50.34
0.15
0.14
1.34
10.69
3.07
0.05
32.42
0.45
1
.oo
0.07
0.28
SOURCE:
Ucar Emulsion Systems: Ucar Latex
161
:
Formulation
CM-294
Sealants and Related
Compowrds
203
Weather-Barrier Mastic
Inaredi ents:
Pi
gment
Gr
i
nd
:
Water
Cellosize Hydroxyethyl Cellulose
Di
spersant (1
)
Potassium Tripolyphosphate
Ethyl ene G1 ycol
Antifoam (2)
Titanium Dioxide (3)
Calcium Carbonate (4)
Zinc Oxide
(5)
Mi
ldewcide (6)
Let Down:
Ucar Latex 163
Ucar Filmer
IBT
Antifoam (2)
Pounds
150.0
QP-4400H 4.0
4.0
1
.o
20.0
1.5
62.0
407.0
40.0
5.0
Gallons
18.0
0.3
0.4
2.2
0.2
1.9
18.1
0.9
0.5
---
502.0 56.4
6.0
0.8
2.0
0.3
Suppl
i
ers
:
(1)
Dispersant
-
Colloid 226/35 (Colloids) or equivalent.
(2) Antifoam
-
Nopco
NXZ
(Diamond Shamrock) or equivalent.
(3) Titanium Dioxide
-
"Ti-Pure" R-960 (DuPont) or equivalent
(4) Calcium Carbonate
-
"Atomite" (Thompson, Weinman) or
(5)
Zinc Oxide
-
AZO-55
(ASARCO)
or equivalent.
(6) Mildewcide
-
Nopcocide N-96 (Diamond Shamrock) or equiv-
equi Val ent
.
a1 ent
.
Mastic Properties:
Pigment Volume Concentration (PVC),
%:
40.0
Total Solids,
%:
by Volume: 53.0
by Weight: 67.3
Film
Properties*:
Tensi 1 e Propert
i
es
:
Strain Rate,
%:
20
100 200
Stress, psi: 120 120 200
Elongation,
%:
420 300 260
200
Strain Rate, in/min:
--- ---
70
Stress, psi:
---
---
800
Elongation,
%:
---
---
Tensile Properties after 7 days water immersion:
Water Ponding: Water Transmission at 24 hr: 210 mg water
Low-Temperature Flexibility: 180 Bend at -4F:
No
cracking
Water Vapor Transmission Rate for 336 hr, perms: 5.7
Adhesion to Urethane Foam, 180 Peel, lb/in:
Dry: 7.8 (Foam Cohesion Failure)
Wet-7 days immersion in water: 2.2 (Foam Cohesion Failure)
*Dried and conditioned 7 days at 72F and
50%
RH
SOURCE:
Ucar Emulsion Systems: Ucar Latex
183:
Formulation
Suggestion WB-2081
204
Water-Based
Paint
Formulations
Weather-Barrier Mastic
The following formulation has undergone extensive exterior
exposure and provides improved resistance to dirt and darly
chal ki ng
:
Inqredients:
Pi
ament
Or
i
nd
:
Wa:er
Dispersant
(
1
)
Potassi um Tripolyphosphate
Wetting Agent (2)
Ethylene Glycol
Antifoam (3)
Titanium Dioxide (4)
Calcium Carbonate
(5)
Zinc Oxide (6)
Mi
1 dewci de (7)
Water
Cel losi ze Hydroxyethyl Cellulose
QP-15000
Let Down:
Ucar Latex 163
Ucar Filmer I81
Antifoam (3)
Water
Pounds
95.8
8.9
1
.o
1.2
19.3
1.5
112.5
420.3
44.3
2.5
33.3
3.9
496.9
5.8
1.9
2.5
Gal 1 ons
11.5
0.9
0.2
2.1
0.2
3.5
18.7
I
.o
0.3
4.0
0.3
---
55.8
0.8
0.3
0.3
Suppl
i
ers
:
(1) Dispersant
-
Colloid 226/35 (Collods)
or
equivalent.
(2) Wetting Agent
-
Surfynol 104
(Air
Products) or equivalent.
(3) Antifoam
-
Colloid 643 (Colloids) or equivalent.
(4)
Titanium Dioxide
-
Ti-Pure R-960 (DuPont)
or
equivalent.
(5)
Calcium Carbonate
-
Atomite (Thompson, Weinman) or equiv-
(6) Zinc Oxide
-
XX-503
(NJ
Zinc) or equivalent.
(7) Mildewcide
-
Skane
M-8
(Rohm and Haas) or equivalent.
alent.
Mastic Propert
i
8s
:
Pigment Volume Concentration (PVC)
%:
43.0
Total Solids,
%
by Volume:
55.0
SOURCE:
Ucar Emulsion Systems: Ucar Latex 183: Formulation
Suggestion
WB-2002
206
Water-Based Paint Formulations
Brown Wiping Stain
Materi
a1
:
Kelsol 3931-WG4-45
2-Butoxy Ethanol
Patcote 531
Red Iron Oxide R-4098
Yellow Iron Oxide 1075A
Brown Iron Oxide 444
Syloid 234
Lbs.
261.00
18.00
7.50
7.30
4.50
14.90
25.00
Grind to
a
5+
Hegman grind
Kel
sol
3931 -WG4-45 402.00
Premix the following, then add under agitation.
2-Butoxy Ethanol
Acti v-8
Cobalt Hydrocure
I1
Manganese Hydrocure
I1
Pregel the following, then
add
under agitation:
4.00
2.40
3.80
6.00
Ammoni
um
Hydroxi de
Carbopol 941
Water
Pol
OX
WSR-301 2.20
1.10
1.10
100.00
Analysis:
Figment Volume Concentration, Percent: 2.17
Pigment/Binder Concentration, Percent: 0.164
Percent
Sol
ids, Weight
:
42.55
Percent Solids, Volume: 39.29
Pounds/Gallon: 8.59
VOC (excl
udi
ng
water)
:
Grams/Liter: 229
Pounds/Gallon: 1.91
pH: 8.2-8.6
Gals.
31.45
2.39
1.09
0.17
0.13
0.38
1.50
48.43
0.53
0.30
0.50
0.71
0.29
0.11
0.11
12.00
SOURCE:
Reichhold
Chemicals,
Inc.:
Kelsol
3931:
Formula
2581-81-A
Stains
207
Interior Wiping Stain
IEnulsion
E-2977)
Blend:
Water
Aurasperse W-1021
YIO
Aurasperse W-3041
RIO
Aurasperse W-7012 LB
Emu1 si on E-2977
Surfynol DF-37*
Propylene Glycol
Ammoni um Hydroxi de (28%)
Acrysol ASE-60\1:1
Water/premi x
Water
Surfynol 104DPM
*Surfynol DF-58, 70 and 75
Formulation
E
(Rohm
&
Haas)
Pounds
150.0
22.5
7.6
3.3
372.0
1.3
39.0
6.3
64.0
64.0
133.8
4.4
defoamers are viable alternatives.
Stain
81 end
:
Joncryl 95
Ektasolve
DB
Surfynol DF-37
Super Seatone Burnt Umber
Nuosept 95
Mix at 1000 rpm for 10-15 minutes.
Premix the following and add with agitation:
Letdown
:
Water
Propylene Glycol
Natrosol 250
HBR
Ammon
i
a
Surfynol 104DPM
Formulation F (S.C.Johnson)
Pounds
293.19
9.00
1.32
100.00
1.50
441 .32
30.24
3.00
1
.oo
8.80
Surfynol additives have been shown to provide the following
benef
i
ts
:
*Color uniformity of stains
*Early stain lapping resistance
*Consistent wetting, flow and leveling on various woods
*Foam control
*Topcoat recoatability and intercoat adhesion
*G1
oss
retenti on upon aging
*Tannin bleed resistance
*Water sensitivity
*Chemical resistance
With no detrimantal effect upon:
SOURCE:
Air
Products
&
Chemicals, Inc.: Surfynol Surfactants:
Suggested Formulations
208
Water-Based Paint Formulations
Materi
a1
:
Spensol L54
Water
Di
sperse-Ayd W22
Foamki 11 639AA
Mapico 297
BK
5000
Liaht Redwood Wipina Stain
Pebble
mill
grind 16-24 hrs.
Then add in following order with agitation:
Letdown
:
3% Bentone LT Pregel*
Spensol L54
Arolon 820-W-49
Lodyne S107
QR708B
Ammoni um Hydroxi de
*3% Bentone LT Pregel:
Water (deionized preferred)
Bentone
LT
High speed di sperser 15-20
mi
nutes.
Analysis:
Ratio of Spensol L54 to Arolon 820: 50:50
Pigment Volume Concentration, Percent: 2.6
Pigment/Binder Ratio: 0.15/1
.0
Percent Solids, Weight: 26.5
Percent Solids, Volume: 24.3
Percent Vehicle Sol ids. Weight
:
20.8
Percent Vehicle Solids, Volume: 19.6
Pounds/Gallon: 8.44
VOC
(excluding water):
Grams/Li
ter
:
72
Pounds/Gallon: 0.60
pH: 8.Ot-0.5
Lbs.
Gals.
51.9
5.94
51.8 6.22
0.5
0.06
0.8
0.10
24.5 0.60
1.7 0.04
288.0 34.12
254.2 29.12
187.4 21.29
1.7 0.18
17.5 2.10
1.7
0.23
818.9 98.31
25.4 1.69
SOURCE:
Reichhold Chemicals, Inc.
:
Spensol
L:
Formulation
2099-81
D
Stains
209
Stain Concentrate
Component
A:
Materi a1
:
Kel sol 3931 -WG4-45
2-Butoxy Ethanol
Water
Ammoni um Hydroxi de
Patcote 531
Mapico 567
Mapico 1075
Atomi te
Syloid 234
Pebble or sand
mill
to 6+ Hegman grind.
Letdown
:
Kel sol 3931-WG4-45
Cobalt Hydrocure
I1
Manganese Hydrocure
I1
Activ-8
2-Butoxy Ethanol
Premix the next three materials before adding:
Polyphase AF-1
2-Butoxy Ethanol
Aerosol OT-75
Mi
cheml ube 51 1
Water
Lbs.
207.5
7.5
34.7
1.9
1
.8
50.0
25.0
50.0
10.0
166.0
1.9
2.1
0.2
3.8
9.8
3.8
2.3
32.0
37.5
Gal
s.
25.00
1
.oo
4.17
0.25
0.25
1.16
0.74
2.22
0.60
20.00
0.25
0.25
0.03
0.50
1
.oo
0.50
0.25
4.00
4.50
Add the following amount of water just prior to use and mix well.
Component
0:
Water
Analysis:
Pigment Volume Concentration, Percent
Pigment/Binder Ratio
Percent
Sol
ids, Weight
Percent Solids, Volume
Viscosity
@
25C. #4 Ford, Secs.
Pounds/Gal 1 on
VOC
(excl udi ng water)
:
Grams/Li ter
Pounds/Gal 1 on
:
277.6 33.33
Comp.
A
18
2.8/1
.O
49.0
39.3
110
9.72
169
1.4
Comp.
A+B
18
0.0/1
.O
34.45
26.2
19
9.26
169
1.4
NOTE: This type of formulation might be beneficial
to
paint
manufacturers who sell directly to building or painting
contractors. These stain concentrates can be mixed with
water at the job site.
SOURCE:
Reichhold Chemicals,
Inc.:
Kelsol 3931: Formula 2210-44
210
Water-Based Paint Formulations
Tannin Stain Blockina Formulation
Pigment Grind:
Water
Bubond 357
Busperse 39
Bubreak 4400
Igepal CTA 639
Water
Cel losi ze QP-15000
TiPure R-900
Nytal 300
Let Down:
Ucar 376
Texanol
Ethylene Glycol
Cell osi ze QP-15000
Water
Tint to desired color
%
by
Weisht
9.2
1.0
0.6
0.3
0.3
2.3
0.2
18.3
9.9
39.2
2.0
2.7
0.2
13.8
Acrylic
Tannin Stain-Blockinq Primer
Materi a1
:
Water
Busperse 39
Triton X-100
Bubreak 448
Premix following, then add to above:
Water
Cell osi ze QP-15000
Sift
in following pigments:
Ti
-Pure R-900
Nytal 300
Busan 11-M1
High speed disperse
to
Hegman
5.0.
Reduce speed
as shown below:
Rhopl ex MV-23 Acryl
i
c Emu1 sion
Water
Texanol
Ethylene G1 ycol
%
bv
Weisaht
8.6
0.6
0.3
0.2
2.2
0.2
17.4
6.6
2.5
and let down
48.1
8.8
2.0
2.5
SOURCE:
Buckman Laboratories, Inc.
:
Suggested Paint Formulations
Stains
211
Water Reducible Redwood Solid Color Stain
Incorporation of Agitan 701 into a water reducible wood stain
grind yields improved grind viscosity as well as foam control in
the letdown. Addition of this silicone type FCA has no effect
on recoatability of the topcoat.
Grind:
McWhorter 73-7358
Red Iron Oxide
Aerosil R972 (Degussa)
FCA (Foam Control Agent)
&
%Wt
70 8.13
50
5.80
2.5 0.29
2.5 0.29
High speed 15 Minutes to 6 Hegman
Data on Imoroved Viscositv and Foam Control with Aoitan:
Test
No
Agitan
Grind Viscosity, 25C, Poise 69
Grind Weight per Gallon (pounds) 10.06
Letdown
:
Add while mixing:
McWhorter 73-7358
OK
412 (Degussa Corp.)
Butyl Cell os01 ve
Premix and add:
Manganese Hydro Cure
I1
(Mooney)
Butyl Cellosolve
Polyphase AF-1 (Troy Chemical
)
Add following while mixing:
Aqueous Ammonia 28%
Deionized Water
Aquabead 519 (Micro Powders)
Properties:
%
Nonvolatile (by weight): 29.54
(by volume): 25.41
Pigment to Binder Ratio: 0.44
Pigment Volume Concentration: 11.92
Weight per Gallon (pounds): 8.61
Theoretical
VOC
(pounds/gallon): 2.84
Water-Cosolvent Weight Ratio: 80.68:19.32
pH, 25C:
8.8
Viscosity,
#2
Zahn Cup, 25C (seconds): 33
(grams/liter): 341
-
Agitan 701
58.5
11.11
&
90.0 10.45
25.0 2.90
80.0
9.29
9.5 1
.lo
24.0 2.79
8.0
0.93
11.5 1.33
468.4 54.38
20.2 2.32
SOURCE: King Industries: WR-31: Additives for Waterborne Wood
Formulations
Miscellaneous
213
Anquamine
401
Clear Coat
Semi-Solid EDOXY Dispersion
Part
A:
Dow XUS19000.01 Epoxy Resin*
Benzyl Alcohol
Water
&
Gals
346.93
38.70
17.35 1.99
216.83 25.98
Part
8:
Anquami ne 401 Curing Agent (Ai
r
Products) 177.00 19.37
Water 35.40 4.24
Dowanol
PM
Solvent (Dow) 35.40 4.66
Benzyl Alcohol 44.25 5.07
*Alternately use Epi-Rez 3515 at same loading
Typical Properties:
Wt
solids
(%):
57.45
VOC
solids
(%I:
52.43
VOC
(lb/gal): 1.05
VOC
(g/l): 126
Anauamine 401 Clear Coat ProDerties:
Pot Life, hr: >4
Gloss,
60 spec, 1 day: 100
Gloss, 60 spec,
8
wk:
>90
Mix Ratio: 2:l
Mixed Viscosity, cP: 320
Tack Free Time, hr: 1.0
Hard Dry Time, hr: 6-8
Penci
1
Hardness, overnight
VOC,
lb/gal: 1.1
Volume Solids,
%:
56
SOURCE:
Air
Products and Chem
Agent: Formulation
5
F
cals, Inc.: Anquamine 401 Curing
214
Water-Based Paint Formulations
Anquamine
401
Clear Coat
Solid
EDOXV
Dispersion
Part
A:
€pi-Rez
3520
Water
Part 8:
Anquami ne
401
Water
Defoamer
PnP Solvent
Typical Propert
i
es
:
Wt
Solids
(%):
70.0
Volume Solids
(%):
41.35
VOC
(lb/gal):
1.13
VOC
(g/l):
136
Pot Life, hr:
>5
Gloss,
60
spec,
1
day:
100
Gloss,
60
spec,
8
wk:
>SO
Mix Ratio:
4:l
Mixed Viscosity, CP:
390
Tack Free Time, hr:
0.5
Hard Dry Time:
6-8
Pencil Hardness, overnight:
F
VOC,
lb/gal:
1.1
Volume Solids,
%:
42
Anquami
ne
401
C1 ear Coat Propert
i
es
:
Anquami ne
401
Liquid
EDOXV
Clear Coat
Part
A:
DER
331
Epoxy Resin (Dow)
Benzyl Alcohol
&
621.68
89.20
79.06
61.59
4.25
24.85
Lbs
411 .SO
65.04
Part
B:
Anquami ne
401
Curing Agent (Ai
r
Products)
270.98
Water
169.91
Letdown
:
Water
416.50
Typical Properties:
Wt
Solids
(%):
47.5
VOC
(lb/gal):
0.47
Volume Solids
(%I:
44.2
VOC
(g/l):
56
Resin Stoichiometry:
1.6:l
Gloss,
60
specular:
>90
Hard Dry: Overnight
Pot life, hr:
1
VOC
lb/gal:
0.47
Set to Touch, hr:
3
Liquid Epoxy C1 ear Coat Propert
i
8s
:
69.30
10.69
8.74
7.38
0.53
3.36
Gals
42.54
7.46
29.65
20.36
50.00
SOURCE:
Air
Products and Chemicals, Inc.: Anquamine
401
Curing
Agent: Formulations
8
&
7
Miscellaneous
215
Aaueous Pol yester-Urethane Pi qment
Di
spersi
on
K-Flex XM-2311 and K-Flex XM-4310 are both experimental
aliphatic polyester-urethane aqueous dispersions recommended
for thermoset water-borne coatings. K-Flex XM-2311 provides
excel 1 ent pi gment wetti ng properties. K-F1 ex XM-4310 has a 1 ower
acid number, higher hydroxyl number and is recommended as a
modifying resin for thermoset water-borne acrylics, polyesters,
alkyds or urethanes or primary resin for crosslinking with
ami nopl ast resi ns.
Grind: (Cowles) Grind to 8
N.S.
Hegman Gauge:
Component:
%
by Weight
K-F1 ex XM-2311 10.00
Water 0.70
Ti
-Pure R-900 23.85
Letdown
:
K-F1 ex XM-4310 43.89
HMMM
7.45
Silicone
A
(25%)* 0.18
Silicone
B
(25%)**
0.18
Water 9.45
Nacure 2547
0.30
Dimethylethanolamine 1.43
Water 2.57
Characteri sti cs:
XM-2311/XM-4310/HMMM: 14/61/25
Total Solids,
%:
54.54
Theoretical
VOC,
g/l: 32.2
Pigment/Binder Ratio: 0.8/1
.O
pH Value
(As
is): 8.45
Viscosity, cps***: 200
***Brookfield, Spindle #16, 60
RPM
Substrate: Iron Phosphated Cold Rolled Steel
Cure: 15 Minutes/l49C (300F)
Dry Film Thickness: 20-25 microns (0.8-1.0 mils)
Pencil Hardness: 2H
Knoop Hardness, 259: 4.4
MEK
Double Rubs: 200+
Impact Resistance (in.lbs.): Direct: 160+
60 Gloss,
%:
94.10
Cleveland Humidity Resistance (325 Hours): 60 Gloss,%: 90.54
Taber Abrasion Index
(CS
17, 5009): 274
Film
Properties:
Propert
i
es
:
Reverse: 160+
Formulation Notes:
1. Slowly add neutralizing amine (10% in H20) under good agita-
tion to grind and/or final formulations for pH and viscosity
adjustment.
2. Cosolvent is not recommended for viscosity adjustment.
3. Catalyst level recommendation range: 0.1-0.25% active p-TSA
5.
Immediate letdown
of
grind is recommended.
SOURCE:
King Industries: Formulation
WR-29
on total resin solids. 4. Recommended pH is 7.5-8.0.
*Si
lwet L-7604
**Si
lwet L-7605
216
Water-Based Paint Formulations
Black Gloss Enanel
Materi a1
:
Spensol L52
Aerosol OT-75
Surfynol 104H
Ammoni um Hydroxi de
Regal 330 Carbon Black
Lbs.
Gals.
175.4 20.00
2.3
0.25
2.0 0.25
1.9 0.25
15.0 1
.oo
Add the above materials in the order listed under good agitation,
then pebble
mill
grind to 7
N.S.
Letdown
:
Spensol L52
Add the fol
use and mix
XAMA-
7
Anal
ysi
s
:
owing cross
well. inking agent opt
i
ona
679.7 77.50
)
just prior to
7.4
P;gment Volume Concentration, Percent: 3.5
Pigment/Binder Ratio: 0.6/1
.O
Percent Solids, Weight: 31.9
Percent Solids, Volume: 28.4
Viscosity
@
25C, #4 Ford, Secs.: 25-30
Pounds/Gal 1 on
:
8.82
VOC
(excluding water):
Grams/Liter: 275
Pounds/Gallon: 2.3
pH:
8.5t-0.3
Formulation 21 54-1
0
Clear Barrier/Tie Coat for
Vinyl
Material
:
Arolon 840-W-39
Water
Carbi to1
Ammoni um Hydroxi de
Spensol L54
Aerosol OT-75
Add the above materials in
Lbs.
599.2
33.3
35.0
1.9
194.8
2.9
order under good agitation.
0.75
Gal
s.
68.87
4.00
4.25
0.25
22.31
0.32
Analysis:
Percent Solids, Weight: 33.9 Percent Solids, Volume: 31.2
Viscosity
I3
25C, #2 Zahn. Secs.: 20-25
VOC
(excluding water): Grams/Liter: 209
Pounds/Gallon:
8.7
PH:
8.5-9.0
Pounds/Gallon: 1.7
Formulation 2262-831)
SOURCE: Reichhold Chemicals, Inc.: Sponsol L: Formulations
Miscellaneous
21
7
Clear Tint Base
Material:
Kel sol 3931 -WG4-45
Strodex P-1
00
I
nterci de
T-0
Lbs.
Gals.
370.0 44.52
1.6
0.19
4.2 0.43
Premix the next three materials in order, then add under good
agitation
:
Act
i
v-8
Cobalt Hydrocure
I1
Manganese Hydrocure
Add the following in order:
Pol ymekon
SPP-W
Polyphase AFl
Water
Ammoni um Hydroxi de
Analysis:
Percent Solids, Weight: 23.3
2.1 0.36
1.3 0.17
5.0
0.66
33.3 4.16
8.4
0.81
405.9 48.73
0.5
0.07
Percent Solids] Volume: 21.6 (approx)
Viscosity
@
25C, #2 Zahn, Secs.: 20-25
VOC
(excluding water):
Grams/Li ter
:
185
Pounds/Gal 1 on
:
1
.54
pH: 8.2-8.6
SOURCE:
Reichhold Chemicals, Inc.: Kelsol
3931:
Formula
2099-32
218
Water-Based
Paint
Formulations
FCA’s for Waterborne Building Product Formulations
Clear Waterborne Cement Sealer
Mater
i
a1
:
Rhoplex AC-3001 (Rohm and Haas)
FCA (Foam Control Agent)
Butyl Cellosolve
Surfynol 104E (Air Products)
Propert
i
es
:
%
Nonvolatile (by weight): 45.78
Viscosity, CPS: 150+-10%
pH: 7.7-8.7
Waterborne Black Topcoat
Grind:
Water
Natrosol 250MR (Hercules)
Ammoni a (28%)
Tamol 731-25 (Rohm and Haas)
FCA (Foam Control Agent)
Bayferrox 318M (Miles)
WG-325 Mica (KMG Minerals)
Grind at high speed for 15 minutes
Letdown
:
Rhoplex AC-3001 (Rohm and Haas)
Butyl Cellosolve
Surfynol 104H (Air Products)
Water
Properties:
%
Nonvolatile (by weight): 50.0
(by volume): 37.9
pH, 25C: approx. 9.0
Viscosity, #4 Ford cup, 25C, seconds: 18
Coalescent,
%
on polymer solids: 15
Theretical
VOC
(grams/liter): 119.8
(pounds/gallon): 1.0
&
761.68
0.88
36.40
1.04
&
121.8
1.1
0.5
12.1
3.8
174.5
48.3
605.1
43.6
3.2
13.7
95.21
0.11
4.55
0.13
11.85
0.11
0.05
1.18
0.37
16.98
4.70
58.88
4.24
0.31
1.33
Results demonstrate the versatility of Agitan 260
as
a
persistent foam control agent and its ability to improve color
(represented by the
L
Value and yellow index) and prevent
pigment float.
SOURCE:
King Industries: Formulation
WR-33
Miscellaneous
219
Exterior/Interisr Block Filler
Inqredients:
Pigment
Gri
nd:
Water
Potassi um Tripolyphosphate (KTPP)
Drewplus L-475
Tamol 731
Propylene G1 ycol
Triton Nonionic Surfactant N-101
Kathon
LX
Ti
-Pure R-900
ASP 400
325 Mesh White Waterground Mica
Minex 4
Snowf 1 ake
Ammonium Hydroxide, 28% Aqueous Solution
Water
NeoCar Latex 2300
Ucar Filmer IBT
Water
1
Cellosize Hydroxyethyl Cellulose )Premix
ER-15,000
1
Pounds
240.0
2.0
3.0
10.0
20.0
3.0
1.5
40.0
150.0
50.0
100.0
400.0
2.0
25.0
230.0
15.0
22.0
4.0
Gal 1 ons
28.80
0.09
0.39
1.09
2.31
0.34
0.18
1.20
6.97
2.12
4.61
17.76
0.26
3.00
25.99
1 .89
2.63
0.35
Paint Properties:
PVC.
%:
70.6
Volume Solids,
%:
47.2
Weight Solids,
%:
67.0
Weight per Gal on, lb: 13.17
Stormer,
KU:
115
ICI,
poise: 1.55
pH Value: 9.2
Freeze-Thaw Stability, 3 cycles: Fail
Heat-Aged Stability, 4 weeks at 140F: Pass
Reflectance,
%:
83.5
Gloss, 60: 2.3
Mudcracking,
50
mil
:
Pass
Sag Resistance, mils: 16
Filled Appearance on Block: Exc
Film Properties:
SOURCE: Ucar Emulsion Systems: NeoCar Polymers: Formulation
Suggestion K-2216
220
Water-Based Paint Formulations
High Solids
Self
Priming
Alkyd
Inaredients:
Pigment Grind:
Cargill 57-5766/High Solids Alkyd
Ye1 ki ns-TS/Soya Lecithin
Bentone 38
Methyl Alcohol
Ti-Pure R-SOO/Titanium Dioxide-
Butrol 23/Modi fied Bari um Meta-
Atomite/Calcium Carbonate
Nytal 300/Talc-Magnesium Silicate
Mineral Spirits (Rule 66)
Let Down:
Cargill 57-5766/High Solids Resin
Zi
rconium 6%
Cobalt Naphthenate-6%/Drier
Anti skinni ng Agent
Mineral Spirits (Rule 66)
Paint
Properti es:
Total Vehicle 49.94
Pigment 50.06
Vol ati 1 e 15.95
Organic Solvent 15.95
Non-Volati le 84.05
Non-Volatile Vehicle 33.98
Density (lb/U.S. gal): 11.99
Specific Gravity: 1.44
P.V.C.:
31
.55%
P/B
Ratio: 1.473
Spread
@
1
Mi
1
:
1133 F2
Coating
VOC:
229
G/L
Material
VOC:
229
G/L
Rutile
borate
j&
Gal
224.26 27.35
2.99 0.35
1.99 0.14
1.50 0.23
199.35 5.99
99.68 3.24
149.51 6.62
149.51 6.31
37
*
88 5.89
224.26 27.35
6.98 0.98
1.99 0.27
1.99 0.26
96.68 15.04
77.71
22.29
29.35
29.35
70.65
48.36
18.71
0.25
0.17
0.12
16.63
8.32
12.47
12.47
3.16
18.71
0.58
0.17
0.17
8.07
SOURCE:
Buckman Laboratories: Formulation Suggestion:
KQ-20
Miscellaneous
221
Masonry Block
Materi a1
:
Part
A:
2-Propoxyet hanol
Triton X-100 Surfactant
Tamol 731 (25%
N.V.)
Surfactant
Colloid 640 Defoamer
Rutile Titanium Dioxide
Atomi te Calci um Carbonate
Water
Pounds
11.6
3.5
3.5
4.0
50.0
100.0
50.0
Gal lons
1.50
0.39
0.38
0.50
1.46
4.44
6.00
Mix at high speed
10
minutes; then add and mix 3 minutes:
Short Stuff Polyethylene Fibers 7.0 0.93
Add
under reduced speed:
Water
Epi
-Rez 3520-WY-55 Resin
Part B:
€pi-Cure 8536-MY-60 Curing Agent
ASP
170
Aluminum Silicate
325 Mesh Water Ground Mica
Water
48.6 5.83
260.0 28.57
124.5 15.00
50.0
2.38
100.0 4.24
166.0 20.00
Mix at high speed
10
minutes; then add and mix 3 minutes:
Short Stuff Polyethylene Fibers
Water
Typical Coating Properties:
Total Volume Solids,
%:
41.7
Total Weight Solids,
%:
57.7
PVC,
94:
45.6
Volatile Organic Compounds (VOC):
Pounds/Gallon: 1.60
Grams/Li ter
:
192
Application: Brush and Roller
Resin Composition (solids):
Epoxy Resin,
%:
65.7
Curing Agent,
%:
34.3
Total,
%:
100.0
Composite Blend: Viscosity
Part
A
97
KU
Part
0
>141
KU
Parts
A
and B 131
KU
1
.o
0.13
22.4 2.69
Pounds Gal 1 ons
538.2
50.00
588.9
50.00
SOURCE: Shell Chemical
Co.:
Starting Formulation
No.
1615:
Masonry Block Fill: Epi-Rez
3520-WY-55
Resin/Epi-Cure
8536-MY-60
Curing Agent
222
Water -Based Paint
Formulations
Masonry Blockfi 11
Materi a1
:
Part
A:
2-Propoxyethanol
Triton
X-100
Surfactant
Tamol 731 Surfactant
Colloid 640 Defoamer
Tap Water
Mix and add:
Rutile Titanium Dioxide
Atomite Calcium Carbonate
ASP
170
Alumi num
Si
1 icate
Hi
speed disperse
10
minutes; then add:
Short Stuff Polyethylene Fibers
Tap Water
Add
at
reduced speed:
Epi -Rez 3520-W-55 Resin
Part
8:
Epi -Cure 8537-W-60 Curing Agent
Tap Water
Mix we1 1 and add:
ASP
170 Aluminum
Si
1 icate
325
Mesh Water Ground Mica
Atomite Calcium Carbonate
Hi
speed disperse 10 minutes; then add:
Short Stuff Polyethylene Fibers
Tap Water
Composi te 81 end
:
Part
A
Part B
Typical Coat
Viscosity
P.V.C..
%
Pounds
11.6
3.5
3.5
4.0
71
.O
50.0
75.0
35.0
7.0
11.4
260.0
129.0
166.0
50.0
100.0
125.0
1
.o
28.7
532.0
599.7
ng Properti es
:
Part
A:
128 Krebs Units
Part
B:
108 Krebs Units
Parts
A
and
B:
Fresh: 108 Krebs Units
42.2
Total Weight Solids,
%:
67.4
Total Volume Solids,
%:
46.2
Resin Composition: Epoxy Resin,
%:
65
Volatiles Composition: Water. lbs.: 393.6
Volatile Organic Compounds (VOC):
Curing Agent,
%:
35
Organic, lbs.: 63.6
Pounds/Gal 1 on
:
1
.21
Grams/Liter: 145
Application: Brush and Roller
Gal 1 ons
1.50
0.39
0.38
0.50
8.50
1.46
3.30
1.67
0.93
1.37
30.00
14.25
20.00
2.38
4.24
5.56
0.13
3.44
50.00
50.00
SOURCE: Shell Chemical
Co.:
Starting Formulation
No.
1616:
€pi-Rez
3520-WY-55
Resin/Epi-Cure
8537-WY-60
Curing
Agent
Miscellaneous
223
Water Reducible
A1
kyd
Ingredients:
-
Lb
Pigment Grind:
Water 132.72
Busperse 39/Dispersant 5.90
Bubreak 448/Defoamer 2.95
Zinc Sulfate-Heptahydrate 1.97
Igepal CTA 639/Surfactant 1.97
Butrol 23/Modified Barium Metaborate 49.16
Red Iron Oxide 98.31
Nytal 300/Talc-Magnesi um Si 1
i
cat@ 196.63
Let Down:
Cargill 74-7450/Water Reducible
A1 kyd 252.67
n-Butyl Alcohol 84.55
Ammoni urn Hydroxi de-28% 9.83
Water 216.29
Cobalt Napthenate-6%/Drier 1.97
Zirconium 6% 3.93
Paint Properties:
%Wt
Total Vehicle 67.32 87.47
Pi grnent 32.68 12.53
Vol at
i
1 e 50.16 68.37
Organic Solvent 17.20 26.47
Non-Volatile 49.84 31.63
Non-Volatile Vehicle 17.16 19.11
Density (lb./U.S. gal): 10.59
Specific Gravity: 1.27
P.V.C.: 39.60%
P/B Ratio: 1.905
Spread
F
1
Mil:
507 F2
Coating
VOC:
376 G/L
Material
VOC:
218 G/L
Gal
5
15.93 12.53
0.55
0.56
0.44 0.28
0.12 0.19
0.22 0.19
1.60 4.64
2.51 9.29
8.30 18.57
29.71 23.86
12.53 7.99
1.31 0.93
25.97 20.43
0.27 0.19
0.55
0.37
SOURCE:
Buckman Laboratories: Formulation Suggestion:
KQ-22
224
Water-Based
Paint
Formulations
2-Component Waterborne System
Formulation WR-41 demonstrates the improved performance of a
2-component waterborne system when modified with K-Flex XM-4316,
a polyester-urethane dispersion.
At
both
NCO/OH
ratios, improve-
ments were made in gloss,
MEK
resistance, and flexibility.
NCO/OH
Ratio: 1.6
Acryl ic/PU-Di spersi on: 80/20
Component
A:
Emulsion E-3275
K-Flex XM-4316
Sodium Nitrite
(5%
aq)
Proglyde
DMM
Edaplan LA 402
Silwet 7001
(5%
aq)
Silwet 7605 (25% aq)
Silwet
7604 (25% aq)
Dimethyl ethanol ami ne
Component
B:
Bayhydur XP-7063
Formulation Characteristics:
Nonvolatile, theoretical,
%:
48.7
Theoretical
VOC,
g/L, (lb./gallon): 48, (0.4)
Wt%
69.31
16.89
0.00
1
.23
0.07
0.00
0.00
0.00
0.00
12.50
Formulation Properties,
Ai
r-Dry
20-25C, 2
weeks:
Substrate: Bonderite 1000 cold rolled steel
Film
thickness, micron (mil
.):
32+-2 (1.3+-0.1)
Dry Time (minutes): Set to touch: 4.5
Surface dry: 12
Through dry: 18
20,
%:
74
MEK
Double Rubs: 120
Gloss 60,
%:
96 Knoop Hardness:
5.5
Koenig Hardness (sec): 108 Impact, Direct, inch.lb.: >160
Pencil Hardness: 2H-3H Impact, Reverse, inch.lb.: >160
Formulation Properties, Bake
80C 20
min. Post-cure
20-25C,
2
weeks:
Substrate: Bonderite 1000 cold rolled steel
Film
thickness, micron (mil.): 32+-2 (1.3+-0.1)
NCO/OH
Ratio: 1.6
Gloss 60,
%:
100 Knoop Hardness:
7
Koenig Hardness (sec): 134 Impact, Forward, inch x lb.:>160
Pencil Hardness: 3H Impact, Reverse, inch x lb.:>160
20,
%:
80
MEK
Double Rubs: 135
Formulation Preparation:
agitation for approx.
5
minutes.
SOURCE:
King Industries: Preliminary Formulation WR-41
Add component
B
to component
A
under low shear mechanical
226
Water-Eased Paint Formulations
RAW MATERIAL CHEMICAL DESCRIPTION SOURCE
AC
1024 Acryl
i
c resin Rohm&
Acronal
DS
6183 Copolymer acrylic ester dispersion BASF
Acrysol ASE-60/G-110/ Water-soluble acrylic resins
Rohm&
RM-S25/RM-l02O/RM-2020/
TT-935/WS-68
SCT-200/SCT-275/
Act
i
v-8
Dri
et-, accelerator, stabi 1
i
zer RTVan
Aero Me1 ami ne Powdered grade
Aerosi 1 R-972 Fumed silica
Aerosol OT-75/OTS Surface active agent
A1 umi num L243
A1 umi num Paste #82255
AMP-95 Dispersant
Ancamide 500/2353/
2410
Anquami ne 401
Aquabead 519
Aquacat
Aquamac 640/700
Aquamac 1085/1090
Aqua-sperse 877-9907
Arcosolv
DPM
Arcosolv DPNP
Arcosolv
DPtB
Arcosolv PNB
Arcosolv
PNP
AmCyan
Degussa
AmCyan
Si
1 ber
A1 coa
2-amino-2-methyl-1-propanol Angus
Curing agents for epoxy resins Paci
f
i
c
Liquid polyamide curing agent Paci
f
i
c
Micro
Drier catalyst Ultra
Acrylic latex
e alkyd
Water-sol ub
.ampblack Co
Di
propylene
Sol vent
Coalescent
Solvent
Solvent
McWhort
McWhort
or Dispersant Hul
s
glycol monomethyl ether Arc0
Arco
Arc0
Arc0
Arc0
Trade
Named
Raw
Materials
227
RAW
MATERIAL
Arcosolv PP
Arcosolv PTB
Arolon 500-W-42
Arol on 020-W-49
Arolon 840-W-39
Aromatic
100
Aromatic
150
Atomi te
Aroplaz 1271
Aroplaz 1272
Aroplaz 3859-2-80
ASA
35.3
ASP-NCP/ASP-l70/
ASP-400
Atomi te
Attagel
50
CHEMICAL DESCRIPTION
Solvent
Sol vent
Oxidizing alkyd.
%
solids: 42
Acrylic polymer.
%
solids: 49
Acrylic polymer.
%
solids: 39
Hydrocarbon solvent
Hydrocarbon solvent
Cal ci um carbonate
Long-oil linseed alkyd resin
100% solids version
of
Aroplaz 1271
Alkyd resin
Wax emulsion
A1 uminum si
1
ica extender pigments
SOURCE
Arc0
Arc0
Rei chh
Reichh
Rei chh
Exxon
Exxon
ECC
Rei ch
Reich
Reich
CCA
Engel
Calcium carbonate, natural
ECC
Colloidal attapulgite thickener Engel
Aurasperse W-1021
YIO
Yellow iron oxide Har
s
haw
Aurasperse W-3041
RIO
Red iron oxide Harshaw
Aurasperse W-4123 Harshaw
Aurasperse W-7012 LB Carbon black Harshaw
AZO-33 Zinc oxide Asarco
AZO-55
Zi
nc oxi de. American process Asarco
228
Water-Based
Paint Formulatiom
RAW
MATERIAL CHEMICAL DESCRIPTION
Barytes
No.
1 Barium sulfate extender pigment
Basic Lead Silico Chromate
Bayhydur XP-7063 Water-dispersible isocyanate
Bayferrox 318M Synthetic iron oxide pigment
Beaverwhi te 325 Talc extender pigment
Beckosol 13-402 Water reducible a1 kyd
Beetle 65/80/216-8 Urea-formaldehyde compound
Bentone AD/EW/LT/ Rheological additive
SD-1/38
Benzof
1
ex 9-88 Plasticizer
BK5000 Pigment
BK5099 Pigment
Blastite #220 Aluminum oxide
Brown Iron Oxide 444 Pigment
Bubble Breaker 776-P/ Defoamers
3295
Bubond 357 Cationic polymer
Bubreak 448/4400 Defoamer
Burgess
No.
98/No. 128 Hydrous clay
Busan 11-M1 Barium metaborate microbiocide
Busperse-39/203 Dispersing agent
Butrol 23/35 Corrosion and scale inhibitor
Butyl Carbi to1 Diethylene glycol monobutyl ether
Butyl Carbitol Acetate Diethylene glycol monobutyl ether
acetate
SOURCE
WC&D
Rheox
Bayer
Mi
les
Cyprus
Rei ch
AmCyan
Rheox
Vel sic
Pf
i
zer
Harcros
SOH
IO
Col umb
Wi
tco
Buckman
Buckman
Burgess
Buckman
Buckman
Buckman
Union
Union
Trade Named Raw Materials
229
RAW
MATERIAL CHEMICAL DESCRIPTION SOURCE
Butyl Cel losolve Ethylene glycol monobutyl ether UnCarb
Butyl Oxitol Glycol ether She1 1
Byk 020/023/025 Defoamers Bykchem
acetate
0yk
155/156/301/306/
Additives
320/321/346 BykChem
Bykumen
WS
Wetti ng/di spersi ng agent BykChem
Cab-0-Si 1 L-SO/LM-130 Fumed si
1
i
cas
TS-61
O/TS-720
Calcium Hydrocem Drier catalyst for water systems
Calcium Hydro-Cure Catalyst for water systems
Camel Cal Extra fine ground limestone slurry
Camel Carb Calcium carbonate extender
Camel Fil
CAO-
1
Carbi to1
Calci um carbonate
Antioxidant
Diethylene glycol monoethyl ether
and ethyl ene glycol mixture
Carbopol 941 Thickening agent
Cargi 11 57-5766
WR
High solids alkyd
Cargi 11 72-7203
WR
Oil
free polyester
Cargi 11 74-7450
WR
Short soya alkyd
Cargi 11 74-7474
WR
chain-stopped alkyd
Cargill 7412 Non-oxi di zi ng a1 kyd
Cabot
Mooney
Mooney
Genst a
r
Genstar
Genst a
r
PMCSpec
UnCarb
BFGood
Cargi 11
Cargi 11
Cargi 11
Cargi 11
Cargi 11
230
Water-Based
Paint
Formulations
RAW MATERIAL CHEMICAL DESCRIPTION
Cargill 7464 Water reducible a1 kyd
Cel
i
te 281 /499 Di atomaceous si
1
i
cas
Cellosize ER-52M Hydroxyethyl cellulose thickeners
ER-15,000/ER-30,000/
QP-44OO/QP-44OOH/QP-l5,OOO/
QP-15, OOOH
Chemcor AS-35-3 Wax emulsion
Chempol 10-0091 WR short oxidizing oil alkyd
Chlorez 700 Chlorinated paraffin resin
Chromi
um
Green Oxide 5-5310 Pigment
CL 27NA
Cobalt Chem-All 12%
Cobalt Hydrocure 12%/ Catalysts for water systems
I1
Cobalt Naphthenate-6% Drier
Colloid 107/111/111M/ Dispersants
226/35
Colloid 640/643/650/ Defoamer/Antifoams
653/675/677/679/
694/770
Composi
ti
on
R/T
Surfactants
Cosan 101/158/234 Preservat
i
ves
Cycat 4040 Acid catalyst
Cyclo
Sol
63 Aromatic solvent
Cyme1 303/324/325/ Melamine-formaldehyde resins
327/350/385
SOURCE
Cargi
11
Manvi
11
UNCarb
CCA
Freeman
Dover
Mi
nPi g
Dow
Mooney
Mooney
Interst
Rhone-
Rhone-
Cal gon
Cosan
AmCyan
She1
1
AmCyan
Trade
Named
Raw
Materials
231
RAW
MATERIAL
Dalpad
A
Daxad 30-30
DC
Fluid 593
DC-14
DeeFo HG-12/PI-4/
806-1
15
Dehydran 1293
DER
331/660X80
Di
cyandi ami de
Di
sperbyk
Disperse-Ayd/W22/W28
DMEA
Dowanol DPM/DPnB/
EPh/
PM/
PnB/Pn P/PPH
Dow Corning 14/57
Dowicil 75
Dow XUS19000.01
Drewpl us L-475/
L-493/Y-281
Dri
kal
i
te
Durami te
CHEMICAL DESCIPTION
Coal esci ng agent
Dispersant
Phenyl trimethicone
Si
1
i
cone
Antifoam/defoamers
Defoamer
Epoxy resins
Dispersant
Dispersants
Neutralizing amine
Glycol ether products
Si
1 icone additives
Antimicrobial agent
Epoxy resin
Foam control agents
Calcium carbonate extender pigment
Calcium carbonate extender pigment
E-845 Thickener
Eagle Zinc 417W Zinc oxide
Edaplan LA 402 Flow and leveling agent
SOURCE
Dow
Grace
DowCorn
DowCorn
Ultra
Henkel
Dow
AmCyan
BykChem
Daniel
UnCarb
DowChem
DowCorn
DowChem
DowChem
Drew
ECC
ECC
Rohm&
Eagle
King
232
Water-Based Paint Formulations
RAW
MATERIAL
Ektapro
EEP
Ektasolve DB
Ektasolve DB Acetate
Ektasolve
DE
Ektasolve EB
Ektasolve
EP
Emul sion E-2977
Emulsion E-3122
Emul si on E-3275
€pi -Cure 8290-Y-60
Epi -Cure 8292-Y-60
Epi -Cure 8536-MY-60
Epi -Cure 8537-WY-60
Epi -Rez 351 5-W-60
Epi-Rez 3520-WY-55
Epi -Rez 3522-W-60
Epi
-Rez 3540-WY-55
Epi -Rez 3551 -WY-43
Epi-Rez 5522-WY-55
Epodil
L
Epodil 759
Epotuf 37-058
Epotuf 37-143
Epotuf 37-618
CHEMICAL DESCRIPTION
Ether ester
Sol vent
Solvent
Sol vent
Sol vent
2-propoxyethanol solvent
Acrylic emulsion
Acryl
i
c di spersi on
Epoxy curing agent
Epoxy curing agent
Epoxy curing agent
Epoxy curing agent
Epoxy resin
SOURCE
Eastman
Eastman
Eastman
Eastman
Eastman
Eastman
Rohm&
Rohm&
Rohm&
Shel 1
Shel 1
Shel 1
Shel 1
Shel 1
Epoxy resin Shel
Epoxy resin Shel
Epoxy resin Shel
Epoxy resin Shel
Epoxy resin Shel
Hydrocarbon diluent for epoxy resins
Reactive di
1
uent
Epoxy resin
Epoxy resin
Epoxy resin hardener
Rei ch
Rei ch
Rei ch
Trade Named
Raw
Materials
233
RAW
MATERIAL
EpotUf 37-680
Epotuf 38-501
Exxate
700
CHEMICAL DESCRIPTION
Epoxy resin
Epoxy resin
Oxo-acetate cosolvent
FC-430 F1 uorosurfactant
F1 atti ng Agent TS-100
Fluorad FC-129 F1 uorochemi cal
Foamaster R/VF/VL/ Antifoam/defoamers
333
Foamex 825 Anti foam
Foamki 11 639AA Foam control agent
Fungitrol 234 Fungi ci de
Gold Bond
R
Microcrystalline silica
Haloflex 202 Polymer emu1 si on
Halox 8W-100 Calci
um
bari
um
phospho-si 1
i
cate
Halox BW-191/CW-191/ White non-lead pigments
CW-49l/SW-lll/SW-1116/
sz
P-39 1
Halox Xtain
A
HEC QP-4400 Hydroxyethyl cellulose
Heucophos ZMP/ZPZ Zinc yellows
Hexyl Carbi to1 Solvent
SOURCE
Rei ch
Rei ch
Exxon
3M
Degussa
3M
Henkel
TegoChe
Cruci b
Cosan
Tamms
ICIRes
Hal
ox
Hal ox
Hal ox
UnCarb
Heubach
UnCarb
234
Water-Based
Paint
Formulations
RAW
MATERIAL
Hodag PX-218
Hydrite Flat
D
Iceberg
Igepal GO-630/
CTA-639
Imsil A25
Intercide T-0
Interwet #33
5-1365
5-31 03
Joncryl SCX-1520/
56/95/540/554
Jonwax 26
Kadox-515/911/915
Kathon
LX
K-Cure 129W
Kelecin 1081
Kel sol 3931 -WG4-45
K-F1 ex UD-320W/
XM-2304
K-F1 ex XM-2311
K-Flex XM-4310
CHEMICAL DESCRIPTION
Antifoam
Kaolin extender pigment
Anhydrous aluminum silicate
Surfactants
Microcrystalline silica
Mi
crobi ostat
Wetting agent
Strontium chromate
Acrylic polymers
Wax emulsion
Zinc oxide
Fungicide
Catalyst
Soybean oil
Oil
copolymer.
%
solids: 45
Poly01
s
Pigment dispersing resin
Polyester-urethane dispersion
SOURCE
Hodag
Georgia
Burgess
Rhone-
Unimin
Akzo
Davis
Mi
nPi g
Johnson
Johnson
NJZi
nc
Rohm&
King
Rei ch
Rei ch
King
King
King
Tra&
Named
Raw
Materials
235
RAW
MATERIAL
K-Flex XM-4316
K-Flex
188
Kodaflex DBP
KP-140
Kroma Red R0-7097
Kronos 2020
Kronos 2160
Kronos 2310
K-Sperse 152MS
L-203-D
Lampblack #E77
Lansford L243
Lodyne S107/S107B
LVT 400
Magnacat
Mai ncote HG-54
Mai ncote PR-71
Manganese Hydrocure
CHEMICAL DESCRIPTION
Polyester-urethane dispersion
Pol yo1
Plasticizer
P1 asti ci zer
Iron oxide pigment
Rut
i
1
e
ti
tani um di oxi de
Ti
tani um dioxide
Titanium dioxide
Dispersant
Strontium chromate
Talc
Dri
er-catalyst
Acryl
i
c
1
atex
Acrylic latex
Catalyst
Manganese Hydrocure
I1
Catalyst
Mapico Red 297 Iron oxide
Mapico Red 347A Iron oxide
Mapico 567 Iron oxide
Mapico 1075 Iron oxide
SOURCE
King
King
Eastman
Eastman
Pf
i
zer
Kronos
Kronos
Kronos
King
Cookson
Hul
s
Si
1 ber
Ci
ba-
Barrett
Ultra
Rohm&
Rohm&
OMGroup
OMGrou p
Col umb
Col umb
Col umb
Col umb
236
Water-Based Paint Formulations
RAW
MATERIAL
McWhorter 73-7358
McWhorter 248-5409
Merbac 35
Methocel J-12-MS/856
Methyl Carbi to1
Methyl on 751 08
Mica
Mi
chem 392-25
Mi
chem Lube 11 0/182/
511/737/743/02925
Microtalc MP12-50
Microwhi te 25
Minex 4/10
Min-U-Si1 40
Moly-White 212
Monarch 1300
Mor-Lok 1035/1043
MPA- 1078
Nacor
r
Nacorr 1552/1754
CHEMICAL DESCRIPTION
SOURCE
Modi
f
i
ed pol yo1 ef
i
n
Acrylic emulsion
McWhort
McWhort
Bactericide Cal gon
Hydroxypropyl methylcelluloses Dow
Diethylene glycol monomethyl ether UnCarb
Occi den
325 mesh, water ground Engl ish
KMG/
Uni
mi
n
Wax emulsion Michel
Mi
chel
Wax additives
Pf
i
zer
GeoMarb
Low
micron talc
Sodium potassium aluminum silicates Unimin
Silica paint filler
Corrosion inhibitive pigment
Fluffy carbon black
Anti -settl ing agent
Corrosion inhibitor
Corrosion inhibitors
Nacure
X49-11O/XP-l81/Catalysts
for
polymeric coatings
XP-188/155/25OO-X/
2547
Uni
mi
n
Sherwi n
Cabot
Morton
Rheox
King
King
Ki
ng
Trade Named Raw Materials
237
RAW MATERIAL
Nalco 2300
Nal zi n SC-l/2
Natrosol Pl us/P1 us
330/P1 us 330PA
Natrosol 250 HBR/
1 on
250HR/250MHR/250MR/
250MXR
NeoCar Latex 2300
NeoCar Latex 6035
NeoCar Latex 6040
Neocryl XA-6085
Nicron 400 Talc
Nopco
NDW/NXZ
Nopcoci de N-96
No. 1 White
Novoperm Red F3RK-70
NuoCide 404-D/960
Nuocure Cobalt
10%
Nuocure Manganese 6%
Nuosept 95/951/145/
6351
Nuosperse 657
Nyad 1250
Nytal 300/400
CHEMICAL DESCRIPTION SOURCE
Anti foam Nal co
Corrosion inhibitive pigments Rheox
Hydroxyethylcell ul oses-modi
f
i
ed Aqua1 on
Hydroxyethylcell uloses Aqua-
NeoCar polymer. 55% solids
Exterior polymer. 53.5% solids
For
i
nteri or semigloss appl
i
cati ons
Acryl
i
c copolymer
Defoamers
Mi
1 dewci des
Calcium carbonate
Mi
1 dewci de
Polyurethane catalyst
Polyurethane catalyst
Preservatives
Dispersing agent
Wollastonite
Tal cs
UnCarb
UnCarb
UnCarb
I
CI
Res-
Luzenec
Hen kel
Henkel
ECC
Hoec h st
Huls
Hul
s
Hul
s
Hul
s
Hul
s
Nyco
Vander
238
Water-Based Paint
Formulations
RAW
MATERIAL CHEMICAL DESCRIPTION
OK
412 Flatting agent
Omyacarb
UF
Natural calcium carbonate
Oncor M50 Anti -corrosive pigment
Optiwhi te Anhydrous aluminum silicate
Organofunctional
Si
lane A-187
Patcote 513/519/531/ Defoamers
047
Phos-Chek P/30 Flame retardant
Phosguard 5-0806/
5-0013/5-0015/5-0053
Pigment Disperser
NL
Dispersant
P1
i
01
i
te 7104 Styrene-butadiene copolymer
PMA-100 Fungicide
PM
Acetate
Polygloss
90
C1 ay
Polymekon SPP-W
POlyOX WSR-301 Water soluble resin
Polyphase AF-1 Bactericide fungicide
Pol y-Tex 61 1
-Q
Polywet ND-Z/ND-35 Dispersant/surfactants
Proglyde
DMM
Dipropylene glycol dimethyl ether
Propasol Solvent
B
Industrial solvent
Proxel GXL Chemical biocide
SOURCE
Degussa
Omya
NLChem
Burgess
OSISpec
Patter
Monsant
Mi
nPi g
BASF
Goodyea
Dow
Arco
Huber
Mooney
UnCarb
Troy
Interez
Uni roy
DowChem
UnCarb
IC1
Trade Named
Raw
Materials
239
RAW
MATERIAL CHEMICAL DESCRIPTION
91 48 Defoamer
QR-708/OR-7088/ Rheology modifiers
QR-1374
R-2899 Iron Oxide Red
i
ron oxide
Raven 16/410/1020 Carbon blacks
Raybo 60 F1 ash rust inhibitor
Red Iron Oxide 5-3100 Pigment
Red Iron Oxide 5-3106 Pigment
Red Iron Oxide R-2899/R-4098/R-5098 Pigments
Red Iron Oxide R0-4097 Pigment
Regal 330 Carbon black
Resi mene 747/797 Me1 ami ne resi ns
Rhoplex AC-1024/ Acrylic emulsions
AC-3001/CL-lO4/CL-l05/
E-3188/MV-23/R-AC-507/WL-96
Ropaque OP-62
LO
Opaque polymer
Ross
&
Rowe 551 Modi
f
i
ed 1 eci thi n
Rovace SF-091
Vi
nyl acryl
i
c copolymer
Ruff Buff Coarse silica
SOURCE
Troy
Rohm&
Pf
i
zer
Col umb
Raybo
Mi
nPi g
Mi
nPi g
Pf
i
zer
Harcros
Cabot
Monsan
Rohm&
Rohm&
Ross&
Rohm&
Tammsco
Sancure 81 5/825
Santicizer 160
Santolink EP-560
SF-69
Shi eldex
Short Stuff
Waterborne urethane resin Sanncor
Plasticizer Mon san
t
o
Cross1
i
nker Monsanto
Si
1 icone
GE
Anti-corrosion pigment, nontoxic Davison
Polyethylene fibers Mini Fib
240
Water -Based Paint Formulations
RAW
MATERIAL CHEMICAL DESCRIPTION
Sicor ZNP-S Anti -corrosion pigment
Si 1 ane A-187
Si
lcron G-601 Fine particle silica gel
Si
1 wet L-77/7001/ Silicone wetting agents
L-7604/L-7605
Skane
M-8
Mildewcide for paint
Skino
#2
Anti ski nni ng agent
Snowf 1 ake Calcium carbonate
Solvent 142HT
Sparmi te Bari um sulfate
Special Black
4
Carbon black
Spensol L44/L51/L52/ Urethane polyols
L53/L54
Strodex MO-lOO/P-100/ Surfactants
PK-90/PK-95G
Sunbrite Green 264-8142/ Pigments
Sunbri te Ye1 1
ow
74/
Sunbrite Yellow 272-0558/
Sunfast Blue 248-3750
Super Seatone Burnt Umber Pigment
Surfactol 365 Dispersant
Surfynol CT-lll/ Surfactants
CT-131/CT-151/DF-37/
DF-62
Surfynol DF-58/ Defoamers
DF-70/DF-75
Surfynol DF-llOD/ Surfactants
DF-11 OL/DF-21
O/GA/
TG/104/104DPM/104€/
104H/104PG-50/420/
485
SOURCE
BAS F
OSISpec
SCM
UnCarb
Rohm&
OMGr
ou p
ECC
She1 1
Harcros
Degussa
Reich
Dexter
Sun
Hi
1 ton
CasChem
Ai
rProd
Ai
rProd
Ai
rProd
Trade Named
Raw
Materials
241
RAW
MATERIAL CHEMICAL DESCRIPTION
sws
211 Anti foam
Syloid 234 Si 1
i
ca
f
1 atti ng agent
Syntex 3981 Accelerator
Talc 399 Extender pigment
Tamol 165/681/731/ Dispersants
731A/050/960/983/
11 24/SG-1
Tan 10A
Tergitol NP-4/NP-10/ Nonionic surfactants
NP-40
Texanol Coal esci ng agent
Thalo Blue Aqueous di spersi on
Thixatrol
ST
Thi xotrope
Tint-Ayd WD-2744 Phthalo green dispersion
Tinuvin 328
UV
absorber
Tiona RCL-9 Ti tani
um
dioxide
Ti oxi de TR-92 Ti tani
um
dioxide
Ti -Pure CR-800/ Ti tani
um
dioxides
R-700/R-702/R-706/
R-900/R-901/R-902/
R-960
Ti tanox 2020/2060/ Ti tani
um
dioxides
21 01 /2160
Triton GR-7M Anionic surfactant
Triton CF-10 Wetting agent
Triton
CA/GR-SM/
Nonionic surfactants
N-57/N-lOl/X-100/
X-405
SOURCE
Wacker
Davi son
Rhone-
WC&D
Rohm&
Col umb
UnCarb
Eastman
Tenneco
Rheox
Daniel
Ci
ba-
S
CM
Ti oxide
duPont
Kronos
UnCarb
UnCarb
UnCarb
242 Water-Based
Point
Formulations
RAW MATERIAL CHEMICAL DESCRIPTION
Tronox CR-800/CR-813/ Rutile titanium dioxides
CR-828
Troysan Polyphase Fungicides
AF-1/174/586
Troysol LAC Detergent/surfactant
TS
610
Ucar 515
Ucar Fi 1 mer
IBT
Ucar Latex 100
Ucar Latex 105
Ucar Latex 144
Ucar Latex 146
Ucar Latex
161
Ucar Latex 163
Ucar Latex 169
Ucar Latex 353
Ucar Latex 367
Ucar Latex 379
Ucar Latex 3796
Ucar Latex 421
Ucar Latex 422
Ucar Latex 446
Ucar Latex 447
Ucar Latex 461
Ucar Latex 471
Acrylic latex
High solids acrylic binder
Self-crosslinking acrylic latex
Styrene-acryl
i
c emu1 si on polymer
Vi
nyl acryl
i
c
copolymer
A1 1 -acryl
i
c bi nder
Acryl
i
c polymer bi nder
Vi
nyl acetate copolymer
Acryl
i
c 1 atex polymer
Acrylic latex polymer
Vi
nyl acryl
i
c polymer
Styrene/acrylic latex-soft
Styrene/acrylic latex-hard
SOURCE
Kerr-Mc
Troy
Troy
Cabot
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
Trade Named
Raw
Materials
243
RAW MATERIAL CHEMICAL DESCRIPTION
Ucar Latex
481
Ultra-gloss latex. Polymer: Hard
Ucar Latex
624 100%
acrylic latex
Ucar Latex
625
Acryl
i
c 1 atex
Ucar latex
626
A1 1 -acryl
i
c bi nder
Ucar Latex
651
Acrylic latex
Ucar Latex
2300
Ucar Latex
6030
Fi ne particle
s
ze "booster" 1 atex
Ucar Latex
6336
Hard, all-acryl c latex
Ucar Latex
6390
Acrylic bi nder
.
"Booster" 1 atex
Ucar Pol yphobe
102/103
Rheology modi
f
i
ers
Ucar Polyphobe
106HE/
High efficiency thickeners
107/114-
Ucar Polyphobe
9831
Ucar SCT100/SCT200/
146
Ucar Vehicle
435
Ucar Vehicle
441
Ucar Vehicle
443
Ucar Vehicle
455
Ucar Vehicle
462
Ucar
XYHL
Ucar
376
Rheology modi
f
i
er
Thickeners
SOURCE
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
Acrylic polymer
(45%
solids) UnCarb
Acryl
i
c emu1 si on Uncarb
Acrylic latex
(41%
solids) UnCarb
Self -cross1
i
nki ng acryl
i
c 1 atex UnCarb
Thermosetting styrene acrylic latex UnCarb
Polyvinyl-butyral resin UnCarb
UnCarb
244
Water-Based
Paint
Formulations
RAW
MATERIAL CHEMICAL DESCRIPTION
Varsol No. 1 Mineral spirits
Versa-F1
ow
102
Waterpoxy 701 /702/1401 Epoxies
Wingdale White Natural ground calcium carbonate
Wi
tcobond 234 Polyurethane dispersion
Wollastocoat 10AS
Wollastokup
IOES
W/R
Epoxy Ester Resin
W/R
Polyester 72-7203
SOURCE
Exxon
Shamroc
Henkel
GeorMar
Wi
tco
Nyco
NyCQ
Rei ch
Cargi
11
X-3356 C.P. Medium Medium chrome yellow pigment
Ci
ba-
XX-503/XX-503R Zinc oxides NJZinc
XAMA-
7 Rohm&
YD-2288
Ye1 ki ns-TS Soya lecithin
Yellow Iron Oxide YO-2087 Pigment
Yellow Iron Oxide 1075A Pigment
Zeeospheres 400
Zeeospheres
600
Zinc Chromate Y539D
Zinc Hydro-Nap
Zinc Oxide 417-W
Harcros
Ross&
Harcros
Col
umb
Zeel and
Zeel and
Heubach
Mooney
Eag1
e
Trade Named Raw Materials
245
RAW
MATERIAL CHEMICAL DESCRIPTION
Zirco 6% Drier
Zi
rconi um Chem-All 12%
Zi
rconi um Hydro-Cem
Zi
rconi um dri er, 12%
Zirconium Hydro-Cure 12% Catalyst
for
water systems
Zopaque RCL-6 Titanium dioxide. Rutile
Zopaque RCL-9
Ti
tani um dioxide
1
OES
Wol 1 astocoat
233 Basic Zinc Chromate
399 Lo-Micron Talc Extender pigment
895-9901 Water-dispersed black pigment
SOURCE
Interst
Mooney
Mooney
Mooney
SCM
SCM
Nyco
Wayne
WC&D
Tenneco
Suppliers'
Addresses
247
Air Products and Chemicals
7201
Hami 1 ton Blvd.
Allentown,
PA
18195
(215)-481-4911/(800)-345-3148
Akzo Chemical
s,
Inc.
300
S.
Riverside Plaza
Chicago, IL
60175
(312)-906-7500/(800)-257-8292
Alcoa Industrial Chemicals
P.O.
Box
67
Bauxite,
AR
72011
(501)-776-4981/(800)-643-8771
American Cyanamid Co.
Chemicals Group
One Cyanamid Plaza
Wayne, NJ
07470
(201)-831-2000/(800)-443-0443
Angus Chemical Co.
1500
E.
Lake Cook Rd.
Buffalo Grove,
IL
60089
(708)-215-8600/(800)-362-2580
Aqua1 on
P.O.
Box
15417
2711
Centreville Rd.
Wi
1
mi
ngton,
DE
19850
(302)-996-2000/(800)-345-8104
ARC0
Chemical Co.
3801
West Chester Pike
Newtown Square,
PA
19073
(215)-359-2000
Asarco, Inc.
180
Maiden Lane
New York,
NY
10038
(212)-510-2000
BASF Corp.
100
Cherry
Hill
Rd.
Parsippany, NJ
07054
Buckman Laboratories Int'l Inc.
1256
N.
McLean 8lvd.
Memphis, TN
38018
(201)-316-3000/(800)-526-1072
(901)-278-0330/(800)-BUCKMAN
Burgess Pigment Co.
P.O. Box
349
Sandersville,
GA
31082
(912)-5552-2544/(800)-641-8999
Byk-Chemi e
USA
524
S.
Cherry St.
Wall
i
ngford, CT
06492
Cabot Corp.
Rt.
36
West
Tuscola, IL
61953
(203)-265-2086
(217)-253-3370/(800)-222-6745
Calgon Corp.
P.O.
Box
1346
Pitsburgh,
PA
15230
Cargill, Inc.
P.O.
Box
5630
Mi
nneapol
i
s,
MN
55440
(612)-475-6478/(800)-535-1443
(412)-777-8000/(800)-4-CARBON
CasChem, Inc.
40
Avenue
A.
Bayonne, NJ
07002
Chemical Corp. of America
2
Carlton Ave.
E.
Rutherford, NJ
07073
(201)-858-7900/(8OO)-CAS-CHEM
(201)-438-5600
Ci
ba-Gei gy Corp.
7
Skyline
Dr.
Hawthorne,
NY
10532
(914)-347-4700/(800)-431-1900
Columbian Chemicals Co.
1600
Parkwood Circle
Atlanta,
GA
30339
(404)-951-5700/(800)-235-4003
Cosan Chemical Corp.
400
14th
St.
Carlstadt,
NJ
27072
(201)-460-9300
248
Water-Based
Paint
Formulations
Crucible Chemical Co., Inc.
P.O. Box 6786
Greenville,
SC
29606
(803)-277-1284/(800)-845-8873
Cyprus Industrial Minerals
P.O. Box 3419
Englewood,
CO
80155
(800)-325-0299
Daniel Products
400 Claremont Ave.
Jersey City, NJ 07304
(201)-432-0800
Frank
D.
Davis Co.
7011 Muirkirk Rd.
Bel tsvi
1
le,
MD
20705
(301)-776-2400/(800)-638-4444
Davi son Chemical
Di
v.
W.R.
Grace
&
Co.
P.O.
Box 2117
Baltimore,
MD
21203
Degussa Corp.
65 Challenger Rd.
Ridgefield Park,
NJ
07305
(201)-641-6100
Dexter Chemical Corp.
845 Edgewater Rd.
Bronx,
NY
10474
Dover Chemical Corp
W15
&
Davis
P.O. Box 40
Dover,
OH
44622
(800)-321-8805
Dow Chemical
USA
2020
Dow Center
Midland,
MI
48674
(
800
)
-
258-CH
EM
Dow Corning Corp.
Box 0994
Midland,
MI
48686
(5171-496-4000
Drew Industrial Div.
Ashland Chemical Inc.
One Drew Plaza
Boonton,
NJ
07005
(201)-263-7800/(800)-526-1015
DuPont Co.
1007 Market
St.
Wi
1
mi
ngton
,
DE 19898
(800)
-441 -751
5
Eagle-Picher Industries, Inc.
P.O. Box
550
C &
Porter Streets
Joplin,
MO
64802
(417)-623-8000
Eastman Chemical Co.
P.O. Box 431
Kingsport, TN 37662
(615)-229-4006/(8OO)-EASTMAN
ECC
International
5775 Peachtree-Dunwoody Rd.
Atlanta,
GA
30342
(404)-843-1551/(800)-843-3222
Engelhard Corp.
101 Wood Ave.
Iselin,
NJ
08830
(908)-205-5000
English Mica Co.
Ri
dgeway Center
B1
dg
.
Stamford, CT 06905
(203)-324-9531
Exxon Chemical Americas
13501 Katy Frwy
Houston, TX 77079
(713)-870-6000/(800)-231-6633
Freeman Industries, Inc.
100
Marbledale Rd.
Tuckahoe,
NY
10707
(914)-961-2100
Suppliers' Addresses
249
GE
Si
1
icones
260
Hudson River Rd.
Waterford,
NY
12188
(518)-237-3330/(800)-255-8886
Genstar Stone Products Co.
Exec Plaza
IV
11350
McCormick Rd.
Hunt Valley,
MD
21031
(410)-527-4000
Georgia Marble Co.
1201
Roberts Blvd., 8ldg.
100
Kennesaw,
GA
30144
(404) -421 -6500
B.F.
Goodrich Co.
991
1
Brecksvi 11 e Rd.
Brecksvi 11 e,
OH
441 41
(216)-447-5000/(800)-331~1144
Goodyear Tire
&
Rubber Co.
1144
E.
Market
St.
Akron,
OH
44316
(216)-796-3010
W.R.
Grace
&
Co.-Conn.
55
Hayden Ave.
Lexington,
MA
02173
(61 7)-861 -6600
Harcros Chemical
s
Inc
5200
Speaker Rd.
Kansas City,
KS
66106
(913)-321-3131
Harshaw/Filtrol Partnership
30100
Chagrin Blvd.
Cleveland,
OH
44124
Henkel Corp.
11501
Northlake
Dr.
Cincinnati
,
OH
45299
(513)-530-7300/(800)-543-7370
Heucotech, Ltd.
99
Newbold Rd.
Fairless Hills,
PA
19030
(215)-736-9533/(800)-HEUEACH
Hi
1 ton-Davi
s
Co.
2235
Langdon Farm
Rd.
Cincinnati
,
OH
45237
(513)-841-4000/(800)-477-1022
Hoechst Celanese Corp.
5200 77
Center Drive
Charlotte,
NC
28217
(704)-559-6000/(800)-365-2436
J.M. Huber Corp.
Clay Div.
One Huber Rd.
Macon,
GA
31298
(912)-745-4751/(800)-637-8176
Huls America Inc.
80
Centennial Ave.
Pi
scataway,
NJ
08855
(908)-980-6800/(800)-631-5275
IC1
Resins
US
730
Main
St.
Wilmington,
MA
01887
(508)-658-6600/(800)-225-0947
Interstab Chemicals, Inc.
500
Jersey Ave.
P.O.
Box
638
New Brunswick, NJ
08903
S.C.
Johnson Polymer
1525
Howe
St.
Raci ne,
WI
53403
(414)-631-4875/(800)-231-7868
Kerr-McGee Chemical Corp.
Kerr-McGee
Ctr.
P.O.
Box
25861
Oklahoma City,
OK
73125
(405)-270-1313/(800)-654-3911
King Industries, Inc.
Science Rd.
Norwalk, CT
06852
(203)-866-5551/(800)-431-7900
250
Water-Based Paint Formulations
KMG
Minerals, Inc.
P.O. Box 729
1433 Grover Rd.
Ki
ngs Mountain,
NC
28086
(704)-739-3616/(800)-443-MICA
Kronos, Inc.
P.O. Box 60087
3000
N.
Sam Houston Pkwy
Houston,
TX
77205
(713)-987-6300
Manville Filtration
8,
Minerals
P.O. Box 519
Lompoc,
CA
93438
(303)-978-4900/(800)-6
McWhorter
400 East Cottage Place
Carpentersville, IL 60
4-31 03
10
Michelman, Inc.
9089 Shell Road
Cincinnati,
OH
45236
(5131-793-7766
Micro Powders, Inc.
580 White Plains Rd.
Tarrytown,
NY
10591
(914)-793-4058
Miles Inc.
Mobay Road
Pi
ttsburgh, PA 15205
(412)-777-2000/(800)-662-2927
Mi
neral Pi gments Corp.
Davis Colors
7011 Muirkirk Rd.
Beltsville,
MD
20705
Monsanto Chemi cal Co.
800
N.
Lindbergh Blvd.
St. Loui
s,
MO
63167
(314)-694-1000/(800)-325-4330
Mooney Chemicals Inc.
2301 Scranton Rd.
Cleveland,
OH
44113
Morton International
333
W.
Wacker Drive.
Chicago, IL 60606
Nalco Chemical Co.
One Nalco
Ctr.
Naperville, IL 60563
(312)-807-2000
(708)-305-1000
New Jersey Zinc Co.
Fourth
St.
8
Franklin Ave.
Palmerton, PA 18071
NL Chemicals, Inc.
P.O. Box 700
Hightstown
NJ
08520
Nyco Minerals, Inc.,
P.O. Box 368
Willsboro,
NY
12996
(5181-963-4262
Occidental Chemical Corp.
300 Berwyn Park
Berwyn, PA 19312
(215)-251-1000
OM
Group Inc.
2301 Scranton Rd.
Cleveland, OH 44113
(216)-781-8383/(800)-321-9696
Omya Inc.
61 Main St.
Proctor,
VT
05765
(802)-459-3311/(800)-451-4468
Paci
f
i
c Anchor Chemical Corp.
1224 Mendon
Rd.
Cumberland,
RI
02864
(401)-333-4100/(800)-874-66668
Pfizer, Inc.
235
E.
42
St.
New York,
NY
10017
(212)-573-7217
Suppliers'
Addresses
251
PMC Specialties Group
20525 Center Ridge Rd.
Rocky River,
OH
44116
(216)-356-0700
Raybo Chemical Co.
P.O. Box 2155K
Huntington,
WV
25722
Reichhold Chemicals, Inc.
P.O. Box 13582
Research Triangle Park, NC27709
(919)-990-7500/(800)-448-3482
Rheox, Inc.
P.O. Box 700
Hightstown,
NJ
08520
(609)-443-2500
Rhone-Poulenc Inc.
Prospect Plains Rd.
Cranbury, NJ 08512
(609)-860-4000
Rohm
&
Haas Co.
Independence Mall West
Philadelphia, PA 19105
(215)-592-3000
Sanncor Industries, Inc.
300 Whitney St.
P.O. Box 703
Leomi nster,
MA
01
453
(508)-537-4748
SCM
Chemical
s
2701 Broening Hwy
Baltimore,
MD
21222
(301)-288-8884/(800)-638-3234
Shamrock Technologies, Inc.
Foot of Pacific
St.
Newark, NJ 07114
Shell Chemical Co.
Two
She1
1
Plaza
P.0.80~ 1422
Houston,
TX
77251
(201
)-242-2999
(EOO)-TEC-EPON
Sherwin
Wi
11
i
ams Co.
Chemi cal
s
Di
v.
P.O. Box 6520
Cleveland, OH 44101
(216)-566-2344
Silberline Mfg. Co.
P.O. Box
A
Lansford,
PA
18232
(71 7)
-668-6050
Sun Chemical Corp.
4526 Chickering Ave.
Cincinnati
,
OH 45242
(513)-68l-5950/(800)-543-2323
3M Corp.
3M Center
St.
Paul,
MN
55144
(61 2) -733-1
11
0
Tammsco, Inc.
P.O.
Box J
Tamms, IL 62988
Tenneco Mineral
s
Co.
P.O. Box 281300
Lakewood,
CO
80228
(303)-987-6200
Troy Corp.
72 Eagle Rock Ave.
East Hanover,
NJ
07936
(201)-884-4300
Ultra Additives, Inc.
460 Straight St.
Paterson, NJ 07501
(201)-279-1306/(800)-524-0055
Unimin Corp.
258
Elm
St.
New Canaan, CT 06840
(203)-966-8880/(800)-243-9004
UCAR
Emu1 sion Systems
410 Gregson Drive
Cary,
NC
27511
(919)-469-6700
252
Water-Based
Paint
Formulations
R.T. Vanderbilt
Co..
Inc.
30
Winfield St.
P.O.
Box
5150
Norwalk, CT
06856
(203)-853-1400
Velsicol Chemical Corp.
5600
N.
River Rd.
Rosemont,
IL
60018
(708)-698-7000
Wacker Silicones Corp.
3301
Sutton Rd.
Adrian,
MI
49221
(517)-264-8500/(800)-248-0063
Whittaker, Clark
&
Daniels, Inc.
1000
Coolidge
St.
South Plainfield, NJ
07080
(908)-561-6100/(800-732-0562
Witco Corp.
520
Madison Ave.
New York, NY
10022
(212)-605-394l/(800)-238-9150
